Patents Assigned to Hymo Corporation
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Patent number: 11840744Abstract: Provided are a method for recovering gold, in which gold is recovered from a solution containing a gold cyano complex using a crosslinked resin containing a vinyl amine unit, by which gold can be efficiently recovered from the solution not only in a case (A) where a concentration of the gold cyano complex in the solution is low but also in a case (B) where another metal is dissolved in the solution; a method for recovering gold, in which the crosslinked resin and the solution are brought into contact with each other to separate the crosslinked resin and the solution from each other, by which gold can be efficiently recovered from the solution not only in the case (A) but also in the case (B); and a gold recovery facility comprising: a container inside which the crosslinked resin is accommodated in a flowable manner; and a device which feeds the solution to the container, by which gold can be efficiently recovered from the solution not only in the case (A) but also in the case (B).Type: GrantFiled: June 22, 2020Date of Patent: December 12, 2023Assignee: HYMO CorporationInventors: Ryuichi Ansai, Fumi Oono, Satoshi Sakuma, Fumiaki Satou, Akihiro Ishii, Yasuharu Mori
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Patent number: 11459250Abstract: The purpose of the present invention is to provide a treatment method by which, even for wastewater with organic constituents constituting a large portion of organic wastewater as a whole and suspended solids (SS) and with a large negative charge ratio, organic nitrogen constituents and phosphorus compounds can be efficiently separated and collected and good-quality separated water can be obtained by reducing the quantity of SS, BOD, COD, and nitrogen constituents in the separated water. Provided is a treatment method for organic waste water, in which a flock is formed by adding a polymer flocculant to organic waste water with organic nitrogen constituent content in relation to suspended solids (SS) being 4-50%/SS and organic nitrogen constituent content being 250-50,000 mg/L, and thereafter, the flock is separated from the organic wastewater by solid-liquid separation.Type: GrantFiled: October 22, 2019Date of Patent: October 4, 2022Assignee: HYMO CorporationInventors: Hisanori Goto, Takayuki Kobayashi
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Patent number: 10385147Abstract: A method for efficiently producing polyvinylamine crosslinked polymer particles by simple operation without using an organic solvent is provided. In the present invention, polyvinylamine crosslinked polymer particles can be produced by performing suspension polymerization in salt water containing N-vinylcarboxylic acid amide and a polyvinyl compound in the presence of a dispersant to obtain particles of a polyvinyl carboxylic acid amide crosslinked polymer and subsequently hydrolyzing the polyvinyl carboxylic acid amide crosslinked polymer. Divinylbenzene is preferred as the polyvinyl compound. N-Vinylcarboxylic acid amide, acrylonitrile, and a polyvinyl compound may be used.Type: GrantFiled: May 26, 2015Date of Patent: August 20, 2019Assignee: Hymo CorporationInventor: Go Honda
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Patent number: 10364303Abstract: An iminodiacetic acid type chelate resin which can be easily and efficiently produced and which can efficiently adsorb and separate metal ions; and a method for producing the same are developed. The use of a chelate rein having a carboxymethyl group introduced into primary amino groups of the polyvinylamine crosslinked polymer particles can facilitate the efficient adsorption and separation of metal ions in water. The chelate resin can be obtained by a production method in which an N-vinyl carboxylic acid amide is suspension polymerized with a crosslinkable monomer in salt water in the presence of a dispersant thereby to obtain a polyvinyl carboxylic acid amide crosslinked polymer particles, and the obtained polyvinyl carboxylic acid amide crosslinked polymer is hydrolyzed to thereby introduce a carboxymethyl group into primary amino groups of the polyvinylamine crosslinked polymer particles.Type: GrantFiled: January 10, 2017Date of Patent: July 30, 2019Assignee: HYMO CorporationInventors: Aiko Suzuki, Go Honda
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Publication number: 20170275393Abstract: A method for efficiently producing polyvinylamine crosslinked polymer particles by simple operation without using an organic solvent is provided. In the present invention, polyvinylamine crosslinked polymer particles can be produced by performing suspension polymerization in salt water containing N-vinylcarboxylic acid amide and a polyvinyl compound in the presence of a dispersant to obtain particles of a polyvinyl carboxylic acid amide crosslinked polymer and subsequently hydrolyzing the polyvinyl carboxylic acid amide crosslinked polymer. Divinylbenzene is preferred as the polyvinyl compound. N-Vinylcarboxylic acid amide, acrylonitrile, and a polyvinyl compound may be used.Type: ApplicationFiled: May 26, 2015Publication date: September 28, 2017Applicant: HYMO CorporationInventor: Go HONDA
