Patents Assigned to Japan Technological Research Association of Artificial Photosynthetic Chemical Process
  • Patent number: 11766667
    Abstract: A CON zeolite satisfying the following (1) to (2): (1) The framework is CON as per the code specified by the International Zeolite Association (IZA); and (2) It contains silicon and aluminum, and the molar ratio of aluminum to silicon is 0.04 or more.
    Type: Grant
    Filed: March 8, 2021
    Date of Patent: September 26, 2023
    Assignees: Mitsubishi Chemical Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Hiroaki Onozuka, Masahiro Hara, Masato Yoshioka, Toshiyuki Yokoi
  • Patent number: 11424080
    Abstract: The present invention provides a method of producing a composite photocatalyst having a remarkable water splitting activity, which is capable of efficiently loading a co-catalyst having a small particle size in a highly dispersed manner on a surface of an optical semiconductor. According to the present invention, the method of producing a composite photocatalyst from a plurality types of optical semiconductors includes a step of heating a solid-liquid mixture containing a solvent, a co-catalyst or a co-catalyst source, and a plurality of types of optical semiconductors by irradiating the solid-liquid mixture with microwave.
    Type: Grant
    Filed: May 1, 2019
    Date of Patent: August 23, 2022
    Assignees: MITSUBISHI CHEMICAL CORPORATION, The University of Tokyo, Japan Technological Research Association of Artificial Photosynthetic Chemical Process
    Inventors: Seiji Akiyama, Kazunari Domen
  • Publication number: 20220090278
    Abstract: A method foe producing a transparent electrode for oxygen production having a Ta nitride layer on a transparent substrate, including: a step of forming a Ta nitride precursor layer on the transparent substrate; and a step of nitriding the Ta nitride precursor layer with a mixed gas containing ammonia and a carrier gas.
    Type: Application
    Filed: December 7, 2021
    Publication date: March 24, 2022
    Applicants: Mitsubishi Chemical Corporation, THE UNIVERSITY OF TOKYO, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS, NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Hiroshi NISHIYAMA, Tomohiro HIGASHI, Yutaka SASAKI, Taro YAMADA, Kazunari DOMEN, Yohichi SUZUKI, Seiji AKIYAMA
  • Patent number: 11248304
    Abstract: A method for producing a transparent electrode for oxygen production having a Ta nitride layer on a transparent substrate, including: a step of forming a Ta nitride precursor layer on the transparent substrate; and a step of nitriding the Ta nitride precursor layer with a mixed gas containing ammonia and a carrier gas.
    Type: Grant
    Filed: February 7, 2020
    Date of Patent: February 15, 2022
    Assignees: Mitsubishi Chemical Corporation, THE UNIVERSITY OF TOKYO, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS, NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Hiroshi Nishiyama, Tomohiro Higashi, Yutaka Sasaki, Taro Yamada, Kazunari Domen, Yohichi Suzuki, Seiji Akiyama
  • Publication number: 20210154623
    Abstract: The present invention addresses the problem of providing a bonded body which has a high airtightness and exhibits excellent durability under high-temperature and high-pressure conditions. This problem is solved by a bonded body in which a complex of a zeolite and an inorganic porous support, and a dense member are bonded together by an inorganic glass or an inorganic adhesive. The inorganic glass or the inorganic adhesive has a thermal expansion coefficient of 30×10?7/K to 90×10?7/K, and the inorganic glass has a softening point of 550° C. or lower. The present invention also addresses the problem of providing a method of efficiently producing an alcohol by installing a separation membrane in an alcohol synthesis reactor based on a bonding method that gives good sealing performance and durability under high-temperature and high-pressure conditions and in the presence of methanol vapor.
    Type: Application
    Filed: February 2, 2021
    Publication date: May 27, 2021
    Applicants: Mitsubishi Chemical Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Masamichi ONUKI, Naoyuki SAKAMOTO, Susumu TSUTSUMINAI, Koetsu ENDOU, Naoko FUJITA, Misa HARA, Masahiro KUJIME, Nobuo TORATANI
  • Patent number: 10914013
    Abstract: Provided are a photocatalyst electrode for oxygen generation exhibiting a satisfactory onset potential, and a module including this photocatalyst electrode. The photocatalyst electrode for oxygen generation includes a current collector layer; a photocatalyst on the current collector layer; and a promoter supported on at least a portion of the photocatalyst, in which the promoter contains a first metal oxide having an oxygen generation overvoltage of 0.4 V or lower, and a second metal oxide having an oxygen generation overvoltage of higher than 0.4 V.
