Abstract: Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

Abstract: Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

Abstract: Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

Abstract: Methods and devices and aspects thereof for generating power using PEM fuel cell power systems comprising a rotary bed (or rotatable) reactor for hydrogen generation are disclosed. Hydrogen is generated by the hydrolysis of fuels such as lithium aluminum hydride and mixtures thereof. Water required for hydrolysis may be captured from the fuel cell exhaust. Water is preferably fed to the reactor in the form of a mist generated by an atomizer. An exemplary 750 We-h, 400 We PEM fuel cell power system may be characterized by a specific energy of about 550 We-h/kg and a specific power of about 290 We/kg. Turbidity fixtures within the reactor increase turbidity of fuel pellets within the reactor and improve the energy density of the system.

Abstract: A method of making a package for a fuel unit, a fuel unit including the package, and a hydrogen generator including one or more of the fuel units are disclosed. The package includes a package strip made by forming apertures in a nonconductive substrate strip, forming conductor sections in a conductor strip, aligning the substrate and conductor strips, bonding the conductor sections to the substrate strip to cover the apertures, and removing non-bonded portions of the conductor strip. A package enclosing a hydrogen generating reactant is formed by securing a segment of the package strip to itself, to one or more other segments and/or to one or more other package components. One or more conductor sections in the package strip are in thermal contact with one or more quantities of reactant composition so heat can be transferred thermally decompose the reactant composition and generate hydrogen gas.

Abstract: A packaged fuel unit and a refillable hydrogen generator that uses the fuel unit to produce hydrogen gas are disclosed. The fuel unit includes a reactant that can undergo a thermal decomposition reaction that produces hydrogen gas when heated to at least a minimum initiation temperature. The reactant is contained within a package that includes a poor thermal conductor with one or more thermal conductor sections for conducting heat from outside the package to the reactant. The hydrogen generator includes a holder with a cavity in which the fuel unit can be removably disposed and a heating system for heating the fuel unit when disposed therein. The hydrogen generator can be part of a fuel cell system including a fuel cell battery that is provided with hydrogen gas from the hydrogen generator.

Abstract: A hydrogen generator and a method of producing hydrogen gas using stabilized aluminum hydroxide and water are disclosed. The hydrogen generator contains stabilized aluminum hydride, water, a base, and a reaction chamber within which at least a portion of the stabilized aluminum hydride reacts with at least a portion of the water to produce hydrogen gas. The water that reacts with the stabilized aluminum hydride is contained in a basic aqueous solution including at least a portion of the base. The base can be included with the water in the basic aqueous solution, stored in a reservoir separate from the stabilized aluminum hydroxide, or the base can be a solid contained in a mixture with the stabilized aluminum hydroxide and mix with water when added to the mixture to form the basic aqueous solution.

Abstract: A heater assembly for use in a hydrogen generator can be retracted to facilitate insertion and removal of a replaceable fuel unit without damaging the heater assembly or the fuel unit and extended to provide good thermal contact with the fuel unit during use of the hydrogen generator. The heater assembly includes a support member, a heater, and an actuator for extending and retracting the heater assembly. When the heater is energized it heats the actuator, thereby extending the heater assembly to contact the adjacent fuel unit, and when the heater is deenergized the actuator cools to retract the heater assembly and provide a gap between the heater assembly and the adjacent fuel unit. The actuator is movably secured to the heater or the support member by a retainer such that an end of the actuator is movable within the retainer as the actuator changes shape during heating and cooling.

Abstract: A hydrogen generator is provided for generating hydrogen gas for a fuel cell stack. The hydrogen generator includes a container, and a liquid reactant storage area configured to contain a liquid including a first reactant. The hydrogen generator also includes a reaction area within the container, and a solid containing a second reactant within the reaction area and having a concentration gradient that varies along an axis such as length of the solid. The hydrogen generator further includes a liquid delivery member for delivering the liquid to the solid in the reaction area to generate hydrogen. The concentration gradient controls a reaction rate of the first and second reactants.

Abstract: The invention is a hydrogen generator with a fuel gauge and a method of fuel gauging. The hydrogen generator includes a replaceable fuel unit, containing a hydrogen-containing material (fuel) that can release hydrogen gas when heated and whose thermal conductivity is related to a quantity of releasable hydrogen contained therein, and a fuel gauge including a heat source and a temperature sensor adjacent to the fuel unit and a controller for determining a fuel level value based on a measured temperature. The temperature is measured at a pre-established time after activating the heat source, and the measured temperature is compared to a predetermined relationship between the measured temperature and a releasable hydrogen content in the fuel at the pre-established time. An output signal is provided (e.g., to a visible display, an audible signal or a controller).

Abstract: A hydrogen generator having one or more actuators coupled to one or more heating elements in which the actuator(s) are used to improve the transfer of thermal energy from heating element(s) to one or more fuel units contained within the generator. In one embodiment, an actuator allows insertion and/or removal of packaged fuel units without the need of removing the heating element(s) and/or the actuator(s). When the actuator is in a retracted state (e.g., a low temperature state), the packaged fuel unit may be inserted and/or removed from a cavity of the hydrogen generator. When the actuator is in an extended state (e.g., a higher temperature state), the actuator forces contact between itself or the heating element and the fuel unit when a prescribed operating temperature is reached.

