Patents Assigned to Hoechst Celanese
  • Patent number: 5112685
    Abstract: Poly(2-methyl-1,5-pentylene) terephthalamide is discussed herein. It is manufactured in a process starting with a nylon salt made from terephthalic acid and 2-methyl-1,5-pentylene diamine and an excess amount of the diamine. The polymer is spun to form monofilaments. The monofilaments may be used, among other things, to form dryer screens for use in a paper forming process.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: May 12, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert B. Rashbrook, Clyde W. Alexander, Edward C. Bland
  • Patent number: 5110879
    Abstract: Novel polyimide blends are formed of polyimide polymers each having moieties derived from dianhydride and diamine comonomers. The blends of the present invention may be formed by selecting polyimide polymers having structurally identical dianhydride-derived moieties, but structurally different diamine-derived moieties. Preferred miscible blends are formed wherein one of polyimides in the blend is the polymer condensation product of a dianhydride selected from 2,2-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride, 3,3',4,4'-diphenyl tetracarboxylic dianhydride, 3,3',4,4'-benzophenone tetracarboxylic dianhydride, bis(3,4-dicarboxyphenyl ether dianhydride, pyromellitic dianhydride, and mixtures thereof, and 2,2-bis(3-aminophenyl) hexafluoropropane, and another of the polyimides in the blend is the polymer condensation product of the same dianhydride and mixtures thereof noted above, and 2,2-bis(4-aminophenyl) hexafluoropropane.
    Type: Grant
    Filed: April 24, 1990
    Date of Patent: May 5, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Tai-Shung Chung, Rohitkumar H. Vora
  • Patent number: 5108868
    Abstract: This invention relates to a negative-working, peel developable, single sheet color proofing method which can accurately reproduce images, using photosensitized, color constructions. The final construction is useful in predicting the image quality from a lithographic printing process.
    Type: Grant
    Filed: October 21, 1988
    Date of Patent: April 28, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Stephan J. W. Platzer
  • Patent number: 5106211
    Abstract: This invention provides polymeric chanel waveguides which are formed by means of an excimer laser photoablation procedure. The smooth-wall channel waveguides polymeric medium is in combination with polymeric cladding layers to form a laminated matrix. The polymers in the waveguiding medium and the cladding layers of the laminated matrix have side chains which exhibit second order nonlinear optical susceptibility, and which can be molecularly oriented by an electric field.
    Type: Grant
    Filed: February 14, 1991
    Date of Patent: April 21, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Kophu Chiang, David Haas
  • Patent number: 5107034
    Abstract: The invention provides a method for producing 4-(2'-methoxyethyl)phenol by brominating 4-hydroxyacetophenone to produce alpha-bromo-5-hydroxyacetophenone, and then causing a methoxide-bromide exchange to thereby produce alpha-methoxy-4-hydroxyacetophenone; and then conducting a single step reduction of alpha-methoxy-4-hydroxyacetophenone with at least two equivalents of hydrogen per equivalent of alpha-methoxy-4-hydroxyacetophenone in the presence of a hydrogenation catalyst to thereby directly produce 4-(2'-methoxyethyl)phenol.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: April 21, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Brad L. Smith, Werner H. Mueller, Heinz Strutz
  • Patent number: 5106720
    Abstract: A base developable negative acting photoresist composition which is thermally stable, provides high resolution at short exposure times and is capable of development by means of conventional aqueous alkaline developers. The present compositions comprise an alkali soluble hydroxylated polyamide and/or polyimide binder material, a photopolymerizable compound containing at least two ethylenically-unsaturated double bonds, and a light-sensitive photoinitiator.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: April 21, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Werner H. Mueller, Dinesh N. Khanna
  • Patent number: 5106680
    Abstract: Adhesion between carbon fibers and thermoplastic matrix materials, used in carbon fiber composite materials, is promoted by the use of a bridging agent. The composite material includes: a plurality of carbon fibers; a thermoplastic matrix material intermingled among the plurality of carbon fibers; and a bridging agent adhering the plurality of carbon fibers to the thermoplastic matrix material. The bridging agent includes compounds having multifunctional groups that are capable of chemically bonding with a functional group of the carbon fiber and a functional group of the thermoplastic matrix material; but it excludes multifunctional amine compounds having metal-oxygen bonds.
