Patents Assigned to Huntsman Petrochemicals LLC
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Patent number: 10766994Abstract: The present disclosure provides a method for reducing the aldehyde content in an amine catalyst by treating the amine catalyst with a treating agent selected from a non-cyclic amide substituted with an isocyanate reactive group, a guanidine substituted with an isocyanate reactive group, a polyether amine adducted with a urea compound or a guanidine compound, a free radical scavenger and a mixture thereof. The treated amine catalyst may then be used in the production of polyurethane materials which exhibit reduced aldehyde emissions.Type: GrantFiled: January 13, 2015Date of Patent: September 8, 2020Assignee: Huntsman Petrochemical LLCInventors: Ernest L. Rister, Jr., Haibo Zhao, Robert A. Grigsby, Jr., Robert B. Moore
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Patent number: 10717875Abstract: Provided herein are compositions useful as ink or coatings which contain novel dispersants that are capable of dispersing pigments which are traditionally difficult to disperse while maintaining acceptable levels of viscosity. Use of dispersants as taught herein enables the preparation of a wide variety of inks and coatings having high pigment loading and existing within a conventionally-useful viscosity range.Type: GrantFiled: December 23, 2016Date of Patent: July 21, 2020Assignee: HUNTSMAN Petrochemical LLCInventors: Duy T Nguyen, Howard P Klein
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Patent number: 10519363Abstract: Methods of enhanced oil recovery are disclosed that use compositions including an alkyl polyether anionic surfactant having the general structure R1JA, wherein R1 is a C8-C18 primary or secondary radical group, J is a random, block, alternating, or alternating block polyether segment having the structure [(PO)x(EO)y(BO)z], wherein x is 4 to 18, y is 0 to 20, and z is 0 to 5, and A is an anionic group; a co-surfactant having the general structure (R2)q(B)Ph-L-Ph(D)(R3)r, wherein R2 and R3 are each, independently in each instance, a C8-C24 linear or branched, primary or secondary alkyl group, B and D are anionic groups, q is 1 to 3, r is 1 to 3, and L is O or CH2; and an alkoxy alcohol.Type: GrantFiled: December 1, 2015Date of Patent: December 31, 2019Assignee: HUNTSMAN Petrochemical LLCInventors: Luis C. Salazar, David C. Lewis, Srinivasa Godavarthy
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Patent number: 10513578Abstract: Implementations described herein generally relate to etheramine mixtures formed from a mixture of two or more multifunctional alcohol initiators, processes for the etheramine mixtures production, and its use as a curing agent or as a raw material in the synthesis of polymers. In one implementation, the process comprises mixing a polyol initiator having a melting point greater than a processing temperature and a polyol initiator having a melting point less than the processing temperature to form a polyol initiator mixture having a melting point less than the processing temperature, charging the polyol initiator mixture to an alkoxylation reaction zone, contacting the polyol initiator mixture with an alkylene oxide in the alkoxylation reaction zone to provide a mixture of alkoxylated precursor polyols and charging the mixture of alkoxylated precursor polyols to a reductive amination zone and reductively aminating the mixture of alkoxylated precursor polyols to form the etheramine mixture.Type: GrantFiled: October 30, 2014Date of Patent: December 24, 2019Assignee: HUNTSMAN Petrochemical LLCInventors: Hui Zhou, David C Lewis, Howard P Klein, Terry L Renken, Leah Patterson
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Patent number: 10472456Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of an isocyanate reactive component; a treating agent selected from the group consisting of cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger, or a polymer acid, or a mixture thereof; one or more amine components, each of said amine components having a given structure.Type: GrantFiled: July 9, 2015Date of Patent: November 12, 2019Assignee: HUNTSMAN Petrochemical LLCInventors: Geert Lodewijk Dries, Eugene P Wiltz, Jr., Robert Allison Grigsby, Jr.
