Patents Assigned to Huls AG
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Publication number: 20110117611Abstract: The invention relates to an isolated polynucleotide from coryneform bacteria, comprising a polynucleotide sequence chosen from the group consisting of a) polynucleotide which is identical to the extent of at least 70% to a polynucleotide which codes for a polypeptide which comprises the amino acid sequences of SEQ ID NO. 2 or SEQ ID NO. 4, b) polynucleotide which codes for a polypeptide which comprises an amino acid sequence which is identical to the extent of at least 70% to the amino acid sequences of SEQ ID NO. 2 or SEQ ID NO.Type: ApplicationFiled: November 8, 2010Publication date: May 19, 2011Applicant: Degussa-Huls AGInventors: L K. Dunican, Ashling McCormack, Cliona Stapelton, Kevin Burke, Bettina Mockel
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Publication number: 20040248731Abstract: Furnace carbon black which has a hydrogen (H) content of greater than 4000 ppm and a peak integral ratio of non-conjugated H atoms (1250-2000 cm−1) to aromatic and graphitic H atoms (1000-1250 cm−1 and 750-1000 cm−1) of less than 1.22. The furnace carbon black is produced by injecting the liquid carbon black raw material and the gaseous carbon black raw material at the same point in a furnace carbon black process. The furnace carbon black may be used in the preparation of electrocatalysts.Type: ApplicationFiled: March 8, 2004Publication date: December 9, 2004Applicant: Degussa-Huls AGInventors: Karl Vogel, Emmanuel Auer, Karl-Anton Starz, Peter Albers, Klaus Bergemann, Conny Vogler
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Patent number: 6821922Abstract: Moldings based on pyrogenically produced mixed oxide having the following physicochemical parameters: External diameter 0.8-25 mm BET surface area 5-400 m2/g Pore Volume 0.2-1.8 ml/g Fracture strength 5 to 350 N Composition At least two oxides selected from the group SiO2, Al2O3, TiO 2 and ZrO2 in any desired combination but with the exception of SiO2/Al2O3 mixed oxides, in which > 75 wt. % of SiO2 is present. Other constituents <1 wt. % Bulk density 250-1500 g/l, are produced by homogenizing pyrogenically produced mixed oxide as desired with one or more compounds from the group methylcellulose, methylhydroxyethylcellulose, wax, polyethylene glycol, magnesium stearate and/or aluminium stearate with addition of water, drying the product at a temperature of 70-150° C.Type: GrantFiled: September 24, 1999Date of Patent: November 23, 2004Assignee: Degussa - HULS AGInventors: Thomas Tacke, Helmfried Krause, Hermanus G. J. Lansink Rotgerink, Francis Daly, Martin Reisinger, Helmut Mangold
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Publication number: 20040214219Abstract: The invention relates to an isolated polynucleotide from coryneform bacteria, comprising a polynucleotide sequence chosen from the group consisting ofType: ApplicationFiled: May 18, 2004Publication date: October 28, 2004Applicant: Degussa-Huls AGInventors: L. K. Dunican, Ashling McCormack, Cliona Stapelton, Kevin Burke, Bettina Mockel
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Patent number: 6797509Abstract: The invention is directed to DNA sequences from coryneform bacteria which encode a protein having transaldolase enzymatic activity. The invention also encompasses methods for the fermentative production of L-amino acids using bacteria in which the gene encoding transaldolase is amplified.Type: GrantFiled: March 20, 2000Date of Patent: September 28, 2004Assignee: Degussa-Huls AGInventors: Laurence Kieran Dunican, Ashling McCormack, Cliona Stapelton, Kevin Burke, Bettina Mockel
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Patent number: 6685769Abstract: Aqueous carbon black dispersions contain carbon black and cationic and non-ionic surfactants in addition to water. The dispersions are produced by dispersing the carbon black and the other components in water with bead mills, ultrasonic mills or an Ultra Turrax mixer. The dispersions can be used to produce inks, lacquers and printing inks.Type: GrantFiled: July 21, 2000Date of Patent: February 3, 2004Assignee: Degussa-Huls AGInventors: Alfons Karl, Horst Kleinhenz, Werner Kalbitz, Gerd Tauber, Andreas Stübbe, Johann Mathias
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Publication number: 20020168731Abstract: The invention relates to preferably recombinant DNA derived from Corynebacterium and replicable in coryneform microorganisms, which contains at least one nucleotide sequence that codes for the thrE gene, and a process for the production of L-threonine, which is characterised in that the following steps are carried out:Type: ApplicationFiled: February 15, 2001Publication date: November 14, 2002Applicant: Degussa-Huls AGInventors: Petra Ziegler, Lothar Eggeling, Hermann Sahm, Georg Thierbach
