Patents Assigned to Huls AG
  • Publication number: 20110117611
    Abstract: The invention relates to an isolated polynucleotide from coryneform bacteria, comprising a polynucleotide sequence chosen from the group consisting of a) polynucleotide which is identical to the extent of at least 70% to a polynucleotide which codes for a polypeptide which comprises the amino acid sequences of SEQ ID NO. 2 or SEQ ID NO. 4, b) polynucleotide which codes for a polypeptide which comprises an amino acid sequence which is identical to the extent of at least 70% to the amino acid sequences of SEQ ID NO. 2 or SEQ ID NO.
    Type: Application
    Filed: November 8, 2010
    Publication date: May 19, 2011
    Applicant: Degussa-Huls AG
    Inventors: L K. Dunican, Ashling McCormack, Cliona Stapelton, Kevin Burke, Bettina Mockel
  • Publication number: 20040248731
    Abstract: Furnace carbon black which has a hydrogen (H) content of greater than 4000 ppm and a peak integral ratio of non-conjugated H atoms (1250-2000 cm−1) to aromatic and graphitic H atoms (1000-1250 cm−1 and 750-1000 cm−1) of less than 1.22. The furnace carbon black is produced by injecting the liquid carbon black raw material and the gaseous carbon black raw material at the same point in a furnace carbon black process. The furnace carbon black may be used in the preparation of electrocatalysts.
    Type: Application
    Filed: March 8, 2004
    Publication date: December 9, 2004
    Applicant: Degussa-Huls AG
    Inventors: Karl Vogel, Emmanuel Auer, Karl-Anton Starz, Peter Albers, Klaus Bergemann, Conny Vogler
  • Patent number: 6821922
    Abstract: Moldings based on pyrogenically produced mixed oxide having the following physicochemical parameters: External diameter 0.8-25 mm BET surface area 5-400 m2/g Pore Volume 0.2-1.8 ml/g Fracture strength 5 to 350 N Composition At least two oxides selected from the group SiO2, Al2O3, TiO 2 and ZrO2 in any desired combination but with the exception of SiO2/Al2O3 mixed oxides, in which > 75 wt. % of SiO2 is present. Other constituents <1 wt. % Bulk density 250-1500 g/l, are produced by homogenizing pyrogenically produced mixed oxide as desired with one or more compounds from the group methylcellulose, methylhydroxyethylcellulose, wax, polyethylene glycol, magnesium stearate and/or aluminium stearate with addition of water, drying the product at a temperature of 70-150° C.
    Type: Grant
    Filed: September 24, 1999
    Date of Patent: November 23, 2004
    Assignee: Degussa - HULS AG
    Inventors: Thomas Tacke, Helmfried Krause, Hermanus G. J. Lansink Rotgerink, Francis Daly, Martin Reisinger, Helmut Mangold
  • Publication number: 20040214219
    Abstract: The invention relates to an isolated polynucleotide from coryneform bacteria, comprising a polynucleotide sequence chosen from the group consisting of
    Type: Application
    Filed: May 18, 2004
    Publication date: October 28, 2004
    Applicant: Degussa-Huls AG
    Inventors: L. K. Dunican, Ashling McCormack, Cliona Stapelton, Kevin Burke, Bettina Mockel
  • Patent number: 6797509
    Abstract: The invention is directed to DNA sequences from coryneform bacteria which encode a protein having transaldolase enzymatic activity. The invention also encompasses methods for the fermentative production of L-amino acids using bacteria in which the gene encoding transaldolase is amplified.
