Patents Assigned to Jindal Films Americas LLC
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Patent number: 11801670Abstract: A squeezable, white polypropylene film is disclosed having a novel balance of conformability, stiffness, modulus, opacity, and whiteness. The film includes an ABCBA structure having a core layer of polypropylene resin with an elastomeric copolymer and a cavitating agent. Two intermediate layers of polypropylene resin are present on either side, the intermediate layers optionally including an elastomeric copolymer and a pigmenting agent. Two polymer skin layers surround the two intermediate layers. The resins are co-extruded into a biaxially oriented film having a thickness between 40 to 70 pm for use in pressure-sensitive labeling applications.Type: GrantFiled: August 24, 2018Date of Patent: October 31, 2023Assignee: Jindal Films Americas LLCInventors: Benoît Ambroise, Daniel L. Hinman, Robert M. Sheppard, Michael D. Cleckner
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Patent number: 11794397Abstract: In one example embodiment, disclosed is a biaxially oriented multilayer film, which may include a first tie layer and a second tie layer, wherein each has an inside surface and an outside surface. The film's core layer may consist of: (i) at least 50 wt. % high-crystalline polypropylene; (ii) both cyclic olefin copolymer and polypropylene homopolymer, or, polypropylene heterophasic copolymer; (iii) and, optionally, additives, wherein the core layer is between the inside surface of the first tie layer and the inside surface of the second tie layer. The film may also include a first skin layer on the outside surface of the first tie layer and a second skin layer on the outside surface of the second tie layer, wherein shrinkage is less than 3.5% in a transverse direction for the biaxially oriented multilayer film after subjecting the biaxially oriented multilayer film to 135° C. for 7 min at 1 atm.Type: GrantFiled: July 15, 2021Date of Patent: October 24, 2023Assignee: Jindal Films Americas LLCInventors: Thierry J. L. Dabadie, Gabriel Domingos, Alain Marchal, François Gastineau
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Publication number: 20230311467Abstract: In one example embodiment, disclosed is a polyethylene film, which in example embodiment(s) may comprise, consists essentially or, or consists of: (A) a core layer and a first tie layer on a first side of the core layer consisting essentially of: (i) at least about 20 wt. % olefin-block copolymer; (ii) at least about 40 wt. % low-density polyethylene; and (iii) at least about 40 wt. % high-density polyethylene, wherein “consisting essentially of” and “about,” among other words, are defined elsewhere in this disclosure; (B) a second tie layer on a second side of the core layer comprising, consisting essentially of, or consisting of: (i) at least about 20 wt. % low-density polyethylene; and (ii) at least about 40 wt. % high-density polyethylene; and (C) skin layer(s), be oriented in one or two directions; and contain additional layers external to the skin layer(s).Type: ApplicationFiled: June 8, 2023Publication date: October 5, 2023Applicant: Jindal Films Americas LLCInventors: Eric T. Gohr, Robert M. Sheppard
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Patent number: 11752746Abstract: Disclosed are compositions, methods, and uses for multi-layered films which are intended to provide high quality sealants having sufficient sealing strength for use in packaging and other applications while being more cost-effective and higher-yield than traditional combinations of unoriented polyolefin films and web materials. The film comprises a multilayer structure of LLDPE having a core layer, a surface skin layer, and a sealant skin layer. The core layer further comprises a slip agent, while the skin layers further comprise antiblock agents. Optional embodiments may include tie layers between the core layer and the skin layers, or may include pigments in one or more of the core layer or tie layers. The surface skin layer may be subjected to a surface treatment (e.g., corona treatment) to improve suitability for coating or metallization.Type: GrantFiled: August 24, 2018Date of Patent: September 12, 2023Assignee: Jindal Films Americas LLCInventors: Benoît Ambroise, Michael D. Cleckner, Christophe E. Guillaume, Lesley A. Bliss