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Patent number: 10472318Abstract: Embodiments described herein provide a compound that may be used in a variety of applications such as corrosion inhibition, additives for metalworking, mining reagents, epoxy curatives, emulsifiers, fuel or lubricant additives, surfactant manufacture, acid scavengers and asphalt additives. The compound has the following structure: where R1 is a methoxy group, R2, R3, R4 and R5 are independently a hydrogen atom or an alkyl group, and R6 is an aminomethyl group.Type: GrantFiled: December 6, 2018Date of Patent: November 12, 2019Assignee: HUNTSMAN Petrochemical LLCInventor: Donald H Champion
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Patent number: 10414998Abstract: The present disclosure relates to novel organic friction modifiers for use in non-aqueous lubricant compositions, the organic friction modifiers comprising a product formed from the reaction of polyisobutylene succinic anhydride and a hydrophilic polyetheramine.Type: GrantFiled: March 2, 2016Date of Patent: September 17, 2019Assignee: HUNTSMAN Petrochemical LLCInventor: Haibo Zhao
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Patent number: 10364337Abstract: In an embodiment, an amine-oxidation inhibitor, such as a free radical scavenger and/or antioxidant, is added to an oxidation-sensitive amine, such as an amine catalyst, to inhibit oxidation of the amine. The inhibitor-treated amine may then be used in an application such as a polyurethane application to reduce the emission of undesired oxidation products from the polyurethane.Type: GrantFiled: January 18, 2016Date of Patent: July 30, 2019Assignee: HUNTSMAN Petrochemical LLCInventors: Bhajendra Narayan Barman, Robert A Grigsby, Jr.
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Patent number: 10308754Abstract: An isocyanate reactive composition comprising At least one component selected from the group consisting of a polyether polyol, a polyester polyol, a polyether polyamide and a polyester polyamide; one or more amine components, each of said amine components having a given structure. In some embodiments, the average number of nitrogen atoms of said amine components is in the range of 5 to 10.Type: GrantFiled: July 10, 2013Date of Patent: June 4, 2019Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Geert Lodewijk Dries, Robert Allison Grigsby, Jr., Ernest Lee Rister, Jr., Eugene P. Wiltz, Jr.
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Patent number: 10301489Abstract: Embodiments described herein provide a dispersant for ink and pigmented coatings. The dispersant is a polyurethane having oxamide diol groups. The dispersant may be used to prepare a wide variety of inks and coatings having high pigment loading and existing within a conventionally-useful viscosity range.Type: GrantFiled: November 5, 2015Date of Patent: May 28, 2019Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Howard P. Klein, Frank Bertens, Petra Vanderstraeten, Jolande Celis
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Patent number: 10264785Abstract: New stabilizers for solutions of choline hydroxide and related quaternary trialkylalkanolamines are disclosed. The stabilizers are alkyl hydroxylamines, hydrazines, hydrazides, or derivates thereof, including compounds containing more than one such functionality. The new stabilizers are effective at concentrations less than about 1000 ppm, and choline hydroxide solutions stabilized with the compounds described herein typically have Gardner Color change less than about 2.0 after six months at reasonable temperatures.Type: GrantFiled: May 1, 2017Date of Patent: April 23, 2019Assignee: HUNTSMAN PETROCHEMICAL LLCInventor: Dave C Ferguson
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Patent number: 10239820Abstract: Embodiments described herein provide a compound that may be used in a variety of applications such as corrosion inhibition, additives for metalworking, mining reagents, epoxy curatives, emulsifiers, fuel or lubricant additives, surfactant manufacture, acid scavengers and asphalt additives. The compound has the following structure: where R1 is a methoxy group, R2, R3, R4 and R5 are independently a hydrogen atom or an alkyl group, and R6 is an aminomethyl group.Type: GrantFiled: December 1, 2015Date of Patent: March 26, 2019Assignee: HUNTSMAN PETROCHEMICAL LLCInventor: Donald H Champion
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Patent number: 10131737Abstract: The present disclosure provides a method for reducing the aldehyde content in an amine catalyst by treating the amine catalyst with a treating agent selected from a cyclic urea substituted with at least one isocyanate reactive group, a free radical scavenger and a mixture thereof. The treated amine catalyst may then be used in the production of polyurethane materials which exhibit reduced aldehyde emissions.Type: GrantFiled: September 30, 2014Date of Patent: November 20, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Ernest L Rister, Jr., Srinivasa S Godavarthy, Henry Robertson, Robert A Grigsby, Jr., Robert B Moore, Geert Lodewijk Dries, Eugene P Wiltz, Jr.
