Abstract: The present invention relates to a slurry hydroconversion process of a heavy oil feedstock (101) comprising: (a) preparing a conditioned feedstock (103) by mixing said feedstock with a catalyst precursor formulation (104) so that a colloidal or molecular catalyst is formed when it reacts with sulfur, said catalyst precursor formulation (104) comprising a catalyst precursor composition (105) comprising Mo, an organic additive (102) comprising a carboxylic acid function and/or an ester function and/or an acid anhydride function, and a molar ratio organic additive (102)/Mo from formulation (4) ranging between 0.1:1 and 20:1; (b) heating said conditioned feedstock; (c) introducing the heated conditioned feedstock (106) into at least one slurry bed reactor and operating said reactor in the presence of hydrogen and at hydroconversion conditions to produce an upgraded material (107), the colloidal or molecular catalyst being formed during step (b) and/or (c).

Abstract: A hydroconversion process of a heavy oil feedstock including (a) preparing a first conditioned feedstock (103) by blending heavy oil feedstock (101) with an organic chemical compound (102) containing at least one carboxylic acid function and/or at least one ester function and/or an acid anhydride function; (b) preparing a second conditioned feedstock (105) by mixing a catalyst precursor composition (104) with the first conditioned feedstock in a manner such that a colloidal or molecular catalyst is formed when it reacts with sulfur; (c) heating the second conditioned feedstock in at least a preheating device; (d) introducing the heated second conditioned feedstock (106) into at least one hybrid ebullated-entrained bed reactor containing a hydroconversion porous supported catalyst and operating the reactor in the presence of hydrogen and at hydroconversion conditions to produce an upgraded material (107), the colloidal or molecular catalyst being formed during step (c) and/or (d).

Abstract: The present invention relates to a hydroconversion process of a heavy oil feedstock comprising: (a) preparing a conditioned feedstock (103) by mixing said heavy oil feedstock (101) with a catalyst precursor formulation (104) so that a colloidal or molecular catalyst is formed when it reacts with sulfur, said catalyst precursor formulation (104) comprising a catalyst precursor composition (105) comprising Mo, an organic additive (102) comprising a carboxylic acid function and/or an ester function and/or an acid anhydride function, and a molar ratio organic additive (102)/Mo from formulation (104) ranging between 0.

Abstract: A process for preparing a catalyst comprising an active nickel phase and an alumina support, said catalyst comprising between 1% and 50% by weight of elemental nickel relative to the total weight of the catalyst, the nickel being distributed both over a crust at the periphery of the support, and at the core of the support, which process comprises the following steps: a) said support is impregnated with a volume V1 of a hexanol solution of between 0.2 and 0.8 times the total pore volume TPV of said support in order to obtain an impregnated support; b) the impregnated support obtained at the end of step a) is impregnated with a solution comprising a precursor of the nickel active phase in order to obtain a catalyst precursor; c) the catalyst precursor obtained at the end of step b) is dried at a temperature below 250° C.

Abstract: Process for preparing a catalyst comprising a nickel active phase and an alumina support, said catalyst comprising between 1% and 50% by weight of elemental nickel relative to the total weight of the catalyst, the nickel being distributed both over a crust at the periphery of the support, and at the core of the support, which process comprises the following steps: a) said support is impregnated with a volume V1 of a heptanol solution of between 0.2 and 0.8 times the total pore volume TPV of said support in order to obtain an impregnated support; b) the impregnated support obtained at the end of step a) is impregnated with a solution comprising a precursor of the nickel active phase in order to obtain a catalyst precursor; c) the catalyst precursor obtained at the end of step b) is dried at a temperature below 250° C.

Abstract: The present invention relates to a process for producing olefins from a hydrocarbon feedstock 11 having a sulfur content of at least 0.1 weight %, an initial boiling point of at least 180° C. and a final boiling point of at least 600° C.

Abstract: A heat storage and recovery system and process includes at least one cylindrical external wall, at least one first volume, at least one second volume and at least two fluid injection/withdrawal devices. The first and second volumes are separated by at least one heat storage system comprising at least one bed of heat storage particles. Furthermore, the storage system and the first and second volumes extend substantially over the entire axial length of the cylindrical external wall. The longitudinal axis of the said cylindrical external wall is horizontal. A system and a process for the storage and recovery of energy by compressed gas include such a heat storage means.

