Abstract: To reduce the concentration of methyl tert-butyl ether (MTBE) or tert-amyl methyl ether (TAME) in an aquifer polluted by these ethers, a new mineral support for fixing bacteria, and in particular Mycobacterium austroafricanum I-2562, said mineral support comprising perlite, is used in a biobarrier- or biofilter-type process.
Type:
Grant
Filed:
June 2, 2004
Date of Patent:
May 6, 2008
Assignee:
Institute Francais du Petrole
Inventors:
Darwin Lyew, Francoise Fayolle, Serge Guiot, Frederic Monot
Abstract: Described are a reactor for carrying out a chemical conversion process in a catalytic bed with mechanism for supplying heat integrated into the reactor, and with a very compact reaction zone, combined with efficient use of the catalyst, and a process for converting a feed, such as a hydrocarbon feed, undergoing an endothermic reaction using the disclosed reactor.
Type:
Grant
Filed:
May 30, 2006
Date of Patent:
April 15, 2008
Assignee:
Institute Francais du Petrole
Inventors:
Eric Lenglet, Nicolas Boudet, Frédéric Hoffman
Abstract: A porous inorganic membrane comprises at least one inorganic phase having separating properties. Said membrane has a carbon content representing 0.05% to 25% by weight with respect to the mass of said inorganic phase and is selective to non-condensable gases. It is obtained by means of a selectivation treatment of a porous carbon-free inorganic membrane using a hydrocarbon feed. It is used in processes for separating non-condensable molecules such as hydrogen, and in association with a catalyst in a catalytic membrane reactor.
Abstract: Relative and controlled sealing between a pipe (1) and a ceramic tube (7) utilizes a cylindrical chamber (5) that is attached in a sealed manner to the pipe (1), and to one end of the ceramic tube that is placed inside the chamber. At least two sets of sealing fixtures (3, 3?) are placed in an annular space between the ceramic tube and the chamber. A crosspiece (4) is interposed between the two sets sealing of fixtures (3, 3?). A metal mating flange (6) is pressed against a compression ring (4?) to compress the sealing fixtures (3, 3?). Injection of a fluid (8) between the two sets of sealing fixtures (3, 3?) applies a pressure differential that is determined on each of the fixtures.
Type:
Grant
Filed:
March 22, 2004
Date of Patent:
August 14, 2007
Assignee:
Institute Francais Du Petrole
Inventors:
Stéphane Bertholin, Luc Nougier, Michel Cohen
Abstract: A process for the selective hydrogenation of diolefinic compounds to mono-olefinic compounds uses a catalyst composition comprising at least one salt of a transition metal from groups IB, IIB, VB, VIB, VIIB and VIII of the periodic table, at least one ligand and at least one organometallic reducing agent, optionally in the presence of a non-aqueous ionic liquid selected from the group formed by liquid salts with general formula Q+A? (in which Q+ represents a quaternary ammonium and/or quaternary phosphonium and A? represents any anion which can form a liquid salt below 90° C.).
Type:
Application
Filed:
June 16, 2003
Publication date:
June 15, 2006
Applicant:
INSTITUTE FRANCAIS DU PETROLE
Inventors:
Gerard Hillion, Laurent Savary, David Proriol, Christophe Gautreau, Denis Uzio, Helene Olivier-Bourbigou
Abstract: Process and device for the transport of granular solids with a controlled flow rate, in particular for the transport of catalyst in a hydrocarbon reforming unit. The device comprises a gravity-feed pipe (A) for solid particles in the dense phase, a pneumatic transport pipe (C) in the dilute phase, and an inclined transfer pipe (B) that connects, without a buffer space, the base of the feed pipe to the pneumatic transport pipe, whereby this transfer pipe comprises means (17, 18, 35) for injection of a secondary gas located at the junction between the feed pipe and the transfer pipe.
Abstract: Process and device for regeneration of a used absorbent from a desulfurization zone or from the desulfurization of a gas containing sulfur oxides, comprising regeneration simultaneously with filtering of the absorbent, in a reducing atmosphere, wherein partial combustion of a regeneration gas is also carried out upstream from regeneration, the products of the partial combustion being mixed with the used absorbent prior to the regeneration-filtration stage. The absorbent may be, e.g., solid absorbents based on magnesium oxide. The regeneration gas may be hydrogen sulfide and/or a hydrocarbon. For example, H2S can be partially combusted and the products of the partial combustion, including H2S, H2, SO2 and sulfur, mixed with the used absorbent prior to the regeneration-filtration stage.