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Patent number: 9233861Abstract: A water-in-oil emulsion is a product form having many practical advantages. A vinylamine-based macromolecule having specific effects as papermaking chemicals and a flocculant is provided in the form of a water-in-oil emulsion having good storage stability and high performance as a flocculation treatment agent. Disclosed is a flocculation treatment agent including a water-in-oil emulsion of a water-soluble macromolecule that is produced by subjecting a water-in-oil emulsion of an aqueous poly-N-vinylcarboxylic acid amide solution coexisting with a polyoxyalkylene alkyl ether to hydrolysis in the presence of an acid or a base. Preferably, the polyoxyalkylene alkyl ether is added before the hydrolysis reaction.Type: GrantFiled: December 13, 2012Date of Patent: January 12, 2016Assignee: HYMO CORPORATIONInventors: Shohei Mitsui, Kazuoki Takeo, Shogo Wakatsuki, Atsushi Yonekura
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Publication number: 20140243458Abstract: Provided is a powdery hydrophilic polymer by aggregating a hydrophilic polymer comprising a water-in-oil emulsion in a liquid form by emulsion breaking and granulating the aggregate, followed by drying. As an emulsion breaker, ionic surfactants, nonionic surfactants having an HLB value of 11 to 20, or oil-soluble polymer compounds having a hydrophilic group and a hydrophobic group can be used. The powdery hydrophilic polymer obtained by this method exhibits excellent effects as a flocculating agent.Type: ApplicationFiled: January 13, 2012Publication date: August 28, 2014Applicant: HYMO CORPORATIONInventors: Manabu Tonami, Kiyoshi Aoyama, Kazuyuki Hirata
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Patent number: 8394360Abstract: The present invention provides an additive for a hair cosmetic preparation and a hair cosmetic preparation containing the additive that can give a supple feel to the finished hair. The additive for a hair cosmetic preparation contains a graft copolymer obtainable by graft-copolymerizing a cationic water-soluble monomer and a nonionic water-soluble monomer in an aqueous solution containing either one or both of a natural polymer and a natural polymer derivative that have an OH group.Type: GrantFiled: August 6, 2009Date of Patent: March 12, 2013Assignee: Hymo CorporationInventors: Aiko Kato, Hisao Takeda
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Publication number: 20120234669Abstract: This invention relates to a precast gel for electrophoresis comprising a support filled with an aqueous gel prepared by polymerizing an aqueous solution comprising a radically polymerizable monomer, a crosslinkable monomer, a buffer, a redox initiator comprising an oxidizer/reducer, and a photo sensitizer and having a pH level of 6.0 to 7.5 via light application. The slab gel for electrophoresis of the present invention can produce a precast gel for electrophoresis within a shorter period of time and in an easier manner than is possible with conventional techniques. Accordingly, the present invention enables production of a high-quality precast gel for electrophoresis in terms of productivity, cost, and quality, and the industrial applicability thereof is remarkable.Type: ApplicationFiled: May 31, 2012Publication date: September 20, 2012Applicant: HYMO CORPORATIONInventors: Kazuhisa SUZUKI, Mika SUZUKI, Yukiko MINEGISHI
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Publication number: 20110056833Abstract: This invention relates to a precast gel for electrophoresis comprising a support filled with an aqueous gel prepared by polymerizing an aqueous solution comprising a radically polymerizable monomer, a crosslinkable monomer, a buffer, a redox initiator comprising an oxidizer/reducer, and a photo sensitizer and having a pH level of 6.0 to 7.5 via light application. The slab gel for electrophoresis of the present invention can produce a precast gel for electrophoresis within a shorter period of time and in an easier manner than is possible with conventional techniques. Accordingly, the present invention enables production of a high-quality precast gel for electrophoresis in terms of productivity, cost, and quality, and the industrial applicability thereof is remarkable.Type: ApplicationFiled: July 8, 2008Publication date: March 10, 2011Applicant: HYMO CORPORATIONInventors: Kazuhisa Suzuki, Mika Suzuki, Yukiko Minegishi
