Abstract: Dust-free alkaline earth peroxides are obtained by mixing alkaline earth peroxides with a compacting aid and dry-compacted in a compactor, for example, a roller press. Examples of suitably useful compacting aids include sodium bicarbonate, cellulose, magnesium montanate and cross-linked silicone compounds.

Abstract: A highly stabilized hydrogen peroxide useful for chemical sterilization of packaging materials in high-speed aseptic packaging plants.

Abstract: Homogeneous, boron-doped alkaline earth peroxides and mixed alkaline earth peroxides, methods for the production thereof, and use thereof as oxygenating agents for agricultural purposes.

Abstract: Coated metal peroxides, their preparation and use, in which metal peroxides are coated with silicone compounds from selected from the group siliconates, hydrogen-polysiloxanes, siloxanes, silicone resin emulsions, silane/siloxane emulsions, silane/siloxane mixtures, silicone microemulsion concentrates, and silicic acid ester mixtures.

Abstract: Sodium percarbonate is traditionally made in a crystallization process from aqueous hydrogen peroxide and sodium carbonate with recycle of mother liquor in the presence of a substantial concentration of a salting out agent, conventionally sodium chloride. The invention provides a process intended to be conducted without addition of chloride salting-out agent in which the dissolution step is controlled to restrict the sodium carbonate concentration to below 95%, preferably 60 to 90% of its saturated concentration at a temperature preferably controlled to at most 35C. and the mole ratio of hydrogen peroxide:sodium carbonate in the reaction vessel is controlled to between 0.7 to 1.2:1, and preferably about 1:1.

Abstract: Hydrogenation catalysts based on palladium, platinum or rhodium comprising at least one other metal M which are deposited on zirconium oxide and silicon oxide supports. Process for the manufacture of these catalysts by successive impregnation of the support using palladium, platinum or rhodium and using another metal M. Use of these catalysts in hydrogenation reactions and in particular in preparing hydrogen peroxide.

Abstract: Sodium percarbonate exhibits a tendency to decompose in built compositions and particularly detergent compositions built with zeolites. The tendency can be ameliorated by selecting sodium percarbonate which intrinsically has a mean particle size of from 500 to 1000 microns and not more than 20% by weight of below 350 microns and has a moisture pick-up when measured in a test at 80% relative humidity and 32° C. after 24 hours of not greater than 30 g/1000 g sample. A suitable sodium percarbonate can be made most conveniently by crystallisation from a bulk saturated solution of sodium percarbonate in a crystalliser/classifier that does not employ a conventional chloride salting-out agent.

Abstract: A homogeneous calcium/magnesium peroxide, its manufacture and use are described. The new calcium/magnesium peroxide is suitable in particular as an additive used as source of oxygen and acid buffer, e.g. in the application, processing, treatment and/or disposal of various biomaterials.

Abstract: Storage stable aqueous acidic solutions, often having a pH of up to 1 containing an ester peracid and/or an acid peracid can be obtained by reacting a diester satisfying the general formula R1—O—CO—R2—CO—O—R3 in which R1 and R3 each represents a alkyl group containing from 1 to 4 carbon atoms which may the same of different and R2 represents an aliphatic alkylene group optionally unsaturated which may be linear or branched containing from 2 to 6 carbon atoms with aqueous hydrogen peroxide in the presence of an acid, such as sulphuric acid and permitting the compositions to progress towards equilibrium concentrations. By starting with a diester, perhydrolysis generates an ester peracid which is a particularly effective peracid. The process can be controlled to produce solutions containing a high peracid content and within a wide range of ratios of ester peracid to acid peracid.

Abstract: The present invention relates to an apparatus for the continuous manufacture of solid particles of alkali metal persalts by reaction of an aqueous hydrogen peroxide solution with an aqueous solution of an alkali metal salt and crystallization of the persalt. The persalt is formed in a crystallizer classifier, which is made up of stirred region and a growth region for the persalt crystals a non-stirred clarifying region for the solution and a classification region for the particles obtained by elutriation in a liquid stream withdrawn in the clarifying region.

Abstract: Poly(lactones) are provided. The poly(lactones) are obtained by polymerization of a lactone with an initiator system comprising at least one polyfunctional initiator. The poly(lactones) have a shear viscosity at some temperature in the range of from 35 to 45° C. above the melting temperature of the poly(lactone) of at least 6 kPas at 0.1 s−1 shear rate and no greater than 3.5 kPas at 100 s−1 shear rate, and a shear viscosity activation energy of greater than 40 kJ/mol. Preferably, the poly(lactone) is poly(caprolactone).