Type:
Grant
Filed:
May 31, 2001
Date of Patent:
November 1, 2005
Assignee:
Institute Francais du Petrole
Inventors:
Etienne Lebas, Gérard Martin, Christian Streicher
Abstract: A process for co-producing para-xylene and styrene from a feed (1) of hydrocarbons containing xylenes and ethylbenzene is described, the process comprising the following succession of steps: a step for separating the feed in a simulated moving bed in an adsorption column (6) containing beds of an adsorbent, from which an extract that is rich in para-xylene (7a) of at least 99.7% purity and at least one raffinate (7b) containing ethylbenzene, ortho-xylene, meta-xylene and a very small quantity of para-xylene is withdrawn; a step for dehydrogenating (10) the ethylbenzene contained in the raffinate (7b) to styrene; at least one step for primary separation of the stream (11) from the dehydrogenation step (10), to eliminate by-products; a step for separating the purified mixture (18) derived from the stream (11) containing styrene, unconverted ethylbenzene, meta-xylene and ortho-xylene, from which a stream (21a) that is rich in styrene of at least 99.
Abstract: An austenitic stainless steel with a composition comprising:
at most 0.15% of C;
2% to 10% of Mn;
at most 2% of Ni;
at most 4% of Cu;
0.1% to 0.4% of N;
10% to 20% of Cr;
at most 1% of Si;
at most 3% of Mo; and
at most 0.7% of Ti;
is used to manufacture equipment, for example furnaces, reactors or ducts, or elements of this equipment, or to coat the internal walls of this equipment, said equipment being used to implement petrochemical processes conducted at temperatures of 350° C. to 1100° C. and in which coke can be formed.
Type:
Grant
Filed:
January 15, 2002
Date of Patent:
November 30, 2004
Assignees:
Institute Francais du Petrole, USINOR
Inventors:
Philippe Lecour, Xavier Longaygue, François Ropital, Laurent Antoni
Abstract: A process for desulphurizing a gasoline feed comprising at least 150 ppm by weight of sulphur-containing compounds using a hydrodesulphurization catalyst is characterized in that said feed undergoes prior denitrogenation treatment under conditions such that the amount of nitrogen-containing compounds present in said feed when it is brought into contact with said hydrodesulphurization catalyst does not exceed 150 ppm by weight.
Abstract: A process is described for eliminating sulphur from a feed containing hydrogen sulphide, sulphur dioxide, carbon oxysulphide and/or carbon sulphide and a minimal quantity of benzene, toluene and/or xylenes in at least one reaction zone containing a catalyst, and recovering elemental sulphur and an effluent that is at least partially free of sulphur, the process being characterized in that the catalyst used is at least one catalyst containing a support comprising at least one compound selected from de group formed by alumina, titanium oxide and zirconia, the support further comprising at least one doping element selected from the group formed by iron, cobalt, nickel, copper and vanadium.
Type:
Application
Filed:
June 3, 2003
Publication date:
February 19, 2004
Applicant:
Institute Francais du Petrole
Inventors:
Christophe Nedez, Jean-Francois Chapat, Jean-Louis Ray
Abstract: The present invention relates to a process for regenerating an at least partly reduced catalytic redox solution. The solution includes at least one polyvalent metal chelated by a chelating agent and is circulated in at least one regeneration zone while an oxygen-containing gas is injected into the regeneration zone. The process includes measuring a concentration of oxygen dissolved in a regeneration zone effluent. The process also includes adjusting a flow rate of the at least partly reduce catalytic redox solution entering the at least one regeneration zone and/or an oxygen-containing gas entering the regeneration zone in response to a measured concentration of oxygen, until a concentration of oxygen in the regeneration zone effluent is less than 20% of an amount of oxygen dissolved in water saturated with oxygen. Thus, degradation of the chelating agent in the catalytic redox solution is minimized.
