Abstract: Process for the preparation of 4-fluoroalkoxycinnamonitriles.The invention relates to a process for the preparation of fluoroalkoxycinnamonitriles of the formula (I) ##STR1## in which n is 1 to 8 and m is 1 to 17, where m.ltoreq.2n+1, by reacting 4-fluorobenzaldehyde with a fluoroalkanol of the formula (II)H.sub.2n+1-m F.sub.m C.sub.n O--H (II)in which m and n are as defined above, in the presence of a base and, if appropriate, a solvent, and reacting the resulting 4-fluoroalkoxybenzaldehyde with cyanoacetic acid or an alkyl cyanoacetate in the presence of a base and, if appropriate, a solvent.
Abstract: A process for the preparation of chlorofluoronitrobenzenes and difluoronitrobenzenes, which comprises heating dichloronitrobenzene to not more than 200.degree. C. in excess with an alkali metal fluoride having a total water content of about 0.2 to about 2.5% by weight in the presence of a quaternary ammonium and/or phosphonium salt, crown ether and/or polyethylene glycol dimethyl ether as catalyst in the absence of a solvent.
Type:
Grant
Filed:
December 22, 1992
Date of Patent:
August 13, 1996
Assignee:
Hoechet AG
Inventors:
Theodor Papenfhus, Andreas Kanschik-Conradsen, Wilfried Pressler