Abstract: The invention relates to mixed metal borohydrides used for solid hydrogen storage. The mixed metal borohydrides are synthesized through solution synthesis using multiple metal borohydrides. First and second precursor solutions are prepared and combined to create a mixture in which the mixed metal borohydride is formed. The solvent is removed, leaving the mixed metal borohydride. The first precursor solution consisting essentially of lithium borohydride, and the second precursor solution consisting essentially of a borohydride compound containing one or more metal cations selected from the group of metals consisting of sodium, magnesium, calcium and titanium.

Abstract: A hydrogen generator, a fuel cell for use in the hydrogen generator and a fuel cell system are disclosed. The hydrogen generator includes a housing and a plurality of fuel pellets disposed in the housing. Each fuel pellet includes a hydrogen-containing reactant that will react to release hydrogen gas when heated. The hydrogen generator also includes a plurality of heating elements extending into the plurality of fuel pellets to generate heat to selectively heat one or more fuel pellets to initiate a reaction to produce hydrogen gas. The hydrogen generator further includes a plurality of electrical contacts operatively coupled to the plurality of heating elements to selectively supply electrical power to the plurality of heating elements.

Abstract: A hydrogen generator, a fuel pellet assembly for use in the hydrogen generator and a fuel cell system are disclosed. The hydrogen generator includes a housing having a lid pivotally connected to a base and a strip having a plurality of heaters on one side and a second plurality of heaters on the opposite side. A first cartridge is disposed on one side of the strip and a second cartridge is disposed on the opposite side. Each of the first and second cartridges has a plurality of fuel pellets, each including a hydrogen-containing material that will release hydrogen gas when heated. The heaters are selectively activated to heat one or more fuel pellets to initiate the release of hydrogen gas.

Abstract: Disclosed is a hydrogen generator with a door that can be opened to replace a fuel unit and closed to seal the door. A lock responds directly to pressure within the chamber to prevent opening when the pressure exceeds a threshold value. The lock includes a locking member with a lug that engages a retainer to seal the door when the door is locked and is disengaged from the retainer when the door is unlocked. An opening mechanism moves the locking member to lock and unlock the door. A movable key is engaged with the opening mechanism and the locking member when the pressure in the chamber is at or below the threshold value and disengaged from one of the opening mechanism and the locking member by an actuator (e.g., a flexible diaphragm) so the door cannot be unlocked and opened when the pressure is above the threshold value.

Abstract: Disclosed are a hydrogen generator and a method of producing hydrogen gas therefrom. A fuel unit containing a fuel that releases hydrogen gas when heated is removably disposed in a cavity within a housing having a door. A heater assembly for heating the fuel unit is disposed in the hydrogen generator. A mechanism retracts the heater assembly from the fuel unit when the door is opened and extends the heater assembly to contact the fuel unit when the door is closed. When the heater assembly is retracted, more space is available into which the fuel unit can be inserted to prevent damage to the heater assembly and the fuel unit, and when the heater assembly is extended, good contact is provided between the heater assembly and the fuel unit for efficient heating. A cam bar can move the heater assembly normal to the lateral motion of the cam bar.

Abstract: A hydrogen generator and a fuel cell system including the hydrogen generator are disclosed. The hydrogen generator includes a fuel composition including a hydrogen containing material that releases hydrogen gas to produce hydrogen when heated. A biasing member working in cooperation with a heating element and retainer, all of which are disposed within a unitary container, facilitate and control the release of hydrogen gas. The fuel composition can be segregated into individual quantities.

Abstract: Disclosed is a fuel unit for a gas generator such as a hydrogen gas generator that can supply gas to a gas consuming system such as a fuel cell system. The fuel unit includes a housing containing a solid fuel composition and a heat producing material. The fuel composition contains gas releasing solid material that reacts to release gas when heated. The heat producing material reacts exothermically to produce heat. A plurality of quantities of the heat producing material are in thermal communication with corresponding portions of an unsegregated quantity the fuel composition such that, following initiation of a reaction of each quantity of the heat producing material, the quantity of heat producing material will heat the corresponding portion of the unsegregated quantity of the fuel composition, and the corresponding portion of the unsegregated quantity of the fuel composition will react to release a quantity of the gas.

Abstract: A gas generator includes a reactant capable of producing a gas and a gas outlet valve that can function as both a gas flow valve and a pressure relief vent, using the same gas flow path through the valve. When the valve is closed and the pressure within the gas generator is below a threshold pressure, a moveable valve member is biased against a valve seat to block the outlet port. When gas generator is coupled to the apparatus, an actuator is inserted into the valve, displacing the moveable valve member and separating it from the valve seat to open the valve. When the gas generator is uncoupled, pressure at or above a threshold displaces the moveable member, separating it from the valve seat to open the outlet port so pressure can be released to the external environment.

Abstract: Disclosed are a fuel unit for a hydrogen generator and methods for producing the fuel unit and the hydrogen generator. A fuel sheet (50) is made by disposing a plurality of fuel pellets (50A-50J) containing a hydrogen-containing material on a substrate (52), and one or more fuel sheets are formed into a non-cylindrical fuel sheet assembly my moving (e.g., bending) a portion of the fuel sheet (50) to position pellets adjacent to each other such that adjacent sides of the adjacent pellets lie in essentially parallel planes. A non-cylindrical fuel unit is produced from one or more of the fuel sheet assemblies. Fuel units can be replaceably disposed in a hydrogen generator, and fuel pellets can be selectively heated to produce hydrogen gas as needed.