    Type: Grant
    Filed: May 8, 1990
    Date of Patent: April 21, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Julia A. King, Daniel A. Buttry
  • Patent number: 5104961
    Abstract: Polymers comprising perfluoroalkyl groups, reproduction layers containing these polymers and use thereof for waterless offset printing. The novel perfluoroalkyl group-containing polymers comprise polymers or polycondensates and have, in each case as substituents on different carbon atoms of benzene rings, phenolic OH groups and perfluoroalkyl groups which are optionally attached through intermediate members. In particular, at least 10% of the polymer units carry perfluoroalkyl groups. These polymers are either formed by condensation of substituted phenols (e.g., 4-hydroxybenzoic acid-perfluoroalkyl ester) with an aldehyde, a ketone, or a reactive bismethylene compound or by reacting polymers containing phenolic OH groups (e.g., hydroxypolystyrene) or polycondensates containing reactive OH groups (e.g., phenol-formaldehyde resins) with a perfluoroalkyl group-containing compound (e.g., 2,2-dihydroperfluorodecanoic acid chloride).
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: April 14, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Werner H. Muller
  • Patent number: 5104770
    Abstract: A photolithographic resist with sensitivity for actinic radiation in the short wavelength, ultraviolet region is produced from (1) an organic film-forming material, and (2) an oxime carboxylate ester which releases a carboxylic acid on exposure to deep ultraviolet radiation, thereby rendering the composition more soluble in a developer in the exposed regions than in the unexposed regions. A process for the formation of an image is also disclosed comprising (1) exposing the above composition to actinic radiation in a pre-determined pattern and (2) treating the composition with aqueous base developer to remove the exposed areas. The image-forming process may be used in the production of printing plates and microelectronic circuits.
    Type: Grant
    Filed: March 11, 1988
    Date of Patent: April 14, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Douglas A. Usifer, Michael G. Kelly
  • Patent number: 5102713
    Abstract: A blend of low shrinkage polyester fibers and high shrinkage polyester fibers is described. In particular, the blend includes high shrinkage PET copolymers having boiling water shrinkages from 6 to 11 percent and low shrinkage PET copolymer fibers having a shrinkage of less than 3 percent. Saxony carpets made from the blend consistently have better initial tuft end point definition and, in most cases, better bulk than corresponding saxony polyester carpets made from conventional polyester fibers.
    Type: Grant
    Filed: September 5, 1990
    Date of Patent: April 7, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: James A. Corbin, Allen J. Hopkins, Michael C. Whited
  • Patent number: 5102739
    Abstract: Provided is a method for preparing an optical information medium which comprises a polycarbonate substrate. A polycarbonate substrate is subjected to an aqueous ammonia solution treatment at a temperature below ambient temperatures and for an extended period of time. This treatment occurs prior to assembly of the optical information medium. Use of the treated polycarbonate substrate in the optical information medium results in the medium exhibiting a high level of performance over an extended useful life.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: April 7, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Frank J. Onorato, David E. Nikles, Leroy McKenzie, Jeffrey A. Schneider
  • Patent number: 5102552
    Abstract: A composite membrane is disclosed having a microporous support which is coated with a UV curable polymer composition having a sufficiently high viscosity to prevent pore filling upon coating and curing. A process for making and a process for using the membrane is also disclosed.
    Type: Grant
    Filed: September 25, 1990
    Date of Patent: April 7, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Robert W. Callahan, Richard D. Johnson
  • Patent number: 5100757
    Abstract: This invention relates to a method for forming a colored image on a degradable sheet material. As a result, a negative- or positive-working color proofing sheet can be produced on a variety of printing paper stocks. Upon exposure to an actinic radiation source through a screened image and development, it can accurately reproduce the image on the degradable sheet. The construction is useful as a color proof which can be employed to accurately predict the image quality from a lithographic printing process on a variety of printing surfaces.
    Type: Grant
    Filed: October 21, 1988
    Date of Patent: March 31, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Stephan J. W. Platzer, Arthur E. Proctor, Thomas Dunder
  • Patent number: 5101008
    Abstract: A process for producing a copolyester by copolymerizing the monomers from the ester interchange of at least two lower dialkyl esters of dicarboxylic acid and glycol using a novel catalyst system. The novel catalyst composition includes from about 20 ppm to about 150 ppm manganese; from about 50 ppm to about 350 ppm lithium; preferably from about 10 ppm to about 70 ppm cobalt; and from about 200 ppm to about 400 ppm antimony, all amounts being based upon the expected yield of the copolyester. The novel process to make copolyester includes the step of employing an effective catalytic amount of manganese and lithium in an ester interchange reaction where the lower dialkyl esters and glycol produce a monomer mixture; and using an effective catalytic amount antimony in a copolycondensation reaction of the monomers.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: March 31, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Anthony W. Cooke, Monika E. Bader
  • Patent number: 5100985
    Abstract: In one embodiment this invention provides novel organic compounds and polymers characterized by a 1,4-bis(4-arylbutadienyl)benzene structure which exhibits third order nonlinear optical response.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: March 31, 1992
    Assignee: Hoechst Celanese Corp.