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Patent number: 6472571Abstract: Process for the production of organic compounds in a membrane reactor. Inorganic membranes composed of an inorganic backing layer and an inorganic interlayer are used in the membrane reactor. The inorganic interlayer may be modified with organic groups.Type: GrantFiled: October 2, 2000Date of Patent: October 29, 2002Assignee: Degussa-Huls AGInventors: Andreas Karau, Jens Wöltinger, Olaf Burkhardt, Andreas Bommarius, Kai Boldt, Jean-Louis Philippe, Hans Henniges, Karlheinz Drauz
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Patent number: 6471763Abstract: An oxidatively aftertreated carbon black has a content of volatile constituents of more than 10 wt. %, based on its total weight, and the ratio of its CTAB surface area to the iodine adsorption number is greater than 2 m2/mg. The carbon black may be a channel black oxidatively aftertreated with ozone. The carbon black according to the invention is used preferably as pigment carbon black for the production of water-based paints, printing inks and as inks for mechanical and manual recording and drawing instruments. The combination of properties imparts to the carbon black an excellent dispersibility in water-based binder systems. The paints, printing inks and printer inks produced from this carbon black have an outstanding stability in storage.Type: GrantFiled: May 28, 1999Date of Patent: October 29, 2002Assignee: Degussa-Huls AGInventor: Alfons Karl
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Patent number: 6451100Abstract: Aqueous carbon black dispersions contain carbon black and cationic surfactants in addition to water. The aqueous carbon black dispersions are produced by dispersing the carbon black and other components in water with bead mills, ultrasonic mills or an Ultra Turrax mixer. The dispersions can be used to produce inks, lacquers and printing inks.Type: GrantFiled: July 21, 2000Date of Patent: September 17, 2002Assignee: Degussa-Huls AGInventors: Alfons Karl, Horst Kleinhenz, Werner Kalbitz, Johann Mathias, Gerd Tauber, Andreas Stübbe
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Patent number: 6447744Abstract: In carrying out the hydrogenation stage of the anthraquinone process for the preparation of hydrogen peroxide in a hydrogenation reactor on a fixed bed catalyst of a particulate catalyst, the service life of the catalyst is increased in that the working solution comprising the reaction carrier and a gas phase comprising hydrogen, are passed through the hydrogenation reactor from the bottom upwards. The empty tube speed of the working solution is 0.05 to 100 m/h, preferably 10 to 50 m/h.Type: GrantFiled: November 6, 2000Date of Patent: September 10, 2002Assignee: Degussa-Huls AGInventors: Thomas Haas, Jürgen Glenneberg, Rudolf Wagner, Matthias Creutz, Jörg Sauer, Rudolf Vanheertum
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Patent number: 6441255Abstract: Carrier-bound ruthenium catalysts are used to produce alcohols by the catalytic hydrogenation of aldehydes and ketones. The problem of deactivation of the catalyst is solved by the use of a ruthenium catalyst on an oxide carrier of the series TiO2, SiO2, ZrO2, MgO, mixed oxides thereof and silicates thereof. In particular, Ru on TiO2 or SiO2 results in a long service life of the catalyst.Type: GrantFiled: September 27, 1999Date of Patent: August 27, 2002Assignee: Degussa -Huls AGInventors: Thomas Haas, Bernd Jaeger, Jörg Sauer, Rudolf Vanheertum
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Patent number: 6436715Abstract: A method for the quantitative determination of silica oil or siloxane concentrations present in trace quantities in silicas or pyrogenic oxides by the quantitative evaluation of proton spectra is presented. The silica or pyrogenic oxide of interest is dispersed in a suitable organic solvent and the phases are then separated. The liquid phase is evaporated to a dry residue which is then redissolved in a deuterated solvent. The redissolved residue is evaluated quantitatively by proton NMR spectroscopy to determine the concentration of silica oil or siloxane by measuring the integral of the methyl silyl protons present in the 1H spectra and comparing same to the integral of the deuterated solvent.Type: GrantFiled: June 30, 2000Date of Patent: August 20, 2002Assignee: Degussa Huls AGInventors: Günther Michael, Arndt Müller
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Patent number: 6437145Abstract: The invention concerns a method of producing oxazolidinones of formula (I), wherein R1-R5 have the meanings given in the description, by reacting cyclical anhydrides of formula (II) with carbonyl compounds of general formula (III) at temperatures between ambient temperature and approximately 150° C. The invention also concerns the production of the cyclical anhydrides of formula (II) by reacting N-protected aminodicarboxylic acids of formula (IV) with a dehydrating agent in situ. The invention further concerns the use of oxazolidinones of formula (I) for the &agr;-selective production of esters of formula (V) and amides of general formula (VII).Type: GrantFiled: April 4, 2000Date of Patent: August 20, 2002Assignee: Degussa-Huls AGInventors: Karlheinz Drauz, Günter Knaup, Stefan Retzow