    Type: Grant
    Filed: March 20, 2000
    Date of Patent: September 28, 2004
    Assignee: Degussa-Huls AG
    Inventors: Laurence Kieran Dunican, Ashling McCormack, Cliona Stapelton, Kevin Burke, Bettina Mockel
  • Patent number: 6685769
    Abstract: Aqueous carbon black dispersions contain carbon black and cationic and non-ionic surfactants in addition to water. The dispersions are produced by dispersing the carbon black and the other components in water with bead mills, ultrasonic mills or an Ultra Turrax mixer. The dispersions can be used to produce inks, lacquers and printing inks.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: February 3, 2004
    Assignee: Degussa-Huls AG
    Inventors: Alfons Karl, Horst Kleinhenz, Werner Kalbitz, Gerd Tauber, Andreas Stübbe, Johann Mathias
  • Publication number: 20020168731
    Abstract: The invention relates to preferably recombinant DNA derived from Corynebacterium and replicable in coryneform microorganisms, which contains at least one nucleotide sequence that codes for the thrE gene, and a process for the production of L-threonine, which is characterised in that the following steps are carried out:
    Type: Application
    Filed: February 15, 2001
    Publication date: November 14, 2002
    Applicant: Degussa-Huls AG
    Inventors: Petra Ziegler, Lothar Eggeling, Hermann Sahm, Georg Thierbach
  • Patent number: 6472571
    Abstract: Process for the production of organic compounds in a membrane reactor. Inorganic membranes composed of an inorganic backing layer and an inorganic interlayer are used in the membrane reactor. The inorganic interlayer may be modified with organic groups.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: October 29, 2002
    Assignee: Degussa-Huls AG
    Inventors: Andreas Karau, Jens Wöltinger, Olaf Burkhardt, Andreas Bommarius, Kai Boldt, Jean-Louis Philippe, Hans Henniges, Karlheinz Drauz
  • Patent number: 6471763
    Abstract: An oxidatively aftertreated carbon black has a content of volatile constituents of more than 10 wt. %, based on its total weight, and the ratio of its CTAB surface area to the iodine adsorption number is greater than 2 m2/mg. The carbon black may be a channel black oxidatively aftertreated with ozone. The carbon black according to the invention is used preferably as pigment carbon black for the production of water-based paints, printing inks and as inks for mechanical and manual recording and drawing instruments. The combination of properties imparts to the carbon black an excellent dispersibility in water-based binder systems. The paints, printing inks and printer inks produced from this carbon black have an outstanding stability in storage.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: October 29, 2002
    Assignee: Degussa-Huls AG
    Inventor: Alfons Karl
  • Patent number: 6451100
    Abstract: Aqueous carbon black dispersions contain carbon black and cationic surfactants in addition to water. The aqueous carbon black dispersions are produced by dispersing the carbon black and other components in water with bead mills, ultrasonic mills or an Ultra Turrax mixer. The dispersions can be used to produce inks, lacquers and printing inks.
    Type: Grant
    Filed: July 21, 2000
    Date of Patent: September 17, 2002
    Assignee: Degussa-Huls AG
    Inventors: Alfons Karl, Horst Kleinhenz, Werner Kalbitz, Johann Mathias, Gerd Tauber, Andreas Stübbe
  • Patent number: 6447744
    Abstract: In carrying out the hydrogenation stage of the anthraquinone process for the preparation of hydrogen peroxide in a hydrogenation reactor on a fixed bed catalyst of a particulate catalyst, the service life of the catalyst is increased in that the working solution comprising the reaction carrier and a gas phase comprising hydrogen, are passed through the hydrogenation reactor from the bottom upwards. The empty tube speed of the working solution is 0.05 to 100 m/h, preferably 10 to 50 m/h.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: September 10, 2002
    Assignee: Degussa-Huls AG
    Inventors: Thomas Haas, Jürgen Glenneberg, Rudolf Wagner, Matthias Creutz, Jörg Sauer, Rudolf Vanheertum
  • Patent number: 6441255
    Abstract: Carrier-bound ruthenium catalysts are used to produce alcohols by the catalytic hydrogenation of aldehydes and ketones. The problem of deactivation of the catalyst is solved by the use of a ruthenium catalyst on an oxide carrier of the series TiO2, SiO2, ZrO2, MgO, mixed oxides thereof and silicates thereof. In particular, Ru on TiO2 or SiO2 results in a long service life of the catalyst.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: August 27, 2002
    Assignee: Degussa -Huls AG
    Inventors: Thomas Haas, Bernd Jaeger, Jörg Sauer, Rudolf Vanheertum
  • Patent number: 6436715
    Abstract: A method for the quantitative determination of silica oil or siloxane concentrations present in trace quantities in silicas or pyrogenic oxides by the quantitative evaluation of proton spectra is presented. The silica or pyrogenic oxide of interest is dispersed in a suitable organic solvent and the phases are then separated. The liquid phase is evaporated to a dry residue which is then redissolved in a deuterated solvent. The redissolved residue is evaluated quantitatively by proton NMR spectroscopy to determine the concentration of silica oil or siloxane by measuring the integral of the methyl silyl protons present in the 1H spectra and comparing same to the integral of the deuterated solvent.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: August 20, 2002
    Assignee: Degussa Huls AG
    Inventors: Günther Michael, Arndt Müller
  • Patent number: 6437145
    Abstract: The invention concerns a method of producing oxazolidinones of formula (I), wherein R1-R5 have the meanings given in the description, by reacting cyclical anhydrides of formula (II) with carbonyl compounds of general formula (III) at temperatures between ambient temperature and approximately 150° C. The invention also concerns the production of the cyclical anhydrides of formula (II) by reacting N-protected aminodicarboxylic acids of formula (IV) with a dehydrating agent in situ. The invention further concerns the use of oxazolidinones of formula (I) for the &agr;-selective production of esters of formula (V) and amides of general formula (VII).
