Patents Assigned to Hydro-Quebec
  • Publication number: 20230207808
    Abstract: Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds may be obtained by a direct synthesis embodying a hydrothermal method. The method may include preparing an aqueous mixture including a M-containing compound, a M?-containing compound and a M?-containing compound to obtain a M-M?-M? mixture; adding a P-containing compound to the mixture M-M?-M? mixture to obtain a M-M?-M?-P mixture; adding a Na-containing compound to the M-M?-M?-P mixture to obtain a Na-M-M?-M?-P mixture; and introducing the Na-M-M?-M?-P mixture into an autoclave to perform crystal growth and obtain the compound of general formula NahMiM?jM?kPO4.
    Type: Application
    Filed: December 22, 2022
    Publication date: June 29, 2023
    Applicants: HYDRO-QUÉBEC, CIC ENERGIGUNE
    Inventors: Montse GALCERAN MESTRES, Montse CASAS-CABANAS, Abdelbast GUERFI, Michel ARMAND, Teofilo ROJO, Karim ZAGHIB, Andrea PAOLELLA
  • Patent number: 11668819
    Abstract: A method for locating and quantifying obstructions in a pipe is described. The method comprises the steps of emitting at one end of the pipe, by means of a loudspeaker, an emitted signal comprising a wave train at a first frequency, the waves being of an acoustic type; receiving at the same end of the pipe, by means of a microphone, a reflected signal, resulting from the reflection of the wave train from obstructions in the pipe; determining a position of each of the obstructions according to a delay measured between the wave train of the emitted signal and the wave train of the reflected signal received by the microphone; and determining, for each of the obstructions, its degree of obstruction by extrapolating the energies of the emitted, reflected and transmitted signals. A system comprising the loudspeaker, the microphone, a processor, and a memory for performing the above method is also described.
    Type: Grant
    Filed: May 27, 2022
    Date of Patent: June 6, 2023
    Assignee: HYDRO-QUÉBEC
    Inventors: André Roman Taras, Mathieu Soares
  • Patent number: 11661344
    Abstract: The present invention proposes a process for purifying raw carbon nanotubes to obtain an content in metallic impurities comprised between 5 ppm and 200 ppm. The process includes an increase in the bulk density of the raw carbon nanotubes via compacting to produce compacted carbon nanotubes. The process further includes sintering the compacted carbon nanotubes by undergoing thermal treatment under gaseous atmosphere in order to remove at least a portion of the metallic impurities contained in the raw carbon nanotubes, and consequently producing purified carbon nanotubes. These purified carbon nanotubes are directly usable as electronic conductors serving as basis additive to an electrode material without requiring any subsequent purification step. The electrode material can then be used to manufacture an electrode destined to a lithium-ion battery.
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: May 30, 2023
    Assignees: HYDRO-QUEBEC, ARKEMA FRANCE
    Inventors: Ali Darwiche, Martin Dontigny, Naoyuki Kondo, Abdelbast Guerfi, Karim Zaghib, Julien Beausoleil, Alexander Korzhenko
  • Patent number: 11649190
    Abstract: This document describes processes for preparing ceramics, especially lithium-based ceramics. The ceramics produced by this process and their use in electrochemical applications are also described as well as electrode materials, electrodes, electrolyte compositions, and electrochemical cells comprising them.
    Type: Grant
    Filed: May 30, 2019
    Date of Patent: May 16, 2023
    Assignee: HYDRO-QUEBEC
    Inventors: Andrea Paolella, Sylvio Savoie, Vincent Gariepy, Wen Zhu, Abdelbast Guerfi, Karim Zaghib
  • Patent number: 11652209
    Abstract: A copolymer including a monomer A with a molar ratio a varying between around 0.01 and around 0.20, a monomer B with a molar ratio b varying between around 0.2 and around 0.4, and a monomer C with a molar ratio c varying between around 0.50 and around 0.70, the monomer A being a hydrophilic monomer including a pendant chain of poly(ethylene oxide) (POE) with low molar weight, the monomer B being a hydrophobic monomer with a glass transition temperature (Tg) of around ?30° C. or less, the monomer C being a monomer that is more hydrophobic than the monomer Band having a glass transition temperature (Tg) of around 80° C. or more, said monomers being organised in a hydrophilic segment, a hydrophobic segment and an intermediate segment located between the hydrophilic segment and the hydrophobic segment.