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Patent number: 7745529Abstract: A flocculent composition and a method for manufacturing the same are provided. The flocculent composition has an excellent ability to adhere to suspended particles, does not cause an increase in the viscosity of sludge, provides good drainage during mechanical dewatering to allow a reduction in the water content of a cake, and is applicable to various types of sludge. These characteristics are obtained by utilizing advantages of a crosslinking water-soluble polymer and a linear water-soluble polymer and changing the compounding ratio of the crosslinking water-soluble polymer to the linear water-soluble polymer according to the form of the size distribution of sludge particles. The flocculent composition includes a vinyl crosslinking water-soluble polymer (A) having a charge inclusion ratio of 20% or more and a vinyl linear water-soluble polymer (B) having a charge inclusion ratio of 5% or more and less than 20%.Type: GrantFiled: January 30, 2009Date of Patent: June 29, 2010Assignee: HYMO CorporationInventors: Ryousuke Yonemoto, Syougo Wakatuki
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Water-soluble polymers reduced in molecular weight, process for production thereof and usage thereof
Patent number: 7732527Abstract: The invention relates to water-soluble polymers reduced in molecular weight, a process for production of the same, and usage thereof.Type: GrantFiled: February 19, 2004Date of Patent: June 8, 2010Assignee: Hymo CorporationInventor: Motosuke Ono -
Publication number: 20090137720Abstract: A flocculent composition and a method for manufacturing the same are provided. The flocculent composition has an excellent ability to adhere to suspended particles, does not cause an increase in the viscosity of sludge, provides good drainage during mechanical dewatering to allow a reduction in the water content of a cake, and is applicable to various types of sludge. These characteristics are obtained by utilizing advantages of a crosslinking water-soluble polymer and a linear water-soluble polymer and changing the compounding ratio of the crosslinking water-soluble polymer to the linear water-soluble polymer according to the form of the size distribution of sludge particles. The flocculent composition includes a vinyl polymer-type crosslinking water-soluble polymer (A) having a charge inclusion ratio of 20% or more and a vinyl polymer-type linear water-soluble polymer (B) having a charge inclusion ratio of 5% or more and less than 20%.Type: ApplicationFiled: January 30, 2009Publication date: May 28, 2009Applicant: HYMO CORPORATIONInventors: Ryousuke Yonemoto, Syougo Wakatuki
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Patent number: 7300545Abstract: A water-soluble polymer dispersion, process for producing the same and a method of use therefor. In particular, the water-soluble polymer dispersion is one comprising water-soluble polymer fine particles of 100 ?m or less diameter having at least one ionic property selected from among cationic, amphoteric, nonionic and anionic properties together with a polyalkyleneimine and/or a product of polyalkyleneimine modification wherein according to necessity an appropriate amount of water-soluble inorganic salt is incorporated. The provided process enables easily performing the production in dispersed form by means of production facilities of low cost. The obtained water-soluble polymer dispersion is excellent in storage stability and exhibits satisfactory fluidity and solubility so as to enable use in papermaking raw material pretreatments added to papermaking raw materials prior to machine operation and also for enhancement of freeness, increase of sizing degree and enhancement of yield.Type: GrantFiled: February 25, 2003Date of Patent: November 27, 2007Assignee: Hymo CorporationInventors: Takumi Ohara, Emiko Odaka, Ryousuke Yonemoto
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Patent number: 7250462Abstract: The invention relates to an amphoteric water-soluble polymer dispersion containing polymer particles with particle diameters of 100 ?m or smaller and produced by dispersion-copolymerization of a monomer mixture comprising a methacrylate monomer containing a quaternary ammonium salt group, an acrylate monomer containing a quaternary ammonium salt group, an anionic monomer, and a (meth)acrylamide in respectively ratios specified in an aqueous salt solution in the presence of a polymer dispersant soluble in the aqueous salt solution and the invention also relates to a dewatering agent for organic sludge, a pretreatment agent or yield improver for paper making raw materials, and/or a drainage properties-enhancing agent using the amphoteric water-soluble polymer.Type: GrantFiled: May 28, 2002Date of Patent: July 31, 2007Assignee: Hymo CorporationInventors: Isamu Kubota, Hiroyuki Koshio