Abstract: A subject matter of the invention is a process for the hydrotreating of a hydrocarbon feedstock having a distillation range of between 150° C. and 600° C., so as to obtain a hydrotreated effluent, said process comprising the following stages: a) said hydrocarbon feedstock is brought into contact, in the presence of hydrogen, with at least one first catalyst occupying a volume V1 and comprising a support based on alumina or silica or silica-alumina and an active phase consisting of nickel and molybdenum, b) the effluent obtained in stage a) is brought into contact, in the presence of hydrogen, with at least one second catalyst occupying a volume V2 and comprising a support based on alumina or silica or silica-alumina and an active phase consisting of nickel, molybdenum and tungsten, and phosphorus, the distribution of the volumes V1/V2 being of between 50% vol/50% vol and 90% vol/10% vol respectively.

Abstract: The present invention relates to a slurry hydroconversion process of a heavy oil feedstock comprising: (a) preparing a first conditioned feedstock (103) by blending said heavy oil feedstock (101) with an organic chemical compound (102) comprising at least one carboxylic acid function and/or at least one ester function and/or an acid anhydride function; (b) preparing a second conditioned feedstock (105) by mixing a catalyst precursor composition (104) with said first conditioned feedstock so that a colloidal or molecular catalyst is formed when it reacts with sulfur; (c) heating the second conditioned feedstock in at least one preheating device; (d) introducing the heated second conditioned feedstock (106) into at least one slurry bed reactor and operating said slurry bed reactor in the presence of hydrogen and at hydroconversion conditions to produce an upgraded material (107), the colloidal or molecular catalyst being formed during step (c) and/or (d).

Abstract: The present invention relates to a gas/liquid reactor for the oligomerization of gaseous ethylene, comprising a central pipe which delimits inside the reactor chamber a central zone allowing a descending flow and an outer zone allowing an ascending flow, thus making it possible to increase the time of travel of the injected gas bubbles in the liquid phase, without increasing the volume of the liquid phase and thus the volume of the reactor.

Abstract: Nickel and copper catalyst, and an alumina support: nickel distributed both in the core of and on a crust at the periphery of the support, crust thickness being 2% to 15% of catalyst diameter; nickel density ratio between the crust and the core greater than 3; crust contains more than 25% by weight of nickel element relative to total weight of nickel in the catalyst; mole ratio between nickel and copper is 0.5 to 5, at least one portion of nickel and copper is a nickel-copper alloy; nickel content in the nickel-copper alloy is 0.5% to 15% by weight of nickel element relative to total weight of the catalyst; size of the nickel particles in the catalyst is less than 7 nm.

Abstract: Catalyst comprising a nickel-based active phase and an alumina support, characterized in that: the nickel is distributed both on a crust at the periphery of the support, and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst; the nickel density ratio between the crust and the core is strictly greater than 3; said crust comprises between 40% and 80% by weight of nickel element relative to the total weight of nickel contained in the catalyst; the size of the nickel particles in the catalyst is less than 7 nm.

Abstract: The present invention relates to an absorbent composition for absorbing the carbon dioxide contained in a gaseous effluent comprising the combination of a base B or of a mixture of bases B of carbonate, hydrogen carbonate or hydroxide type with at least one unsaturated heterocyclic organic compound R(NH)n wherein the radical R is an alicyclic, monoaromatic or polyaromatic, or heterocyclic group having at least one nitrogen atom, and n is between 1 and 20, in an aqueous solvent Z and/or the product obtained by reaction of said base B or of said mixture of bases B with said compound R(NH)n in said aqueous solvent Z. The invention also relates to a process to capturing the CO2 in a gaseous effluent using said composition.