    Type: Grant
    Filed: February 4, 2021
    Date of Patent: May 16, 2023
    Assignee: HYDRO-QUÉBEC
    Inventors: Jean-Christophe Daigle, Karim Zaghib
  • Patent number: 11643497
    Abstract: Here are described polymers comprising monomeric units from vinylimidazole derivatives and their use in electrode materials and/or electrolyte compositions, as well as their methods of preparation. Also described are electrode materials, electrodes, and electrochemical cells comprising the polymers and their use.
    Type: Grant
    Filed: July 6, 2018
    Date of Patent: May 9, 2023
    Assignees: HYDRO-QUEBEC, MURATA MANUFACTURING CO., LTD.
    Inventors: Jean-Christophe Daigle, Charlotte Mallet, Yuichiro Asakawa, Melanie Beaupre, Shinichi Uesaka, Karim Zaghib
  • Publication number: 20230136818
    Abstract: All-solid-state electrochemical cells comprising an inorganic particle-polymer composite, where the polymer is a crosslinked polymer and the content of inorganic particles in the composite is at least 50 wt. % are described. Also described are processes for the preparation of such all-solid-state electrochemical cells, all-solid-state batteries comprising them and their uses in mobile devices, electric or hybrid vehicles, or in renewable energy storage.
    Type: Application
    Filed: April 27, 2021
    Publication date: May 4, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Chisu KIM, Ali DARWICHE, Benoit FLEUTOT, Emmanuelle GARITTE, Ki Seok KOH, Marc-Andre GIRARD, Catherine GAGNON, Karim ZAGHIB
  • Publication number: 20230132005
    Abstract: The present technology relates to inorganic compounds having an argyrodite-type structure based on an alkali metal obtained by a preparation process comprising a step of grinding the sulfide of the alkali metal, the sulfate of the alkali metal, phosphorus pentasulfide and a halide of the alkali metal. Also described are electrode materials, electrodes, electrolytes comprising said inorganic compound having an argyrodite-type structure and their uses in electrochemical cells, for example, in electrochemical accumulators, particularly in all-solid-state batteries.
    Type: Application
    Filed: October 27, 2022
    Publication date: April 27, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Fabien NASSOY, Benoît FLEUTOT, Marc-André GIRARD, Steve DUCHESNE, Catherine GAGNON, Alexis PEREA, David ROZON, Sergey KRACHKOVSKIY
  • Publication number: 20230095475
    Abstract: A system and a method for reducing a risk of bacterial contamination in a water heater are disclosed. A bypass conduit is connected to cold water supply and hot water outlet conduits of the water heater with T-shaped fittings, the bypass conduit generally extending in a same horizontal plane as the fittings and running alongside a top surface of the water heater. A thermostatic mixing valve is integrated to the bypass conduit close to the fitting with the hot water outlet so that its mixed water outlet is connected to the fitting with the hot water and its cold water inlet is connected to the fitting with the cold water, its hot water inlet being blocked. The thermostatic mixing valve is adjusted to regulate the hot water temperature at the outlet of the system and to produce a thermosiphon loop in the system depending on whether there is extraction or no extraction of hot water from the water heater.
    Type: Application
    Filed: September 8, 2022
    Publication date: March 30, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Francois LAURENCELLE, Jonathan DESPRES, Serge GAUTHIER
  • Publication number: 20230094444
    Abstract: A method for producing an electrode material for a lithium-ion secondary battery. The method includes the following steps: (a) mixing components of a basic ingredient or active substance of electrode material and a conductive carbon material to obtain a conductive carbon material-composited material; (b) mixing the conductive carbon material-composited material and a surface layer-forming material; an (c) burning the mixture obtained at step (b) to obtain the electrode material. Also, a lithium-ion secondary battery including an electrode which includes the material.