    Type: Grant
    Filed: March 7, 2018
    Date of Patent: February 9, 2021
    Assignees: FUJIFILM Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS, THE UNIVERSITY OF TOKYO
    Inventors: Kazunari Domen, Tsutomu Minegishi, Atsushi Ohnishi, Koichiro Ueda, Chisato Katayama, Hiroyuki Kobayashi
  • Publication number: 20200407859
    Abstract: An object of the present invention is to provide a photocatalyst for water splitting, which can form a water splitting device that is excellent in durability and responsiveness to visible light and excellent in the amount of generated gas, and a water splitting device having the photocatalyst for water splitting. A photocatalyst for water splitting according to the embodiment of the present invention is a photocatalyst for water splitting, which is used for an electrode that generates gas by irradiation with light in a state of being immersed in water, and includes a compound represented by a formula, (Ln)2CuO4. In the formula, Ln represents a lanthanoid, and a part of Ln's may be substituted with an element of Groups II to IV of the periodic table.
    Type: Application
    Filed: September 14, 2020
    Publication date: December 31, 2020
    Applicants: FUJIFILM Corporation, Japan Technological Research Association of Artificial Photosynthetic Chemical Process
    Inventors: Hiroyuki KOBAYASHI, Masahiro ORITA
  • Publication number: 20200385873
    Abstract: An object of the present invention is to provide a photocatalytic electrode for water splitting and a water splitting device excellent in the onset potential. The water splitting device of the present invention is a water splitting device which generates gases from a photocatalytic electrode for hydrogen generation and a photocatalytic electrode for oxygen generation by irradiating the photocatalytic electrode for hydrogen generation and the photocatalytic electrode for oxygen generation with light, and includes a bath to be filled with an electrolytic aqueous solution and the photocatalytic electrode for hydrogen generation and the photocatalytic electrode for oxygen generation each disposed in the bath. The photocatalytic electrode for hydrogen generation has a p-type semiconductor layer, an n-type semiconductor layer provided on the p-type semiconductor layer, and a co-catalyst provided on the n-type semiconductor layer.
    Type: Application
    Filed: August 25, 2020
    Publication date: December 10, 2020
    Applicants: FUJIFILM Corporation, Japan Technological Research Association of Artificial Photosynthetic Chemical Process
    Inventors: Hiroyuki KOBAYASHI, Masahiro ORITA
  • Publication number: 20200240028
    Abstract: An object of the invention is to provide a water splitting device having a low electrolysis voltage and excellent gas separation performance. The water splitting device of the invention is a water splitting device that generates gases from the positive electrode and the negative electrode, the water splitting device including: a bath to be filled with an electrolytic aqueous solution; the positive electrode and the negative electrode disposed in the bath; and a polymer membrane that is ion-permeable and is disposed between the positive electrode and the negative electrode in order to separate the electrolytic aqueous solution filling the bath into the positive electrode side and the negative electrode side, wherein the positive electrode and the negative electrode are installed at a predetermined distance from the polymer membrane, and the moisture content of the polymer membrane is 40% or more.
    Type: Application
    Filed: April 16, 2020
    Publication date: July 30, 2020
    Applicants: FUJIFILM Corporation, Japan Technological Research Association of Artificial Photosynthetic Chemical Process
    Inventors: Hiroyuki KOBAYASHI, Taisei NISHIMI, Hiroshi NAGATE
  • Publication number: 20200173044
    Abstract: A method for producing a transparent electrode for oxygen production having a Ta nitride layer on a transparent substrate, including: a step of forming a Ta nitride precursor layer on the transparent substrate; and a step of nitriding the Ta nitride precursor layer with a mixed gas containing ammonia and a carrier gas.
    Type: Application
    Filed: February 7, 2020
    Publication date: June 4, 2020
    Applicants: Mitsubishi Chemical Corporation, THE UNIVERSITY OF TOKYO, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS, NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Hiroshi NISHIYAMA, Tomohiro HIGASHI, Yutaka SASAKI, Taro YAMADA, Kazunari DOMEN, Yohichi SUZUKI, Seiji AKIYAMA
  • Publication number: 20200047167
    Abstract: A CON zeolite satisfying the following (1) to (2): (1) The framework is CON as per the code specified by the International Zeolite Association (IZA); and (2) It contains silicon and aluminum, and the molar ratio of aluminum to silicon is 0.04 or more.
