Abstract: A process for upgrading hydrocarbonaceous oil containing heteroatom-containing compounds where the hydrocarbonaceous oil is contacted with a solvent system that is a mixture of a major portion of a polar solvent having a dipole moment greater than about 1 debye and a minor portion of water to selectively separate the constituents of the carbonaceous oil into a heteroatom-depleted raffinate fraction and heteroatom-enriched extract fraction. The polar solvent and the water-in-solvent system are formulated at a ratio where the water is an antisolvent in an amount to inhibit solubility of heteroatom-containing compounds and the polar solvent in the raffinate, and to inhibit solubility of non-heteroatom-containing compounds in the extract. The ratio of the hydrocarbonaceous oil to the solvent system is such that a coefficient of separation is at least 50%.
Abstract: A process for upgrading hydrocarbonaceous oil containing heteroatom-containing compounds where the hydrocarbonaceous oil is contacted with a solvent system that is a mixture of a major portion of a polar solvent having a dipole moment greater than about 1 debye and a minor portion of water to selectively separate the constituents of the carbonaceous oil into a heteroatom-depleted raffinate fraction and heteroatom-enriched extract fraction. The polar solvent and the water-in-solvent system are formulated at a ratio where the water is an antisolvent in an amount to inhibit solubility of heteroatom-containing compounds and the polar solvent in the raffinate, and to inhibit solubility of non-heteroatom-containing compounds in the extract. The ratio of the hydrocarbonaceous oil to the solvent system is such that a coefficient of separation is at least 50%.
Abstract: A process for controlling the continuous production of acetylene and hydrated lime from the reaction of water with calcium carbide is disclosed where the hydrated lime is withdrawn at a desired mass ratio of the hydrated lime to the calcium carbide feed. The process is also controlled by regulating the temperature so that it is independent of the variations in the production of acetylene by regulating heat transfer to the environment at a rate to maintain a constant temperature in the reactor. Preferably, the reaction is controlled by withdrawing the hydrated lime slurry product at a rate low enough to maintain a slurry concentration of hydrated lime above about 14 weight percent.
Type:
Grant
Filed:
September 20, 1999
Date of Patent:
September 25, 2001
Assignee:
James W. Bunger & Associates, Inc.
Inventors:
James W. Bunger, Christopher P. Russell, Jerald W. Wiser, Jesse C. Tsai
Abstract: A solution process for the purification of calcium hydroxide, particularly from hydrated carbide lime, which is subsequently used as a feed stock for a high-value calcium product, preferably calcium carbonate. Precipitated calcium carbonate is formed by reaction of the purified calcium hydroxide solution with carbon dioxide in a plug-flow reaction system.
Type:
Grant
Filed:
December 4, 1998
Date of Patent:
December 7, 1999
Assignee:
James W. Bunger and Associates, Inc.
Inventors:
James W. Bunger, Don Cogswell, Jerald W. Wiser
Abstract: An apparatus for the manufacture of acetylene and hydrated lime from the reaction of calcium carbide and an excess of water is disclosed. A primary reactor for the initial reaction of the calcium carbide and water is disposed concentrically within a secondary reactor. Hydrated lime and unreacted calcium carbide flow directly from the primary reactor to the secondary reactor, where the carbide lime settles from the water and is removed.
Type:
Grant
Filed:
June 23, 1997
Date of Patent:
September 21, 1999
Assignee:
James W. Bunger and Associates, Inc.
Inventors:
James W. Bunger, Christopher P. Russell, Jerald W. Wiser, Jesse C. Tsai
Abstract: A solution process for the purification of calcium hydroxide, particularly from hydrated carbide lime, which is subsequently used as a feed stock for a high-value calcium product, preferably calcium carbonate. Precipitated calcium carbonate is formed by reaction of the purified calcium hydroxide solution with carbon dioxide in a plug-flow reaction system.
Type:
Grant
Filed:
October 10, 1995
Date of Patent:
December 8, 1998
Assignee:
James W. Bunger and Associates, Inc.
Inventors:
James W. Bunger, Don Cogswell, Jerald W. Wiser
Abstract: A method for calculating the average aggregate mass of individual molecules in a sample, where the molecules in solution associate to form clusters. Data sets of average aggregate mass of the sample versus concentration of the sample in the solvent are generated. The basic principles and technology in generation of the data is the well understood action of a solute upon the solvent vapor pressure above the solution. By observing the effect of a sample solute on the temperature/vapor pressure properties of a solvent, if is possible by known methods to determine its average aggregate mass. When dealing with a solute material that tends to form clusters, however, the average aggregate mass found is an apparent average aggregate mass, i.e. the average aggregate mass of all of the particles, which are the clusters and any unassociated molecules, if any. To determine the true average aggregate mass, a method employing the determined apparent average aggregate masses, referred to herein as the BRD method, is used.
Type:
Grant
Filed:
November 12, 1996
Date of Patent:
April 14, 1998
Assignee:
James W. Bunger and Associates, Inc.
Inventors:
James W. Bunger, Christopher P. Russell, Prasad A. V. Devineni
Abstract: A method for calculating the average molecular weight of individual molecules in a sample, where the molecules in solution associate to form clusters. Data sets of apparent molecular weight of the sample versus concentration of the sample in the solvent are generated. The basic principles and technology in generation of the data is the well understood action of a solute upon the solvent vapor pressure above the solution. By observing the effect of a sample solute on the temperature/vapor pressure properties of a solvent, it is possible by known methods to determine its molecular weight. When dealing with a solute material that tends to form clusters, however, the molecular weight found is an apparent molecular weight, i.e. the average molecular weight of all of the particles, which are the clusters and any unassociated molecules, if any. To determine the true molecular weight, a method employing the determined apparent molecular weights, referred to herein as the BRD method, is used.
Type:
Grant
Filed:
February 28, 1995
Date of Patent:
November 12, 1996
Assignee:
James W. Bunger & Associates, Inc.
Inventors:
James W. Bunger, Christopher P. Russell, Prasad A. V. Devineni