Abstract: A process of making an electrochromic or an electrolytic film by Ultrasonic Spray Pyrolysis (USP) deposition on a substrate comprising: mixing a surfactant to an aqueous precursor solution comprising an electrochromic component or an electrolytic component to provide a spray solution; introducing the spray solution into an ultrasonic spray deposition nozzle at a constant flow rate between 0.1 mL/min and 2 mL/min and applying an ultrasonic frequency between 80 and 120 kHz to generate atomized droplets of the precursor solution; entraining the atomized droplets with a controlled jet of air as gas carrier at a pressure between 0.50 to 2.0 psi, onto a pre-heated substrate at a temperature of 200 to 450° C.; thermally converting the atomized droplets when depositing onto the pre-heated substrate to generate an electrochromic or an electrolytic film.
Type:
Grant
Filed:
December 11, 2015
Date of Patent:
April 9, 2019
Assignees:
UNIVERSITE DE LIEGE, INISMA
Inventors:
Rudi Cloots, Catherine Henrist, Jessica Denayer, Anthony Maho, Francis Cambier, Véronique Lardot, Geoffroy Bister, Philippe Aubry
Abstract: A process of making an electrochromic or an electrolytic film by Ultrasonic Spray Pyrolysis (USP) deposition on a substrate comprising: mixing a surfactant to an aqueous precursor solution comprising an electrochromic component or an electrolytic component to provide a spray solution; introducing the spray solution into an ultrasonic spray deposition nozzle at a constant flow rate between 0.1 mL/min and 2 mL/min and applying an ultrasonic frequency between 80 and 120 kHz to generate atomized droplets of the precursor solution; entraining the atomized droplets with a controlled jet of air as gas carrier at a pressure between 0.50 to 2.0 psi, onto a pre-heated substrate at a temperature of 200 to 450° C.; thermally converting the atomized droplets when depositing onto the pre-heated substrate to generate an electrochromic or an electrolytic film.
Type:
Application
Filed:
December 11, 2015
Publication date:
December 21, 2017
Applicants:
UNIVERSITE DE LIEGE, INISMa
Inventors:
Rudi CLOOTS, Catherine HENRIST, Jessica DENAYER, Anthony MAHO, Francis CAMBIER, Véronique LARDOT, Geoffroy BISTER, Philippe AUBRY