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Patent number: 6423331Abstract: Pyrogenically prepared silica doped with silver or silver oxide is prepared by feeding an aerosol into a flame such as is used for the preparation of pyrogenic silica, mixing the aerosol homogeneously with gas mixture before the reaction, then allowing the aerosol/gas mixture to react in a flame. The resulting pyrogenic silicas doped with silver or silver oxide are separated from the gas stream. The pyrogenic silica doped with silver or silver oxide by means of an aerosol can be used as a bactericidal filler.Type: GrantFiled: September 8, 2000Date of Patent: July 23, 2002Assignee: Degussa-Huls AGInventors: Helmut Mangold, Rainer Golchert
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Patent number: 6420151Abstract: Isolated polynucleotide from coryneform bacteria, comprising a polynucleotide sequence chosen from the group consisting of a) polynucleotide which is identical to the extent of at least 70% to a polynucleotide which codes for a polypeptide which comprises the amino acid sequence of SEQ ID No. 2, b) polynucleotide which is identical to the extent of at least 70% to a polynucleotide which codes for the polypeptide which is expressed by the pck gene contained on vector pK19mobsacB&Dgr;pck in the deposited E.coli strain DSM 13047, c) polynucleotide which codes for a polypeptide which comprises an amino acid sequence which is identical to the extent of at least 70% to the amino acid sequence of SEQ ID No. 2, d) polynucleotide which is complementary to the polynucleotides of a), b) or c) and e) polynucleotide comprising at least 15 successive bases of the polynucleotide sequence of a), b), c) or d).Type: GrantFiled: December 7, 1999Date of Patent: July 16, 2002Assignee: Degussa-Huls AGInventors: Bernard Eikmanns, Christian Riedel, Hermann Sahm, Bettina Mockel
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Patent number: 6419892Abstract: The invention relates to a process for carrying out gas-liquid reactions in a continuous flow reactor having several reactor chambers arranged parallel to one another, open in the direction of flow. The space-time yield can be increased in that a reactor is used with at least three chambers, the ratio of chamber width b to slit width s of which is, on average, greater than 3 and the slit width s of which is in the range of 5 to 100 mm. Preferably, s is in the range of 5 to 50 mm and s/b in the range of 5 to 100. The continuous flow reactor according to the invention with the at least three reactor chambers and the above ratio s/b is preferably tubular and contains one or more plate stacks.Type: GrantFiled: September 13, 1999Date of Patent: July 16, 2002Assignee: Degussa-Huls AGInventors: Rudiger Schutte, Hubertus Eickhoff
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Patent number: 6417409Abstract: The invention relates to an improved process for the production of 2,3,5-trimethylhydroquinone diesters by rearrangement of 2,6,6-trimethyl-2-cyclohexene-1,4-dione (4-oxoisophorone, ketoisophorone) in the presence of a dissolved, acidic catalyst and an acylating agent, such as for example carboxylic anhydrides or carboxylic acid halides. The 2,3,5-trimethylhydroquinone diester can optionally then be saponified to give free 2,3,5-trimethylhydroquinone (TMHQ), which is a valuable building block in the synthesis of vitamin E.Type: GrantFiled: February 11, 2000Date of Patent: July 9, 2002Assignee: Degussa-Huls AGInventors: Steffen Krill, Klaus Huthmacher
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Patent number: 6413490Abstract: Granules based on titanium dioxide with the characteristics: Average particle diameter: 10 to 150 &mgr;m BET surface area: 25 to 100 m2/g pH: 3 to 6 Compacted density: 400 to 1,200 g/l The granules are prepared by dispersing titanium dioxide in water, spray-drying and silanizing. In the silanized form, the granules have the following characteristics: Average particle diameter: 10 to 160 &mgr;m BET surface area: 15 to 100 m2/g pH: 3.0 to 9.0 Compacted density: 400 to 1,200 g/l Carbon content: 0.3 to 12.0 wt. % The granules are used, inter alia, as catalyst supports, in cosmetics, as sun screens, in silicone rubber, in toning powder, in lacquers and colorants, as grinding and polishing agents and as a raw material for producing glass and ceramics.Type: GrantFiled: June 23, 2000Date of Patent: July 2, 2002Assignee: Degussa-Huls AGInventors: Hilmar Gilges, Dieter Kerner, Jürgen Meyer
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Patent number: 6414177Abstract: A method for producing compounds of the general formula (I) in which R is a linear or any branched (C1-C18) alkyl group, from compounds of the general formula (II) that are reacted in the presence of hydrogen cyanide or a precursor producing hydrogen cyanide in situ and of catalytic amounts of base. The presence of another polar solvent is not necessary. Compounds of formula (I) are important intermediates for perfumes and aromatic substances.Type: GrantFiled: March 20, 2001Date of Patent: July 2, 2002Assignee: Degussa-Huls AGInventor: Johny Edmond De Schrijver