    Inventor: Diane E. Allen
  • Patent number: 5101005
    Abstract: The present invention provides cross-linkable polyimide polymers having at least one repeating unit of the sturcture of: ##STR1## wherein n is the number of repeating groups and A is a tetravalent aromatic organic radical wherein each pair of carbonyl groups are attached to adjacent carbons in the ring moiety A.It has been found that polyimides having the structure of formula I may be crosslinked at surprisingly low temperatures when heated from about 75 to about 110.degree. C. to form infusible and solvent resistant shapes, thereby rendering them useful in the preparation of films, laminates and composites where inertness to solvents is a prerequisite.
    Type: Grant
    Filed: May 18, 1989
    Date of Patent: March 31, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Rohitkumar H. Vora, Dinesh N. Khanna, Wolfgang K. Appel
  • Patent number: 5099039
    Abstract: A process for converting 1,4-butanediol to tetrahydrofuran using polybenzimidazole to catalyze the reaction. The conversion is accomplished by heating the 1,4-butanediol in the presence of the PBI. The THF product may be distilled from the reaction solution as an azeotrope with water. To function as the catalyst, the PBI must first be pre-treated with a strong aqueous acid such as sulfuric acid. The catalyst may be in the form of microporous resin beads, hollow fibers, or other forms of PBI. This process exhibits a high selectivity for producing THF without side reactions.
    Type: Grant
    Filed: November 6, 1990
    Date of Patent: March 24, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: David A. Schiraldi, Bennett C. Ward
  • Patent number: 5096784
    Abstract: A polyester film having a nodule surface is disclosed. The acrylic coating is preferably a crosslinked composition having a relatively high methyl methacrylate content and specific surfactants. The acrylic coating composition is applied as an aqueous dispersion to polyester film, preferably after corona treatment of the polyester film. The nodule surface reduces the coefficient of friction of the polyester film. The coating composition comprises from 60 to 90 mole percent methyl methacrylate; from 10 to 35 mole percent of at least one modifier selected from the group of ethyl acrylate, propyl acrylate, butyl acrylate, and mixtures of these; and from 3 to 10 mole percent of a crosslinkable monomer or a self-crosslinking monomer selected from the group of N-methylol methacrylamide, N-methylol acrylamide, acrylamide, methacrylamide, and mixtures of these; with from 2 to 15 weight percent of the nonionic surfactant and at least 0.1 percent by weight of the anionic surfactant.
    Type: Grant
    Filed: December 20, 1989
    Date of Patent: March 17, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: Edwin C. Culbertson, John M. Heberger
  • Patent number: 5096951
    Abstract: A polyoxymethylene molding composition which exhibits improved ambient and heat aged color stability includes a metal deactivator and calcium hydroxystearate. One preferred composition of the invention includes: (a) greater than about 95 weight percent of polyoxymethylene, (b) between about 0.01 to about 0.1 weight percent of 3 salicyloyl-amido-1,2,4 triazole or tris-2-tert.butyl- 4-thio-(2'methyl-4'hydroxy-5'tert.butyl) phenyl-5-methyl phenyl phosphite, (c) between about 0.015 to about 0.4 weight percent of 2,4,6-triamino-sym-triazine, (d) between about 0.25 to about 1.0 weight percent of tetrakis(methylene-(3,5-di-tert-butyl- 4-hydroxyhydrocinnamate)) methane, (e) between about 0.05 to about 0.2 weight percent of calcium 12-hydroxystearate, and (f) between about 0.1 to about 0.3 weight percent of N-N'-ethylenebisstearamide. Due to their enhanced color stability, the compositions of this invention find particular utility as molded automobile components.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: March 17, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Andrew Auerbach
  • Patent number: 5096742
    Abstract: Provided is a method for stabilizing an optical recording medium containing a polycarbonate substrate. The method comprises treating the substrate material in a high temperature, high humidity environment for an extended period of time. Dramatic improvements in the useful life of the optical recording medium in which the treated polycarbonate substrate is used have been found to result.
    Type: Grant
    Filed: January 9, 1990
    Date of Patent: March 17, 1992
    Assignee: Hoechst Celanese Corporation
    Inventors: David E. Nikles, Charles E. Forbes