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Patent number: 10130091Abstract: An agrochemical emulsifiable concentrate (EC) formulation comprising at least one agrochemical active ingredient; at least one surfactant emulsifier; optionally, a stabilizer; and a primary solvent system, wherein the solvent system is selected from benzyl acetate or a combination of benzyl acetate and at least one substantially water-immiscible co-solvent.Type: GrantFiled: February 25, 2013Date of Patent: November 20, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Rowan Brown, Marie Giansiracusa, Dilek Saylik, Martin Edmond Doyle, Andrew F Kirby
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Patent number: 10123532Abstract: Embodiments of the present invention disclose using low hydrophilic-lipophilic balance surfactants as spray drift reduction agents and methods of using such agents.Type: GrantFiled: January 4, 2016Date of Patent: November 13, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventor: Curtis M. Elsik
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Patent number: 10015960Abstract: A sticker adjuvant that may be used in agrochemical compositions is disclosed. The sticker adjuvant is a polyether amide or a polyether imide formed by the reaction of a polyether polyamine with a polyfunctional monomer. The polyfunctional monomer may be a polyacid, a di-functional acyl halide, an acid anhydride, a poly(acid anhydride) and a mixture thereof.Type: GrantFiled: December 8, 2016Date of Patent: July 10, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Matthew T. Meredith, Alan J Stern, Dilek Saylik
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Patent number: 9988571Abstract: The present disclosure provides a surfactant formulation for use in treating and recovering fossil fluid from a subterranean formation. The surfactant formulation includes a primary surfactant, a formulation stability agent and injection water. The surfactant formulation may be injected into one or more injection wells located within the subterranean formation and fossil fluids can then be subsequently recovered from one or more producing wells.Type: GrantFiled: September 12, 2013Date of Patent: June 5, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Luis C. Salazar, David C. Lewis, Guy Biesmans, Srinivasa S. Godavarthy, Farron W. Miller
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Patent number: 9987588Abstract: Amine compositions comprising sterically hindered amines and associated methods are provided. In some embodiments, amine compositions of the present disclosure may be useful for selective removal of H2S from an acidic gas stream.Type: GrantFiled: February 6, 2017Date of Patent: June 5, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Wei-Yang Su, Robert A. Grigsby, Jr., Jingjun Zhou
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Patent number: 9988483Abstract: The present disclosure relates to pyrrolidine-based catalysts for use in a polyurethane formulation. The polyurethane formulation includes the pyrrolidine-based catalyst, a compound containing an isocyanate functional group, an active hydrogen-containing compound. The use of such catalysts produces high quality polyurethane foam while reducing environmental concerns that can arise during the production of polyurethane foam as well as in the foam that is produced.Type: GrantFiled: June 24, 2015Date of Patent: June 5, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: Matthew W. Forkner, Robert A. Grigsby, Jr., Eugene P. Wiltz, Jr., Ernest L. Rister, Jr., Frank Rodriguez, Howard P. Klein
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Patent number: 9873664Abstract: A surface active agent comprising an arylated methyl ester of a fatty acid, or mixture of fatty acids, derived from biodiesel or a triglyceride source is disclosed. The fatty acid mixture is condensed to methyl esters and alkylated with aromatic substituents under Friedel-Crafts conditions. The alkylated methyl esters may be alkoxylated using a catalyst derived from fatty acids, alkaline earth salts, and strong acids. The resulting nonionic surfactant may also be sulfonated to produce one class of anionic surfactants. The alkylated methyl esters may also be directly sulfonated to produce another class of anionic surfactants.Type: GrantFiled: December 9, 2016Date of Patent: January 23, 2018Assignee: HUNTSMAN PETROCHEMICAL LLCInventors: George A Smith, Daniel R. Weaver, Zheng Chai