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Publication number: 20230249443Abstract: In one embodiment, the disclosure provides a film, which may be oriented, cast, or blown, that includes a core layer having a first side and a second side, wherein the core layer comprises hydrocarbon resin and polypropylene. Further, the film may include a first tie layer on the first side, wherein the first tie layer consists of polypropylene and about 5% or less of additives with exclusion of hydrocarbon resin (“HCR”), wherein the polypropylene is standard-crystalline polypropylene, high-crystalline polypropylene, or a mixture thereof, but preferably, it is a majority of high-crystalline polypropylene. Further still, the film may include a first skin layer on the first tie layer, and, also a coating on the first skin layer, wherein the coating comprises acrylic or acetate polymers or combinations thereof. The film maintains a minimum seal temperature of 300 g in?1 seal strength as compared to the film without any HCR.Type: ApplicationFiled: March 3, 2023Publication date: August 10, 2023Applicant: Jindal Films Americas LLCInventors: Christian Leger, Christophe Guillaume
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Patent number: 11718079Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising, consisting essentially of, or consisting of low-density polyethylene, optionally linear, and at least about 80 wt. % of high-density polyethylene, as well as a second skin layer comprising either: (i) one or more low-density polyethylenes, any or all of them optionally being linear; or (ii) one or more polypropylene-based copolymers. The multilayer film may be oriented in at least one direction.Type: GrantFiled: August 18, 2022Date of Patent: August 8, 2023Assignee: Jindal Films Americas LLCInventors: Benoit Ambroise, Alain Marchall, Robert M. Sheppard, Christophe Guillaume, Detlef Hütt
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Patent number: 11712878Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising at least 80 wt. % of high-density polyethylene, and a second skin layer comprising either: (i) one or more low-density polyethylenes; or (ii) one or more polypropylene-based copolymers. The multilayer film may be oriented in at least one direction.Type: GrantFiled: March 31, 2021Date of Patent: August 1, 2023Assignee: Jindal Films Americas LLCInventors: Benoît Ambroise, Alain Marchall, Robert M Sheppard, Christophe Guillaume, Detlef Hütt
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Patent number: 11613111Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer consisting essentially of one or more ethylene-propylene copolymers. Further still, the multilayer film may include a second skin layer consisting essentially of one or more ethylene-propylene-butylene terpolymers. And yet further, the multilayer film may be oriented in at least one direction, and at least two layers of the multilayer film are coextruded.Type: GrantFiled: May 3, 2021Date of Patent: March 28, 2023Assignee: Jindal Films Americas LLCInventors: Eric T. Gohr, Robert M. Sheppard
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Publication number: 20220388292Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising, consisting essentially of, or consisting of low-density polyethylene, optionally linear, and at least about 80 wt. % of high-density polyethylene, as well as a second skin layer comprising either: (i) one or more low-density polyethylenes, any or all of them optionally being linear; or (ii) one or more polypropylene-based copolymers. The multilayer film may be oriented in at least one direction.Type: ApplicationFiled: August 18, 2022Publication date: December 8, 2022Applicant: Jindal Films Americas LLCInventors: Benoît Ambroise, Alain Marchall, Robert M. Sheppard, Christophe Guillaume, Detlef Hütt
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Publication number: 20210347101Abstract: In one example embodiment, disclosed is a biaxially oriented multilayer film, which may include a first tie layer and a second tie layer, wherein each has an inside surface and an outside surface. The film's core layer may consist of: (i) at least 50 wt. % high-crystalline polypropylene; (ii) both cyclic olefin copolymer and polypropylene homopolymer, or, polypropylene heterophasic copolymer; (iii) and, optionally, additives, wherein the core layer is between the inside surface of the first tie layer and the inside surface of the second tie layer. The film may also include a first skin layer on the outside surface of the first tie layer and a second skin layer on the outside surface of the second tie layer, wherein shrinkage is less than 3.5% in a transverse direction for the biaxially oriented multilayer film after subjecting the biaxially oriented multilayer film to 135° C. for 7 min at 1 atm.Type: ApplicationFiled: July 15, 2021Publication date: November 11, 2021Applicant: Jindal Films Americas LLCInventors: Thierry J. L. Dabadie, Gabriel Domingos, Alain Marchal, François Gastineau