Abstract: A method for the “dry” production of sodium percarbonate (dry process), in which monohydrate crystals of sodium carbonate are reacted with a quasi-stoichiometric quantity of concentrated aqueous hydrogen peroxide solution, relative to the quantity of active oxygen required in the sodium percarbonate to be produced. This method can be combined to great advantage with subsequent compaction of the sodium percarbonate obtained. Sodium percarbonate products containing varying concentrations of active oxygen of at least 10 weight percent, particularly high active oxygen concentrations of above 14.5 weight percent, can be produced. The resulting sodium percarbonate products are distinguished in that they have remarkably advantageous dissolution rates, stabilities and compatibility with detergent bases, and are superior to conventional sodium percarbonates obtained, for example, by a crystallization process.

Abstract: Sodium percarbonate is traditionally made in a crystallization process from aqueous hydrogen peroxide and sodium carbonate with recycle of mother liquor in the presence of a substantial concentration of a salting-out agent, conventionally sodium chloride. The invention provides a process intended to be conducted without addition of chloride salting-out agent in which the dissolution step (1) is controlled to restrict the sodium carbonate concentration to below 95%; preferably 60 to 90% of its saturated concentration at a temperature preferably controlled to at most 35° C. and the mole ratio of hydrogen peroxide: sodium carbonate in the reaction vessel is controlled to between 0.7 to 1.2:1, and preferably about 1:1.

Abstract: A flexible process for production of homogeneous sodium precarbonate particles or granules according to which a reaction slurry with an average to high solids content is prepared initially from an aqueous hydrogen peroxide solution of up to maximum 50% by weight and solid soda, this reaction slurry, which optionally may be finely ground by wet comminution, being subsequently subjected immediately to short-term drying, preferably spray drying, and, optionally, granulation. The process enables production, in an efficient manner, of essentially homogeneous sodium percarbonate particles or granules with variable active oxygen contents of 10 to 14.5% by weight and grain sizes and bulk densities which are variable within wide ranges.

Abstract: Process for bleaching a chemical paper pulp to a brightness of at least 89° ISO, consisting in subjecting the pulp to a treatment sequence of several stages including a final bleaching stage with hydrogen peroxide in alkaline medium carried out in the presence of at least one stabilising agent and at a consistency of at least 25% by weight of solids, the stages preceding this final stage having purified the pulp so that its manganese content does not exceed 3 ppm by weight with respect to the solids and that the pulp has been delignified beforehand to a kappa number not exceeding 5.

Abstract: Storage stable, aqueous acidic solutions having a pH in the range of from 1 to 5 comprising at least one ester peracid having general formula where R represents an alkyl group having from 1 to 4 carbons and x equals 1 to 4, are provided. The solutions can be prepared by contacting an aqueous solution of a carboxylic compound having general formula where x is from 1 to 4 and R represents an alkyl group having from 1 to 4 carbons with an inorganic peroxygen compound, preferably hydrogen peroxide, at a pH of less than 4 until at least some ester peracid is produced, and thereafter adjusting the pH to be in the range of from 1 to 5, if necessary.

Abstract: A homogeneous calcium/magnesium peroxide, its manufacture and use are described. The new calcium/magnesium peroxide is suitable in particular as an additive used as source of oxygen and acid buffer, e.g. in the application, processing, treatment and/or disposal of various biomaterials.

Abstract: Aqueous acidic solutions of hydrogen peroxide used for metal surface treatments suffer from an increased decomposition rate of the hydrogen peroxide, caused by the dissolved metals such as iron, copper or titanium. A method is provided wherein stabilization can be achieved by employing a combination of a) a hydroxybenzoic acid, preferably p-hydroxybenzoic acid; b) a hydrotropic sulphonic acid, preferably p-toluene sulphonic acid; and c) a hydrophobic alkaryl sulphonic acid, preferably dodecylbenzene sulphonic acid.

Abstract: Aqueous acidic solutions of hydrogen peroxide used for metal surface treatments suffer from an increased decomposition rate of the hydrogen peroxide, caused by the dissolution of metals such as iron, copper, or titanium. Stabilization can be achieved by employing a combination of a) hydroxybenzoic acid, preferably p-hydroxybenzoic acid; b) a hydrotropic sulphonic acid, preferably p-toluene sulphonic acid; and c) a hydrophobic alkaryl sulphonic acid, preferably dodecylbenzene sulphonic acid.

Abstract: A process for the delignification and bleaching of chemical pulp utilizes an acid treatment stage aimed at reducing the quantity of hexene uronic acids present in the pulp by at least 30%, and a pH adjustment stage of the pulp aimed at depositing or redepositing ions of alkaline-earth metals on the fibres of the pulp. The process further includes a washing stage of the pulp and a treatment stage of the pulp with an oxidizing agent. A chelating agent is added to the pulp before and/or during the acid treatment stage and/or before or during the pH adjustment stage or between the pH adjustment stage and washing stage.