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: August 20, 2002
    Assignee: Degussa-Huls AG
    Inventors: Karlheinz Drauz, Günter Knaup, Stefan Retzow
  • Patent number: 6423331
    Abstract: Pyrogenically prepared silica doped with silver or silver oxide is prepared by feeding an aerosol into a flame such as is used for the preparation of pyrogenic silica, mixing the aerosol homogeneously with gas mixture before the reaction, then allowing the aerosol/gas mixture to react in a flame. The resulting pyrogenic silicas doped with silver or silver oxide are separated from the gas stream. The pyrogenic silica doped with silver or silver oxide by means of an aerosol can be used as a bactericidal filler.
    Type: Grant
    Filed: September 8, 2000
    Date of Patent: July 23, 2002
    Assignee: Degussa-Huls AG
    Inventors: Helmut Mangold, Rainer Golchert
  • Patent number: 6420151
    Abstract: Isolated polynucleotide from coryneform bacteria, comprising a polynucleotide sequence chosen from the group consisting of a) polynucleotide which is identical to the extent of at least 70% to a polynucleotide which codes for a polypeptide which comprises the amino acid sequence of SEQ ID No. 2, b) polynucleotide which is identical to the extent of at least 70% to a polynucleotide which codes for the polypeptide which is expressed by the pck gene contained on vector pK19mobsacB&Dgr;pck in the deposited E.coli strain DSM 13047, c) polynucleotide which codes for a polypeptide which comprises an amino acid sequence which is identical to the extent of at least 70% to the amino acid sequence of SEQ ID No. 2, d) polynucleotide which is complementary to the polynucleotides of a), b) or c) and e) polynucleotide comprising at least 15 successive bases of the polynucleotide sequence of a), b), c) or d).
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: July 16, 2002
    Assignee: Degussa-Huls AG
    Inventors: Bernard Eikmanns, Christian Riedel, Hermann Sahm, Bettina Mockel
  • Patent number: 6419892
    Abstract: The invention relates to a process for carrying out gas-liquid reactions in a continuous flow reactor having several reactor chambers arranged parallel to one another, open in the direction of flow. The space-time yield can be increased in that a reactor is used with at least three chambers, the ratio of chamber width b to slit width s of which is, on average, greater than 3 and the slit width s of which is in the range of 5 to 100 mm. Preferably, s is in the range of 5 to 50 mm and s/b in the range of 5 to 100. The continuous flow reactor according to the invention with the at least three reactor chambers and the above ratio s/b is preferably tubular and contains one or more plate stacks.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: July 16, 2002
    Assignee: Degussa-Huls AG
    Inventors: Rudiger Schutte, Hubertus Eickhoff
  • Patent number: 6417409
    Abstract: The invention relates to an improved process for the production of 2,3,5-trimethylhydroquinone diesters by rearrangement of 2,6,6-trimethyl-2-cyclohexene-1,4-dione (4-oxoisophorone, ketoisophorone) in the presence of a dissolved, acidic catalyst and an acylating agent, such as for example carboxylic anhydrides or carboxylic acid halides. The 2,3,5-trimethylhydroquinone diester can optionally then be saponified to give free 2,3,5-trimethylhydroquinone (TMHQ), which is a valuable building block in the synthesis of vitamin E.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: July 9, 2002
    Assignee: Degussa-Huls AG
    Inventors: Steffen Krill, Klaus Huthmacher
  • Patent number: 6413490
    Abstract: Granules based on titanium dioxide with the characteristics: Average particle diameter: 10 to 150 &mgr;m BET surface area: 25 to 100 m2/g pH: 3 to 6 Compacted density: 400 to 1,200 g/l The granules are prepared by dispersing titanium dioxide in water, spray-drying and silanizing. In the silanized form, the granules have the following characteristics: Average particle diameter: 10 to 160 &mgr;m BET surface area: 15 to 100 m2/g pH: 3.0 to 9.0 Compacted density: 400 to 1,200 g/l Carbon content: 0.3 to 12.0 wt. % The granules are used, inter alia, as catalyst supports, in cosmetics, as sun screens, in silicone rubber, in toning powder, in lacquers and colorants, as grinding and polishing agents and as a raw material for producing glass and ceramics.
    Type: Grant
    Filed: June 23, 2000
    Date of Patent: July 2, 2002
    Assignee: Degussa-Huls AG
    Inventors: Hilmar Gilges, Dieter Kerner, Jürgen Meyer
  • Patent number: 6414177
    Abstract: A method for producing compounds of the general formula (I) in which R is a linear or any branched (C1-C18) alkyl group, from compounds of the general formula (II) that are reacted in the presence of hydrogen cyanide or a precursor producing hydrogen cyanide in situ and of catalytic amounts of base. The presence of another polar solvent is not necessary. Compounds of formula (I) are important intermediates for perfumes and aromatic substances.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: July 2, 2002
    Assignee: Degussa-Huls AG
    Inventor: Johny Edmond De Schrijver