Abstract: The invention discloses a method for selectively introducing carbonyl groups into polymers by oxygenation of double C?C bonds of polymers with the aid of nitrous oxide (N2O) at a temperature comprised between 50 and 350° C. and a pressure of N2O of from 0.01 to 100 atmospheres. The introduction of an insignificant amount of C?O groups allows one to modify the physico-chemical properties of a polymer, with its molecular weight and molecular-weight distribution preserved. Deeper oxygenation results in controlled cleavage of polymer macromolecules and makes it possible to produce oxygen-containing oligomers having a desired molecular weight.

Abstract: The invention relates to a method for producing monocyclic ketones C7–C20. The method of patent protection sought is based on the oxidation reaction of monocyclic alkenes C7–C20 into corresponding monocyclic ketones with nitrous oxide or a mixture thereof with inert gas. The process proceeds at a temperature ranging from 20 to 350° C. and a pressure of the nitrous oxide ranging from 0.01 to 100 atm. The process provides a high selectivity involving the target product, blast-resistant work operations and is promising for industrial use.