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Patent number: 11135820Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may include a core layer comprising a polyethylene stabilizer optionally in a masterbatch solution and at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising at least 90 wt. % ethylene-propylene polymer and antiblock, and a second skin layer consisting of an ethylene-propylene copolymer or terpolymer. Further still, the multilayer film may include a primer layer on the second skin, an aqueous barrier layer of ethylene vinyl alcohol polymer, polyvinyl alcohol polymer, or combinations thereof on the primer layer. And, further still, multilayer film may include a metallization layer on the aqueous barrier layer, wherein the multilayer film may be oriented in at least one direction.Type: GrantFiled: April 29, 2021Date of Patent: October 5, 2021Assignee: Jindal Films Americas LLCInventors: Eric T. Gohr, Robert M. Sheppard, Ting Chen
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Publication number: 20210252842Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising an ethylene-propylene polymer, and a second skin layer comprising at least one or more ?-olefin copolymers and antiblock. One or more of the at least one or more ?-olefin copolymers in the second skin layer, which may be a sealant skin layer, may include at least one ethylene-propylene-butylene polymer in combination with a plastomer and/or elastomer that contain propylene, ethylene, or a combination thereof.Type: ApplicationFiled: May 4, 2021Publication date: August 19, 2021Applicant: Jindal Films Americas LLCInventors: Eric T. Gohr, Robert M. Sheppard, Benoît Ambroise
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Publication number: 20210252841Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer consisting essentially of one or more ethylene-propylene copolymers. Further still, the multilayer film may include a second skin layer consisting essentially of one or more ethylene-propylene-butylene terpolymers. And yet further, the multilayer film may be oriented in at least one direction, and at least two layers of the multilayer film are coextruded.Type: ApplicationFiled: May 3, 2021Publication date: August 19, 2021Applicant: Jindal Films Americas LLCInventors: Eric T. Gohr, Robert M. Sheppard
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Publication number: 20210245480Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may include a core layer comprising a polyethylene stabilizer optionally in a masterbatch solution and at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising at least 90 wt. % ethylene-propylene polymer and antiblock, and a second skin layer consisting of an ethylene-propylene copolymer or terpolymer. Further still, the multilayer film may include a primer layer on the second skin, an aqueous barrier layer of ethylene vinyl alcohol polymer, polyvinyl alcohol polymer, or combinations thereof on the primer layer. And, further still, multilayer film may include a metallization layer on the aqueous barrier layer, wherein the multilayer film may be oriented in at least one direction.Type: ApplicationFiled: April 29, 2021Publication date: August 12, 2021Applicant: Jindal Films Americas LLCInventors: Eric T. Gohr, Robert M. Sheppard, Ting Chen
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Publication number: 20210213719Abstract: Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising at least 80 wt. % of high-density polyethylene, and a second skin layer comprising either: (i) one or more low-density polyethylenes; or (ii) one or more polypropylene-based copolymers. The multilayer film may be oriented in at least one direction.Type: ApplicationFiled: March 31, 2021Publication date: July 15, 2021Applicant: Jindal Films Americas LLCInventors: Benoît Ambroise, Alain Marchall, Robert M. Sheppard, Christophe Guillaume, Detlef Hütt
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Publication number: 20200369014Abstract: Disclosed are transparent films having a core comprising at least 50 wt. % high-density polyethylene and, optionally, 50 wt. % or less of linear low-density polyethylene. Further, the transparent films may have a printable skin layer adjacent to a first side of the core, wherein the printable skin layer may comprise, consists essentially of or consists of linear low-density polyethylene or ethylene-propylene copolymer. Further, the transparent films may have a skin layer adjacent to a second side of the core, wherein the skin layer may comprise, consists essentially of or consists of linear low-density polyethylene or ethylene-propylene copolymer. Further still, the transparent films may be oriented in at least one direction and have a directional modulus of at least 1200 MPa. Such transparent films may be laminated to a laminating substrate, such as a biaxially oriented polyethylene single or multilayer film, to produce a laminated film with remarkable sealing and integrity.Type: ApplicationFiled: August 4, 2020Publication date: November 26, 2020Applicant: Jindal Films Americas LLCInventor: Benoît Ambroise