    Type: Application
    Filed: October 8, 2019
    Publication date: February 13, 2020
    Applicants: Mitsubishi Chemical Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Hiroaki Onozuka, Masahiro Hara, Masato Yoshioka, Toshiyuki Yokoi
  • Publication number: 20200040470
    Abstract: Provided are an artificial photosynthesis module electrode with high efficiency and an artificial photosynthesis module having the artificial photosynthesis module electrode. The artificial photosynthesis module electrode has a first electrode that decomposes a raw material fluid with light to obtain a first fluid, a first conductive member connected to the first electrode, a second electrode that decomposes the raw material fluid with light to obtain the second fluid, and a second conductive member connected to the second electrode. The first electrode has a plurality of first electrode parts connected to the first conductive member and disposed with a gap in a first direction on a first plane. The second electrode has a plurality of second electrode parts connected to the second conductive member and disposed with a gap in the first direction on a second plane parallel to or identical to the first plane.
    Type: Application
    Filed: October 7, 2019
    Publication date: February 6, 2020
    Applicants: FUJIFILM Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Yoshihiro Aburaya, Satoshi Yoshida
  • Patent number: 10478810
    Abstract: A zeolite catalyst capable of maintaining a high conversion of raw materials over a long period of time, and a method of producing a lower olefin stably over a long period of time using the zeolite catalyst is to be provided. A CON zeolite catalyst containing aluminum (Al) as a constituent element, wherein the CON zeolite catalyst has a ratio ((A2/A1)×100 (%)) of an integrated intensity area (A2) of signal intensity in a range from 57.5 ppm to 70 ppm to an integrated intensity area (A1) of signal intensity in a range from 45 ppm to 70 ppm is not less than 49.0% when analyzed by 27Al-MAS-NMR is prepared, and a lower olefin is produced by a MTO process using the zeolite catalyst.
    Type: Grant
    Filed: May 24, 2018
    Date of Patent: November 19, 2019
    Assignees: Mitsubishi Chemical Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Hiroaki Onozuka, Masahiro Hara, Masato Yoshioka, Toshiyuki Yokoi
  • Patent number: 10465299
    Abstract: A gas production apparatus is provided which includes: a module including a plurality of PN junctions connected in series to one another, each being formed of an inorganic semiconductor and having a light receiving surface; two gas generators that are provided at open ends of PN junctions at both extremities of the module, respectively, on a side of the light receiving surface; an electrolysis chamber which contains an aqueous electrolytic solution in contact with the two gas generators and contains gases generated by the two gas generators; and a diaphragm which is ion-permeable but gas-impermeable, and partitions the electrolysis chamber into two regions including the two gas generators, respectively, and containing hydrogen and oxygen, respectively.
    Type: Grant
    Filed: September 25, 2015
    Date of Patent: November 5, 2019
    Assignees: FUJIFILM Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventor: Kohei Higashi
  • Publication number: 20190323134
    Abstract: The present invention has an object to provide a photocatalyst electrode for oxygen generation having excellent photocurrent density, a production method for a photocatalyst electrode for oxygen generation and a module, and the photocatalyst electrode for oxygen generation of the present invention includes a current collector layer and a photocatalyst layer containing Ta3N5, wherein the photocatalyst electrode for oxygen generation has a charge separation promotion layer between the current collector layer and the photocatalyst layer.