Abstract: The invention concerns a hydrocracking process using a catalyst comprising at least one matrix, an IM-5 zeolite, at least one metal selected from the group formed by metals from group VIB and group VIII of the periodic table, optionally at least one element selected from the group formed by phosphorous, boron and silicon, and optionally at least one group VIIA and/or at least one group VIIB and/or at least one group VB element (in particular niobium). The invention also concerns a catalyst containing at least one matrix, an IM-5 zeolite, at least one metal from groups VIII and/or VIB and at least one promoter element which is boron and/or silicon. The catalyst can also contain at least one group VIIA element and/or at least one group VIIB element and/or at least one group VB element.
Abstract: A lightened cement slurry for cementation of a well includes cement, at least one mineral filler, water, and resin particles obtained by polymerization from vinyl aromatic, alkyl acrylate or acrylic monomers, wherein the polymerization includes crosslinking.
Abstract: In a process for treating a gas containing acid gases, the gas is contacted with a methanol-containing aqueous phase and is then contacted in an absorption column with a mixture of solvents including mehtanol, water and a solvent heavier than methanol. Then, the mixture of solvents is at least partly regenerated through pressure reduction and/or heating. The treated gas is cooled by producing at least a methanol-containing aqueous phase that is at least partly recycled. The mixture of solvents flowing out at the bottom of the absorption column is cooled, then re-introduced at a higher level of the absorption column so as to control the temperature in the absorption column.
Abstract: The invention is a method for dimensioning or adapting an elastic structure immersed in a fluid in motion, the structure having a length Lt. The method comprises: a) the natural excitation modes of the structure and their number N are defined; b) for at least a given time t for an excitation mode of the structure, the various holding zones LR over length Lt and, for each holding zone, the excitation force FR corresponding to the excited natural mode r are determined; c) step b) is carried out for all the natural modes defined in step a); and d) the vibration amplitude response A of the elastic structure over part of length Lt is determined.
Abstract: The invention provides a catalyst including a support, at least one noble metal from group VIII of the periodic table, silicon as a dopant, optionally boron, optionally at least one group VIB element, optionally phosphorous and optionally at least one halogen. The invention also provides a particular preparation of the catalyst. The invention also concerns the use of this catalyst in the hydrotreatment of hydrocarbon-containing feeds, more particularly its use for hydrogenating aromatic compounds in a gas oil cut.
Type:
Grant
Filed:
February 25, 2000
Date of Patent:
April 1, 2003
Assignee:
Institute Francais du Petrole
Inventors:
Slavik Kasztelan, Samuel Mignard, Virginie Harle, Nathalie Marchal-George
Abstract: A process for isomerising a feed comprising normal paraffins containing 5 to 8 carbon atoms per molecule as a major portion in the presence of hydrogen is characterized in that the sum of the amounts of normal paraffins containing 7 and 8 carbon atoms per molecule contained in the feed is in the range 2% to 90% by weight with respect to the feed, and in that said feed is treated in at least one reaction zone containing at least one catalyst in a fixed bed, said catalyst comprising a support, at least one halogen and at least one group VIII metal, the reaction being carried out at a temperature in the range 30° C. to 150° C.
Abstract: A process is described for converting synthesis gas in the presence of a catalyst comprising at least one group VIII element dispersed on a support comprising alumina modified by aqueous impregnation of quaternary ammonium silicate and comprising in the range of about 3% by weight to about 9.5% by weight of silica. Said support can optionally also comprise at least one oxide selected from the group formed by rare earth oxides, alkaline-earth oxides and zirconium oxide.
Type:
Grant
Filed:
October 24, 2001
Date of Patent:
February 4, 2003
Assignees:
Institute Francais du Petrole, AGIP Petroli S.p.A., ENI S.p.A.
Inventors:
Magalie Roy-Auberger, Patrick Euzen, Vincent Zozaya, Roberto Zennaro, Giovanni Pederzani
Abstract: The invention relates to a process for the production of gasoline with a low sulfur content that comprises at least one stage for transformation of sulfur-containing compounds consisting of an alkylation or adsorption of sulfur-containing compounds and/or an increasing of the weight of light sulfur-containing compounds, at least one stage for treatment in the presence of an acid catalyst and at least one desulfurization treatment of at least a portion of the gasoline. The process according to the invention can also optionally comprise at least one stage for selective hydrogenation of diolefins and optionally at least one fractionation of the gasoline that is obtained into at least two fractions: light gasoline and heavy gasoline. FIG. 1 to be published.