Patents Assigned to Hitco
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Patent number: 4369104Abstract: Improved graphite composite electrodes are provided by dispersing within the matrix resin spaced, collimated graphite fibers having a diameter below 30 microns in a direction perpendicular to the face of the electrode plate. The electrodes are particularly useful in the disinfection of aqueous liquids with low power consumption and with very low ablation of the surface of the electrode.Type: GrantFiled: October 22, 1979Date of Patent: January 18, 1983Assignee: HitcoInventor: Don A. Beckley
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Patent number: 4351932Abstract: A novel bis-imide matrix resin system comprising 50 to 95 percent by weight of ethylenically unsaturated bis-imides, preferably a low melting mixture of a major portion of maleimides of aromatic amines with a minor portion of maleimide of an aliphatic amine and 5 percent to 35 percent by weight of a diunsaturated low-temperature cross-linking agent such as divinyl benzene which gels the bis-imide at low temperatures. This reduces stress between the matrix resin and the surface of the reinforcing fiber, thus reducing the tendency to form microcracks. Microcracking is further reduced and transverse strength is increased by the addition of 0 to 15% of compatible elastomers to the resin and cross-linking agent. Room temperature tackiness, heat resistance and cross-link density are improved by the presence of 0 to 10% of a trifunctional curing agent.Type: GrantFiled: March 27, 1980Date of Patent: September 28, 1982Assignee: HitcoInventors: Sidney W. Street, Don A. Beckley
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Patent number: 4343922Abstract: There are disclosed thermoplastic and thermosetting polymers which incorporate tungsten and/or molybdenum metal atoms. The metal atoms are incorporated into the polymer by reacting a monomer or polymer containing at least one free carboxyl group with a reaction product of tungsten or molybdenum and pyrrolidine.Type: GrantFiled: July 31, 1980Date of Patent: August 10, 1982Assignee: HITCOInventor: Robert C. Shaffer
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Patent number: 4331582Abstract: A catalyst for forming ambient temperature stable diamino-diphenyl sulfone-epoxy composition comprises the half-salt of a strong aromatic sulfonic acid such as toluene sulfonic acid and an imidazole, preferably an alkylated imidazole such as 2-ethyl-4-methylimidazole. The composition fully cures at moderate temperature to form a humidity resistant resin having a high heat distortion temperature and can be impregnated onto reinforcing fibers such as graphite to form composites.Type: GrantFiled: January 14, 1980Date of Patent: May 25, 1982Assignee: HitcoInventor: Eduard P. Babayan
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Patent number: 4331091Abstract: Three-dimensional thick fabrics are made from a laminate of fabric plies by first inserting pointed rods through the laminate to form rows of holes after which needles are reciprocated through the different holes to pull loops of various yarns through the holes. The loops of yarns in adjacent holes are interlocked to hold the plies together. A guide releasably clamped to each yarn controls tension in the yarn while a doffing point is employed to insure that the needle passes through a loop just formed when penetrating the next hole to insure interlock of the loops. Hollow circular objects are formed by winding a length of fabric a selected number of times around a form, following which the pointed rods are used to form holes in the resulting laminate with the needles and yarns being used to form the interlocking loops through the thickness of the laminate.Type: GrantFiled: October 22, 1979Date of Patent: May 25, 1982Assignee: HitcoInventors: Leon Parker, Arthur R. Campman
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Patent number: 4325999Abstract: A bias fabric having parallel, spaced-apart yarns oriented .+-.45.degree. relative to the long axis of the fabric is formed by directing one or more pluralities of the yarns back and forth across the width of the fabric and securing the yarns around pins mounted on movable conveyors at the opposite sides of the fabric. Alternatively, the yarns are mounted on strips of film with the film strips being secured to the opposite conveyors. In one preferred embodiment one or more elongated yarn laying units arranged to supply yarns through apertures along the length thereof are cycled laterally between the opposite conveyors as the conveyors are moved at a controlled speed to form a 2-ply fabric, the yarns being wrapped around pins on the opposite conveyors using an adjustable roller arrangement mounted on the shuttle or a plurality of pin mounting rings the alternate ones of which move in unison so as to engage odd and then even numbered yarns in the yarn array.Type: GrantFiled: November 23, 1979Date of Patent: April 20, 1982Assignee: HitcoInventors: Arthur R. Campman, George K. Shibata, William D. Cumming