    Type: Application
    Filed: November 28, 2022
    Publication date: March 30, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Vincent GARIEPY, Abdelbast GUERFI, Kazuma Hanai, Pierre HOVINGTON, Shinji Saito, Takehiko Sawai, Kazunori Urao, Karim ZAGHIB
  • Publication number: 20230064888
    Abstract: The present technology relates to a sulfur-containing polymer or organic compound for use in a positive electrode material, especially in lithium batteries. More specifically, the use of this sulfur-containing polymer or compound as an active electrode material makes it possible to combine sulfur and an active organic cathode material. The present technology also relates to the use of the sulfur-containing polymer or organic compound as defined herein as a solid polymer electrolyte (SPE) or as an additive for electrolyte, especially in lithium batteries.
    Type: Application
    Filed: August 25, 2022
    Publication date: March 2, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Rachel LÉVESQUE-BÉLANGER, Andrea PAOLELLA, Jean-Christophe DAIGLE, Basile COMMARIEU, Michel ARMAND, Karim ZAGHIB
  • Publication number: 20230060872
    Abstract: The present technology relates to the modification of the surface of an electrode comprising a thin layer, for example of 10 microns or less, of an inorganic compound (such as a ceramic) in a solid polymer, the inorganic compound being present in the thin layer at a concentration between about 40% and about 90% by weight. Also described are electrodes comprising the modified film, a component comprising the electrode and a solid electrolyte, and the electrochemical cells and accumulators comprising same.
    Type: Application
    Filed: February 12, 2021
    Publication date: March 2, 2023
    Applicant: HYDRO-QUÉBEC
    Inventors: Nicolas DELAPORTE, Gilles LAJOIE, Steve COLLIN-MARTIN, Ali DARWICHE, Chisu KIM, Karim ZAGHIB, Daniel CLÉMENT, Marie-Josée VIGEANT
  • Patent number: 11569506
    Abstract: This disclosure provides for Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds of the invention are obtained by a direct synthesis embodying a hydrothermal method.
    Type: Grant
    Filed: December 20, 2016
    Date of Patent: January 31, 2023
    Assignees: HYDRO-QUÉBEC, CIC ENERGIGUNE
    Inventors: Montse Galceran Mestres, Montse Casas-Cabanas, Abdelbast Guerfi, Michel Armand, Teofilo Rojo, Karim Zaghib, Andrea Paolella
  • Patent number: 11563209
    Abstract: This application describes a process for the preparation of carbon-coated particles, where the particles comprise an electrochemically active material. The process comprises the steps of emulsion polymerization, drying and thermally treating the polymer to obtain a nano-layer of carbon on the particles, where the carbon layer comprises fibers and nitrogen-containing polyaromatics have a graphene-like structure. The application also further relates to the particles produced by the method as well as to electrode materials, electrodes and electrochemical cells comprising the particles.
    Type: Grant
    Filed: June 30, 2017
    Date of Patent: January 24, 2023
    Assignees: HYDRO-QUEBEC, MURATA MANUFACTURING CO., LTD.
    Inventors: Jean-Christophe Daigle, Yuichiro Asakawa, Shinichi Uesaka, Karim Zaghib
  • Patent number: 11545668
    Abstract: A method for producing an electrode material for a lithium-ion secondary battery. The method includes the following steps: (a) mixing components of a basic ingredient or active substance of electrode material and a conductive carbon material to obtain a conductive carbon material-composited material; (b) mixing the conductive carbon material-composited material and a surface layer-forming material; an (c) burning the mixture obtained at step (b) to obtain the electrode material. Also, a lithium-ion secondary battery including an electrode which comprises the material.
    Type: Grant
    Filed: October 21, 2013
    Date of Patent: January 3, 2023
    Assignee: HYDRO-QUEBEC
    Inventors: Vincent Gariepy, Abdelbast Guerfi, Kazuma Hanai, Pierre Hovington, Shinji Saito, Takehiko Sawai, Kazunori Urao, Karim Zaghib
  • Publication number: 20220393146
    Abstract: Processes are described for the direct or indirect electrochemical alkaliation of an alkali metal deficient electrochemically active material. The processes include an electrolysis step either during the alkaliation of the alkali metal deficient electrochemically active material on an electrode current collector (direct) or during the regeneration of a reducing agent used for the alkaliation of the electrochemically active material (indirect).