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Patent number: 6726821Abstract: A precast acrylamide electrophoresis gel is disclosed, which includes a gel buffer solution containing either Tris and glycine or Tris, glycine and any one or more than two of ampholytes, and a monobasic acid, titrated to a specified pH range. With the gels constituted as stated earlier, proteins can be successfully subjected to electrophoresis using the commonly available Laemmli's buffer system, while the DNA can be also satisfactorily run on the gel using the electrophoresis electrode solution containing Tris, chelating agent, and any one acid of acetic acid, phosphoric acid and boric acid. In either of protein and DNA analyses, the gels even after stored under refrigeration more than six months are fully comparable in resolution and clearness of electrophoretic pattern to the gels just after being prepared.Type: GrantFiled: August 2, 2001Date of Patent: April 27, 2004Assignee: Hymo CorporationInventor: Mika Suzuki
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Patent number: 6669815Abstract: There is provided a treating agent for a sheet surface comprising a graft copolymer composed of a back bone polymer and branch polymer, either of which is a polymer having vinyl alcohol units, and the other of which is a polymer having cationic groups, the treating agent is applied onto a pulp sheet or plastic sheet, and the coated sheet is used in ink jet printing. Cationic groups are introduced by graft copolymerization using di(meth)allylamine-based and/or (meth)acryl-based monomer. Alternatively, the graft copolymer of the present invention is obtained by grafting N-vinylcarboxylic acid amide monomer followed by hydrolysis thereof. A formula weight ratio of vinylalcohol units and the introduced cationic groups of 1:20 to 2:1 is preferable in terms of balanced performance.Type: GrantFiled: March 13, 2000Date of Patent: December 30, 2003Assignee: Hymo CorporationInventors: Toshiaki Sugiyama, Motosuke Ono, Osamu Kamada
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Patent number: 6187853Abstract: A process for producing a water-soluble polymer dispersion comprising polymerizing water-soluble monomers having double bonds in an aqueous salt solution that dissolves the monomers but does not dissolve the formed polymer while stirring in the presence of a dispersant composed of a polymer electrolyte soluble in this aqueous salt solution to obtain fine polymer particles dispersed in the aqueous salt solution, characterized by adding at least one viscosity-increase suppressor selected from the group consisting of: (A) a polyvalent carboxylic acid or a salt thereof, (B) a polyvalent phenol, (C) a cyclic compound containing a hydroxyl group and a carboxyl group or a salt thereof, (D) gluconic acid or a salt thereof, (E) a reaction product obtained by reacting methoxyhydroquinone and/or (meth)acrylic cationic monomer with a compound that generates radicals in an oxidizing atmosphere, (F) a reaction product obtained by reacting (meth)acrylic cationic polymer with a compound that generates radicals in an oxidizinType: GrantFiled: July 6, 1999Date of Patent: February 13, 2001Assignee: Hymo CorporationInventors: Hisao Takeda, Takumi Ohara, Mika Suzuki, Kenji Sakai
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Patent number: 5708071Abstract: A storage stable, flowable aqueous dispersion of an amphoteric water-soluble polymer with good handling as well as a method of manufacturing the same are provided. Such an aqueous dispersion can be effectively used for flocculating and/or dehydrating sludge, or for separating and treating oil-containing industrial waste water, as a drainage aid, a retention aid, or recovering substances from white water in the papermaking process. The aqueous dispersion of an amphoteric water-soluble polymer is obtained by polymerizing a mixture of monomers comprising a specific cationic monomer and an anionic monomer as essential components wish stirring in an aqueous salt solution incapable of dissolving the produced polymer and in the presence of a polymer electrolyte dispersant soluble in said aqueous salt solution.Type: GrantFiled: December 12, 1995Date of Patent: January 13, 1998Assignee: Hymo CorporationInventor: Hisao Takeda
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Patent number: 5587415Abstract: A water-soluble cationic (co)polymer dispersion prepared by the polymerization of a specified cationic quaternary monomer, which is obtained by quaternization by use of an alkyl halide, optionally with another cationic monomer and/or (meth)acrylamide, the polymerization being carried out in a salt solution which does not dissolve the resulting (co)polymer, and in the presence of a specific cationic polymer dispersant which is soluble in the salt solution, and its use as a flocculant or a paper chemical are provided.Type: GrantFiled: July 14, 1995Date of Patent: December 24, 1996Assignee: HYMO CorporationInventor: Hisao Takeda