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Patent number: 4322464Abstract: A high temperature woven refractory fabric is coated by preheating the surface of the fabric by means of actinically matched radiation, suitably infra-red, and then fusion-bonding the inner surface of a thermoplastic film such as polyurethane to at least one surface of the fabric to fusion-bond the film thereto. The warm fusion-bonded film is then processed through a non-heated nip-roll assembly in which at least one of the rollers has a soft facing such as rubber which impresses the film into the interstitial fillweft woven intersections to form a fabric-appearing coated product. The infra-red wave length is selected for maximum absorption by the fabric and the intensity of the radiation and speed of the film are controlled to provide sufficient but not excessive fusion or melting of the film.Type: GrantFiled: May 24, 1978Date of Patent: March 30, 1982Assignee: HITCOInventor: Don A. Beckley
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Patent number: 4321298Abstract: A fibrous carbon material is first coated with a thermosetting material which remains flexible after being subjected to curing temperatures. The thermosetting material contains a refractory metal capable of reacting with boron to form a metal boride. This thermosetting resin is then cured. The fibrous carbon material is then impregnated with a second thermosetting resin containing a boron compound and, optionally, a refractory metal capable of reacting with boron to form a metal boride. The second thermosetting resin is at least partially cured and a plurality of layers of the fibrous material is then assembled to form a laminate. The laminate is heated to a temperature sufficient to carbonize the thermosetting resin. The resultant carbon-carbon composite has better oxidation resistance, improved high temperature stability, higher density and improved interlaminar tensile strength than does a composite prepared without the presence of the refractory metal in the thermosetting resin.Type: GrantFiled: February 26, 1980Date of Patent: March 23, 1982Assignee: HitcoInventors: Robert C. Shaffer, William L. Tarasen
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Patent number: 4302392Abstract: There are disclosed thermoplastic and thermosetting polymers which incorporate tungsten and/or molybdenum metal atoms. The metal atoms are incorporated into the polymer by reacting a monomer or polymer containing at least one free carboxyl group with a reaction product of tungsten or molybdenum and pyrrolidine.Type: GrantFiled: October 12, 1979Date of Patent: November 24, 1981Assignee: HITCOInventor: Robert C. Shaffer
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Patent number: 4288568Abstract: An elastomer containing chemically bonded metal atoms is prepared by reacting a diene elastomer such as a nitrile rubber with the reaction product of an epoxy resin and a metal containing polymer. The metal containing polymer is prepared by reacting a polycarboxylic acid and a metal complex which is a reaction product of tungsten carbonyl and/or molybdenum carbonyl with pyrrolidine.Type: GrantFiled: July 30, 1980Date of Patent: September 8, 1981Assignee: HitcoInventors: Kenneth W. Lewis, Robert C. Shaffer
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Patent number: 4284744Abstract: There are disclosed thermoplastic and thermosetting polymers which incorporate tungsten and/or molybdenum metal atoms. The metal atoms are incorporated into the polymer by reacting a monomer or polymer containing at least one free carboxyl group with a reaction product of tungsten or molybdenum and pyrrolidine.Type: GrantFiled: September 14, 1979Date of Patent: August 18, 1981Assignee: HitcoInventor: Robert C. Shaffer
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Patent number: 4265727Abstract: Improved graphite composite electrodes are provided by rendering the matrix resin conductive by dispersing therein 5 to 15% by weight of a conductive pigment and by uniformly dispersing therein randomly oriented graphite fibers having a diameter below 30 microns and a length no more than 1/2 the thickness of the electrode plate. The electrodes are particularly useful in the disinfection of aqueous liquids with low power consumption and with very low ablation of the surface of the electrode.Type: GrantFiled: October 22, 1979Date of Patent: May 5, 1981Assignee: HitcoInventor: Don A. Beckley
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Patent number: 4256868Abstract: There is disclosed the reaction product of an epoxy resin and a metal complex which is a reaction product of tungsten carbonyl and/or molybdenum carbonyl with pyrrolidine.Type: GrantFiled: December 12, 1979Date of Patent: March 17, 1981Assignee: HitcoInventor: William L. Tarasen
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Patent number: 4193252Abstract: In a method of making carbon or graphite yarn, a bundle of single ply precursor yarns is knit into an elongated fabric to facilitate subsequent processing of the yarns. The elongated fabric is pretreated to facilitate carbonization thereof such as by being advanced in the direction of elongation thereof through a cleaning process. Thereafter the yarns remain in the form of the fabric to facilitate processing thereof through at least a carbonization step. The carbonization step may be accomplished by winding the elongated fabric onto skeins to a desired extent and then severing the fabric, following which the skeins are disposed in a carbonizing oven to at least partially carbonize the yarns. Thereafter, the fabric length on each skein may be deknitted, and the resulting bundle of single ply yarns is twisted to form a multi-ply yarn which is then fired to substantially raise the percentage of carbon in the yarns and then graphitized.Type: GrantFiled: June 28, 1978Date of Patent: March 18, 1980Assignee: HitcoInventors: Gary D. Shepherd, Ramon B. Fernandez, R. Glenn Kapaun, Charles P. Logan