Abstract: The invention relates to a process for depolymerization of a polyester feedstock, comprising: a) conditioning of the feedstock using a means for at least partially melting the feedstock and at least one mixer, which are fed with the feedstock and a diol stream, with a ratio by weight between the diol stream and the feedstock of between 0.01 and 6.00, the volume degree of dilution with diol in each mixer being between 3% and 70%; b) depolymerization of the polyester feedstock at 150-300° C., the ratio by weight between the diol and the diester in step b) being adjusted between 0.3 and 8.0; c) optionally, the separation of the diol, at a temperature of between 60 and 250° C. and a pressure lower than that of step b).

Abstract: The present invention relates to a process for depolymerization of a polyester feedstock comprising PET, comprising: a) a step for conditioning the polyester feedstock, to produce a conditioned feedstock stream; b) a step of depolymerization of the conditioned feedstock stream, at a temperature of between 150 and 300° C., in the presence of diol with a ratio by weight between the diol and the diester in the feedstock of between 0.3 and 8.0, to produce a reaction effluent; c) a step of separation of the diol from the reaction effluent, to produce at least a liquid monomers effluent; d) a step of separation of the liquid monomers effluent into a heavy impurities effluent and a prepurified monomers effluent; and e) a step of purification of the prepurified monomers effluent, comprising a substep e1) of adsorption at a temperature of between 50 and 200° C. and a crystallization substep e2), and producing at least one decolourized purified diester monomer effluent.

Abstract: A process for the production of a terephthalate polyester, containing a stage a) for preparing an esterification feedstock containing at least one mixing section fed with at least one terephthalic acid feedstock and one diester monomer feedstock, where the ratio of the total number of moles of diol units with respect to the total number of moles of terephthalate units introduced into the mixing section is between 1.0 and 2.0, the mixing section being operated at a temperature between 25° C. and 250° C. and at a pressure greater than or equal to 0.1 MPa, an esterification stage b) to produce at least one reaction effluent and one aqueous effluent, a polycondensation stage c) to obtain at least the terephthalate polyester and an effluent containing at least one diol monomer, and a stage d) of treatment of the diols to obtain a purified diol stream.

Abstract: Catalyst comprising nickel and sulfur on an alumina support, said catalyst being characterized in that: the nickel is distributed both on a crust at the periphery of the support, and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst; the nickel density ratio between the crust and the core is strictly greater than 3; said crust comprises more than 25% by weight of nickel element relative to the total weight of nickel contained in the catalyst, the size of the nickel particles in the catalyst, measured in oxide form, is between 7 and 25 nm.

Abstract: The present invention concerns a CLC method and plant for a hydrocarbon feedstock, comprising combustion of said hydrocarbon feedstock (8) on contact with an oxygen carrier in form of particles in a reduction zone (R0), and oxidation of the oxygen carrier from reduction zone (R0) on contact with an oxidizing gas, preferably air, in an oxidation zone. According to the invention, gaseous oxygen is released by the oxygen carrier in a sealing device (S1) operating in a dual fluidized bed and positioned in the path of said carrier from the oxidation zone to the combustion zone, and it is mixed with part of the combustion fumes intended to be recycled to the reduction zone. The gaseous oxygen then enables combustion of the residual unburned species that may be contained in the combustion fumes and/or it participates in the combustion of the hydrocarbon feedstock in the reduction zone.

Abstract: A process for the treatment of a gasoline containing sulfur compounds and olefins includes the following stages: a) hydrodesulfurization in the presence of a catalyst having an oxide support and an active phase having a metal from group VIB and a metal from group VIII, b) hydrodesulfurization at a higher temperature than that of stage a) and in the presence of a catalyst having an oxide support and an active phase with at least one metal from group VIII, c) separation of H2S formed, d) hydrodesulfurization at a low hydrogen/feedstock ratio and in the presence of a hydrodesulfurization catalyst having an oxide support and an active phase having a metal from group VIB and a metal from group VIII or an active phase with at least one metal from group VIII, and e) further separation of H2S formed.

Abstract: The present invention is a tank for storing pressurized gas. The tank comprises at least one tubular element (1) having a wall comprising a layer of prestressed concrete (6), at least one circumferential mechanical reinforcing layer (8), at least one axial mechanical reinforcing layer (7) and a sealing layer (5). The concrete from which the layer of prestressed concrete is made is chosen from ultra high performance fiber-reinforced concretes.