Abstract: Alkali values are recovered in a cyclic method from mechanically mined trona ore or from trona deposits by a solution mining technique utilizing a solvent comprising an aqueous solution of sodium sulfide. The ore is solubilized as sodium carbonate which is precipitated as sodium sesquicarbonate and/or sodium bicarbonate by treating the solution with hydrogen sulfide and the precipitated salt separated from the mother liquor. In the process, sodium sulfide and hydrogen sulfide become converted into sodium hydrosulfide which is contained in the mother liquor. Heat treatment of the mother liquor converts the sodium hydrosulfide into sodium sulfide thereby regenerating a solution of sodium sulfide which is recycled to the trona ore and into hydrogen sulfide which is evolved and recycled to the sodium carbonate solution.