Abstract: A HAPs-free ink jet ink includes a pigment; a binder comprising vinyl chloride-vinyl acetate copolymer; and a HAPs-free solvent component comprising 1-methoxy-2-propanol acetate, a dispersing solvent selected from cyclohexanone, n-propyl acetate, n-butyl acetate, diisobutyl ketone, isobutyl acetate, amyl acetate, and combinations of these, and a diluent solvent selected from dipropylene glycol methyl ether, dipropylene glycol methyl ether acetate, tripropylene glycol methyl ether, ethylene glycol diacetate, propylene glycol n-butyl ether, propylene glycol n-propyl ether, and combinations of these. The ink has excellent stability and printing properties. Printing with the ink avoids release of HAPs while allowing long print runs with low maintenance.

Abstract: A radiation-curable ink jet ink can be formulated with less than 20% by weight of monofunctional monomer by dispersing the pigment or pigments with an acrylated epoxy resin having an average of from about 1.6 to about 2.0 functional groups per molecule, a number average molecular weight of from about 350 to about 600, and a glass transition temperature of from about ?20° C. to about +25° C.