    Type: Application
    Filed: November 13, 2020
    Publication date: December 8, 2022
    Applicant: HYDRO-QUÉBEC
    Inventors: Kamyab AMOUZEGAR, François LAROUCHE, Pascal CHAMPAGNE, Georges HOULACHI, Patrick BOUCHARD, Karim ZAGHIB
  • Patent number: 11513148
    Abstract: A method, a system and a tangible product and non-transitory computer program are provided to automatically identify electrical installations in an electrical distribution system that are likely to exhibit an electrical non-conformity (ENC). The method requires only electrical profiles collected from meters and IT tools, without the need for any other sub-metering equipment. The method includes the steps of recovering electrical profiles generated by the meters; applying algorithmic processing associated with indicators of an ENC on the profiles; and identifying electrical installations likely to exhibit an ENC, according to the indicators that have met their target conditions. The method may include the recovery of local meteorological data and nominal data related to the electrical installations to confirm or deny that the identified electrical installations are likely to be non-conforming.
    Type: Grant
    Filed: October 4, 2019
    Date of Patent: November 29, 2022
    Assignee: HYDRO-QUEBEC
    Inventors: Jean Carignan, Sylvain Gelinas, Alain Poulin
  • Patent number: 11469419
    Abstract: The present technology relates to a sulfur-containing polymer or organic compound for use in a positive electrode material, especially in lithium batteries. More specifically, the use of this sulfur-containing polymer or compound as an active electrode material makes it possible to combine sulfur and an active organic cathode material. The present technology also relates to the use of the sulfur-containing polymer or organic compound as defined herein as a solid polymer electrolyte (SPE) or as an additive for electrolyte, especially in lithium batteries.
    Type: Grant
    Filed: October 2, 2018
    Date of Patent: October 11, 2022
    Assignee: HYDRO-QUEBEC
    Inventors: Rachel Lévesque-Bélanger, Andrea Paolella, Jean-Christophe Daigle, Basile Commarieu, Michel Armand, Karim Zaghib
  • Patent number: 11453835
    Abstract: Polymers used as rolling lubricating agents, to compositions including said polymers, and to alkali metal films including the polymers or compositions on the surface(s) thereof. The use of said polymers and compositions is also described for strip-rolling alkali metals or alloys thereof in order to obtain thin films. Methods for producing said thin films, which are suitable for use in electrochemical cells, are also described. An improved lubricant according to formula I, which, for example, achieves enhanced conductivity, and/or enables the production of electrochemical cells having an improved life span in cycles.
    Type: Grant
    Filed: June 4, 2020
    Date of Patent: September 27, 2022
    Assignee: HYDRO-QUEBEC
    Inventors: Karim Zaghib, Michel Armand, Patrick Bouchard, Serge Verreault, Julie Hamel-Pâquet, Gabriel Girard
  • Patent number: RE49319
    Abstract: A lithium-ion secondary battery including positive and negative electrodes, a separator element, an electrical conductor element and a binder, wherein the positive electrode includes a lithium-containing metal phosphate compound coated with a carbon material having at least one phase selected from a graphene phase and an amorphous phase, and further includes carbon black and a fibrous carbon material and wherein the negative-electrode material includes a graphite carbon material having at least one carbon phase selected from a graphene phase and an amorphous phase, and further includes carbon black and a fibrous carbon material, and wherein the binder includes a water-soluble synthetic resin or a water-dispersible synthetic resin. The most preferred positive electrode includes LiFePO4, The most preferred negative electrode includes artificial graphite or graphitazable powder. The most preferred binder is carboxyl methyl cellulose further including a surface active agent.
    Type: Grant
    Filed: March 3, 2020
    Date of Patent: November 29, 2022
    Assignee: HYDRO-QUEBEC
    Inventors: Karim Zaghib, Shinji Saito, Abdelbast Guerfi, Takehiko Sawai, Kazunori Urao, Jun Nakagawa, Francis Barray, Joel Frechette