Abstract: The present invention relates to apparatus, compositions and methods of fabricating high performance thin-film batteries on metallic substrates, polymeric substrates, or doped or undoped silicon substrates by fabricating an appropriate barrier layer composed, for example, of barrier sublayers between the substrate and the battery part of the present invention thereby separating these two parts chemically during the entire battery fabrication process as well as during any operation and storage of the electrochemical apparatus during its entire lifetime. In a preferred embodiment of the present invention thin-film batteries fabricated onto a thin, flexible stainless steel foil substrate using an appropriate barrier layer that is composed of barrier sublayers have uncompromised electrochemical performance compared to thin-film batteries fabricated onto ceramic substrates when using a 700° C. post-deposition anneal process for a LiCoO2 positive cathode.

Abstract: The present invention relates to apparatus, compositions and methods of fabricating high performance thin-film batteries on metallic substrates, polymeric substrates, or doped or undoped silicon substrates by fabricating an appropriate barrier layer composed, for example, of barrier sublayers between the substrate and the battery part of the present invention thereby separating these two parts chemically during the entire battery fabrication process as well as during any operation and storage of the electrochemical apparatus during its entire lifetime. In a preferred embodiment of the present invention thin-film batteries fabricated onto a thin, flexible stainless steel foil substrate using an appropriate barrier layer that is composed of barrier sublayers have uncompromised electrochemical performance compared to thin-film batteries fabricated onto ceramic substrates when using a 700° C. post-deposition anneal process for a LiCoO2 positive cathode.

Abstract: In accordance with the present invention, deposition of LiCoO2 layers in a pulsed-dc physical vapor deposition process is presented. Such a deposition can provide a low-temperature, high deposition rate deposition of a crystalline layer of LiCoO2 with a desired (101) or (003) orientation. Some embodiments of the deposition addresses the need for high rate deposition of LiCoO2 films, which can be utilized as the cathode layer in a solid state rechargeable Li battery. Embodiments of the process according to the present invention can eliminate the high temperature (>700° C.) anneal step that is conventionally needed to crystallize the LiCoO2 layer. Some embodiments of the process can improve a battery utilizing the LiCoO2 layer by utilizing a rapid thermal anneal process with short ramp rates.

Abstract: The present invention relates to flexible thin film batteries on semiconducting surface or the conductive or insulating packaging surface of a semiconductor device and methods of constructing such batteries. Electrochemical devices may be glued to a semiconducting surface or the conductive or insulating packaging surface of a semiconductor device or deposited directly thereon. The invention also relates to flexible thin film batteries on flexible printed circuit boards where the electrochemical devices may also be glued or deposited on the flexible printed circuit board.

Abstract: The present invention relates to the field of motion/movement sensors, detectors, and/or monitors, as well as other types of sensors. In particular, the present invention may provide, for example, a large pulsed output voltage in response to very low (or slow) sensed movement or environment changes, such as, temperature, pressure, and energy. The present invention relates, for example, to other available sensors and may provide an output high enough to turn on related processing circuitry from an “OFF” state. The present invention relates, among other things, to sensing various events via, for example, axially poled homopolymer polyvinyladine fluoride (PVDF) or other piezoelectric materials.

Abstract: An electrochemical device is claimed and disclosed wherein certain embodiments have a cathode greater than about 4 ?m and less than about 200 ?m thick; a thin electrolyte less than about 10 ?m thick; and an anode less than about 30 ?m thick. Another claimed and disclosed electrochemical device includes a cathode greater than about 0.5 ?m and less than about 200 ?m thick; a thin electrolyte less than about 10 ?m thick; and an anode less than about 30 ?m thick, wherein the cathode is fabricated by a non-vapor phase deposition method. The electrochemical device may also include a substrate, a current collector, an anode current collector, encapsulation and a moderating layer.

Abstract: In accordance with the present invention, deposition of LiCoO2 layers in a pulsed-dc physical vapor deposition process is presented. Such a deposition can provide a low-temperature, high deposition rate deposition of a crystalline layer of LiCoO2 with a desired (101) or (003) orientation. Some embodiments of the deposition addresses the need for high rate deposition of LiCoO2 films, which can be utilized as the cathode layer in a solid state rechargeable Li battery. Embodiments of the process according to the present invention can eliminate the high temperature (>700° C.) anneal step that is conventionally needed to crystallize the LiCoO2 layer. Some embodiments of the process can improve a battery utilizing the LiCoO2 layer by utilizing a rapid thermal anneal process with short ramp rates.

Abstract: The present invention relates to the field of battery and capacitor charging. In particular, the present invention provides pulsed current charging using changes, regardless of polarity, in the local energy environment to obtain power. The present invention relates, for example, to ambient energy charging thin film batteries, other batteries, or capacitors, via, for example, polyvinyladine fluoride homopolymer (PVDF), PVDF bi-axially poled, or other piezoelectric materials. Ambient energy may be defined as any change in energy within the local environment. Charging can be accomplished with, and is not limited to, positive or negative changes of the following energy types: thermal; visible light, including infrared and ultraviolet; mechanical motion or impact; triboelectric, including airflow or physical contact; movement in relation to a gravitational plane (increase or decrease in gravitational potential energy); and radio frequency (RF) electromagnetic energy, regardless of specific frequency.

Abstract: The present invention relates to the field of motion/movement sensors, detectors, and/or monitors, as well as other types of sensors. In particular, the present invention may provide, for example, a large pulsed output voltage in response to very low (or slow) sensed movement or environment changes, such as, temperature, pressure, and energy. The present invention relates, for example, to other available sensors and may provide an output high enough to turn on related processing circuitry from an “OFF” state. The present invention relates, among other things, to sensing various events via, for example, axially poled homopolymer polyvinyladine fluoride (PVDF) or other piezoelectric materials.

Abstract: The present invention relates to the field of battery and capacitor charging. In particular, the present invention provides pulsed current charging using changes, regardless of polarity, in the local energy environment to obtain power. The present invention relates, for example, to ambient energy charging thin film batteries, other batteries, or capacitors, via, for example, polyvinyladine fluoride homopolymer (PVDF), PVDF bi-axially poled, or other piezoelectric materials. Ambient energy may be defined as any change in energy within the local environment. Charging can be accomplished with, and is not limited to, positive or negative changes of the following energy types: thermal; visible light, including infrared and ultraviolet; mechanical motion or impact; triboelectric, including airflow or physical contact; movement in relation to a gravitational plane (increase or decrease in gravitational potential energy); and radio frequency (RF) electromagnetic energy, regardless of specific frequency.

Abstract: The present invention relates to the field of motion/movement sensors, detectors, and/or monitors, as well as other types of sensors. In particular, the present invention may provide, for example, a large pulsed output voltage in response to very low (or slow) sensed movement or environment changes, such as, temperature, pressure, and energy. The present invention relates, for example, to other available sensors and may provide an output high enough to turn on related processing circuitry from an “OFF” state. The present invention relates, among other things, to sensing various events via, for example, axially poled homopolymer polyvinyladine fluoride (PVDF) or other piezoelectric materials.

Abstract: A novel method for production of and an apparatus for an encapsulated solid-state electrochemical device is disclosed. The present invention provides for electrical devices, such as, for example, thin-film batteries with sensitive chemistries that can survive environmental exposure while providing external electrical contact to the internal cell chemistry. The method of packaging of the present invention may include bonding one or more protective multi-layer laminates to the environmentally sensitive surfaces of an electronic device. The present invention may provide the advantage of avoiding entrapped air beneath the laminates.