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Patent number: 4185043Abstract: There are disclosed thermoplastic and thermosetting polymers which incorporate tungsten and/or molybdenum metal atoms. The metal atoms are incorporated into the polymer by reacting a monomer or polymer containing at least one free carboxyl group with a reaction product of tungsten or molybdenum and pyrrolidine.Type: GrantFiled: April 5, 1978Date of Patent: January 22, 1980Assignee: HitcoInventor: Robert C. Shaffer
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Patent number: 4173990Abstract: A plurality of generally parallel, side-by-side warp tows of carbonaceous precursor material are interwoven with fill yarns forming a fabric of low density cross weave to facilitate handling of the warp tows for oxidation, carbonization and other processing thereof. A different fill yarn is interwoven with the warp tows from each of the opposite edges of the fabric so as to form a succession of generally V-shaped loops in each warp yarn with the loops of the two different warp yarns being staggered along the length of the fabric. Each loop of warp yarn is comprised of a pair of lengths of warp yarn which enter the fabric from spaced-apart locations along an edge of the fabric and undulate under and over the warp tows in a like sense which is opposite the sense of the undulations of the immediately adjacent loops prior to joining at a point across part but not all of the width of the fabric.Type: GrantFiled: March 13, 1978Date of Patent: November 13, 1979Assignee: HitcoInventors: Guy B. Langlois, Raymond G. Spain
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Patent number: 4166145Abstract: A carbon-organic resin composite which has been initially shaped as by molding and in which the resin binder has been at least partially precured is transformed into an all-carbon composite and substantially densified by a continuous process in which the composite is continuously heated at different temperatures and subjected to increased pressure. Initially, the composite is heated at a first rate to a temperature on the order of 1000.degree. F., the first rate and the increased pressure applied to the composite being selected to substantially decompose the resin rapidly but without delamination or other damage to the composite. Heating is then continued at a second rate until the composite undergoes substantial softening and becomes plastic, typically at a temperature in excess of 3500.degree. F. Thereafter the composite is maintained at a high temperature, typically in excess of 5000.degree. F.Type: GrantFiled: February 28, 1977Date of Patent: August 28, 1979Assignee: HitcoInventors: Donald M. Hatch, Richard J. Larsen
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Patent number: 4164601Abstract: Fibrous carbon material such as graphite cloth which is to be combined with a thermosetting resin and a boron containing compound to form a carbon-carbon composite is provided with a protective coating consisting of cured furfuryl alcohol copolymers. When formed into a laminate and heated to at least 2150.degree. C. to carbonize and at least partially graphitize the thermosetting resin, the boron greatly increases the interlaminar tensile strength while the coating protects the fibrous material from adverse effects of the boron which reduce the tensile strength in the directions of the fibers of the fibrous carbon material of the composite.Type: GrantFiled: April 24, 1978Date of Patent: August 14, 1979Assignee: HitcoInventor: Robert C. Shaffer
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Patent number: 4145472Abstract: A water soluble sizing for fibrous carbonaceous material consists of either 1,3-diglycidyl-5,5-dimethylhydantoin or 1,3-diglycidylhydantoin. The carbonaceous material is sized by immersion in an aqueous solution of the sizing having a concentration of 0.1-10%, preferably 1-2%, by weight, followed by drying. In addition to being highly water soluble, non-toxic and non-flammable, the sizing provides excellent filament control so as to minimize fuzzing during subsequent handling of the carbonaceous material and is compatible with an epoxy resin matrix system.Type: GrantFiled: September 6, 1977Date of Patent: March 20, 1979Assignee: HITCOInventors: Raymond G. Spain, Albert L. Miller
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Patent number: 4119481Abstract: A high temperature woven refractory fabric is coated by preheating the surface of the fabric by means of actinically matched radiation, suitably infra-red, and then fusion-bondingthe inner surface of a thermoplastic film such as polyurethane to at least one surface of the fabric to fusion-bond the film thereto. The warm fusion-bonded film is then processed through a non-heated nip-roll assembly in which at least one of the rollers has a soft facing such as rubber which impresses the film into the interstitial fill-weft woven intersections to form a fabric-appearing coated product. The infra-red wave length is selected for maximum absorption by the fabric and the intensity of the radiation and speed of the film are controlled to provide sufficient but not excessive fusion or melting of the film.Type: GrantFiled: November 5, 1976Date of Patent: October 10, 1978Assignee: HitcoInventor: Don A. Beckley