    Type: Application
    Filed: June 11, 2019
    Publication date: October 24, 2019
    Applicants: FUJIFILM Corporation, Japan Technological Research Association of Artificial Photosynthetic Chemical Process, THE UNIVERSITY OF TOKYO
    Inventors: Yusuke ASAKURA, Kazunari DOMEN, Taro YAMADA, Hiroyuki KOBAYASHI, Hiroshi NISHIYAMA
  • Patent number: 10392714
    Abstract: Provided is an artificial-photosynthesis module, which decomposes an aqueous electrolyte solution into hydrogen and oxygen by means of light, including a photoelectric conversion unit that receives light to generate electrical energy; a hydrogen gas generating part that decomposes the aqueous electrolyte solution, using the electrical energy of the photoelectric conversion unit, and generates hydrogen gas; and an oxygen gas generating part that decomposes the aqueous electrolyte solution, using the electrical energy of the photoelectric conversion unit, and generates oxygen gas. The photoelectric conversion unit, the hydrogen gas generating part, and the oxygen gas generating part are electrically connected in series, and the hydrogen gas generating part and the oxygen gas generating part are arranged within an electrolytic chamber to which the aqueous electrolyte solution is supplied. The hydrogen gas generating part has an inorganic semiconductor film having a pn junction.
    Type: Grant
    Filed: June 10, 2016
    Date of Patent: August 27, 2019
    Assignees: FUJIFILM Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS, THE UNIVERSITY OF TOKYO
    Inventors: Naotoshi Sato, Kazunari Domen, Jiro Tsukahara
  • Publication number: 20190259543
    Abstract: The present invention provides a method of producing a composite photocatalyst having a remarkable water splitting activity, which is capable of efficiently loading a co-catalyst having a small particle size in a highly dispersed manner on a surface of an optical semiconductor. According to the present invention, the method of producing a composite photocatalyst from a plurality types of optical semiconductors includes a step of heating a solid-liquid mixture containing a solvent, a co-catalyst or a co-catalyst source, and a plurality of types of optical semiconductors by irradiating the solid-liquid mixture with microwave.
    Type: Application
    Filed: May 1, 2019
    Publication date: August 22, 2019
    Applicants: MITSUBISHI CHEMICAL CORPORATION, The University of Tokyo, Japan Technological Research Association of Artificial Photosynthetic Chemical Process
    Inventors: Seiji AKIYAMA, Kazunari DOMEN
  • Patent number: 10384195
    Abstract: An artificial photosynthesis module includes an oxygen generation electrode having a first photocatalyst layer that decomposes water with light to generate oxygen, and has a first substrate, a first conductive layer, a first photocatalyst layer, and a first co-catalyst, and a hydrogen generation electrode that decomposes water with light to generate hydrogen and has a second substrate, a second conductive layer, a second photocatalyst layer, and a second co-catalyst. This provides an artificial photosynthesis module with high reaction efficiency.
    Type: Grant
    Filed: August 22, 2018
    Date of Patent: August 20, 2019
    Assignees: FUJIFILM Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventor: Hiroyuki Kobayashi
  • Patent number: 10351964
    Abstract: In an artificial photosynthesis module, a plurality of first electrode portions of a hydrogen generation electrode are disposed side by side with a gap, and each of a plurality of second electrode portions of an oxygen generation electrode is disposed at a gap between the first electrode portions of the hydrogen generation electrode as seen from the hydrogen generation electrode side with respect to the diaphragm. A first photocatalyst layer of at least one first electrode portion of the hydrogen generation electrode or a second photocatalyst layer of at least one of the second electrode portions of the oxygen generation electrode is tilted with respect to a flow direction of an electrolytic aqueous solution, or a projecting part is provided on a surface of the first photocatalyst layer of at least one first electrode portion of the hydrogen generation electrode or a surface of the second photocatalyst layer of at least one second electrode portion of the oxygen generation electrode.
    Type: Grant
    Filed: May 10, 2018
    Date of Patent: July 16, 2019
    Assignees: FUJIFILM Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Satoshi Yoshida, Hiroshi Nagate
  • Patent number: 10351961
    Abstract: Provided are a water decomposition apparatus and a water decomposition method that can maintain high gas generation efficiency even in an early stage of light irradiation and even in a case where time has elapsed and that can recover the gas generation amount of hydrogen gas or the like, can generate hydrogen gas or the like stably for a long time on an average, and can increase the integrated amount of generation of hydrogen for a long time, even in a case where time has elapsed and the gas generation amount of hydrogen gas or the like has decreased.
    Type: Grant
    Filed: December 28, 2016
    Date of Patent: July 16, 2019
    Assignees: FUJIFILM Corporation, JAPAN TECHNOLOGICAL RESEARCH ASSOCIATION OF ARTIFICIAL PHOTOSYNTHETIC CHEMICAL PROCESS
    Inventors: Kohei Higashi, Naotoshi Sato