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Patent number: 10718046Abstract: This disclosure provides compositions and methods for a film, which may include a base film and a coating layer on the base film, wherein the coating layer has a surface energy of at least 30 dynes/cm and consists essentially of nylon, polyester, ethylene vinyl alcohol-based copolymer, polyvinyl alcohol-based polyethylene terephthalate, polyvinylchloride, acrylate-based polymers, methacrylate-based polymers, polyurethane, polyalkylimine, acid-modified polyolefins, polyetherester-amide block copolymer, and combinations thereof. Further, the film may include a metal oxide layer on the coating layer, wherein the metal oxide layer has an optical density of equal to or less than 0.5 and a thickness from 0.1 nm through 100 nm. Further still, the film has an oxygen transmission rate of less than 4 cm3/m2/day at 23° C. and 0% relative humidity, a water vapor transmission rate of less than 4 g/m2/day at 38° C. and 90% relative humidity, and a thickness of 5 ?m through 50 ?m.Type: GrantFiled: May 13, 2019Date of Patent: July 21, 2020Assignee: Jindal Films Americas LLCInventors: Thierry J. L. Dabadie, Massimo Pignatelli, François Gastineau, Gabriel Domingos
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Publication number: 20200061968Abstract: Disclosed are hot-melt, curl-free methods, structures, and compositions, which in flexible packaging applications, reduce mineral-oil, hydrocarbon migration into packaged food. One embodiment provides an optionally oriented base film having a first side and a second side that is a transparent or opaque film. Further, the composition comprises, consists essentially of, or consists of a water-based primer applied to the first side. Further still, the composition includes a barrier layer to mineral-oil migration, wherein the barrier layer is located between the adhesive-receptive layer and the polymeric substrate, and wherein the barrier layer consists essentially of: (i) polymers of polyvinyl alcohol, ethylene vinyl alcohol, polyester, polyamide, or combinations thereof; and (ii) optionally additives. The barrier layer provides a barrier to mineral-oil migration of 0.1 ?g/day*dm2 or less at 40° C. for 40 days, and the curl-resistant composition does not curl when heated for at least one hour at 60° C.Type: ApplicationFiled: November 1, 2019Publication date: February 27, 2020Applicant: Jindal Films Americas LLCInventor: David Piran
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Publication number: 20200061982Abstract: This disclosure provides compositions and methods for an oriented film that may include a core layer consisting essentially of biaxially oriented linear low-density polyethylene, wherein the core layer has a first side and a second side. Further, the film may include a first sealant layer consisting essentially of biaxially oriented linear low-density polyethylene on the first side, and a second sealant layer consisting essentially of biaxially oriented linear low-density polyethylene on the first side, wherein the linear low-density polyethylenes in each of the film's layers may be of more than one type/grade, have the same or different densities, or both. Further still, the film is 30 ?m or less in thickness, has a water-vapor transmission rate of ?1 g/m2/d at 38° C. and 90% relative humidity, and has an oxygen transmission rate of ?100 cm3/m2/d at 23° C. and 0% relative humidity.Type: ApplicationFiled: October 24, 2019Publication date: February 27, 2020Applicant: Jindal Films Americas LLCInventor: Benoît Ambroise
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Patent number: 10569920Abstract: This disclosure provides compositions, films, labels, structures and methods that may include a substrate having a first side and a second side, wherein the first side comprises a skin layer comprising at least 50 wt. % of high-density polyethylene. Further, the compositions may include a coating on the skin layer, wherein the coating comprises a topcoat and a primer, wherein the topcoat consists of: (i) at least 50 wt. % high-density polyethylene and one or more polyethylene polymers in water; (ii) wax, silicone or combination thereof; and (iii) optionally additives, whereupon imaging the composition by a thermal print head at a temperature of 300° C. or less results in no or negligible solvent-penetrability beneath the skin layer.Type: GrantFiled: September 10, 2018Date of Patent: February 25, 2020Assignee: Jindal Films Americas LLCInventors: Daniel L Hinman, Mark W Lockhart, Terry O Jensen, Robert M Sheppard, Thierry J. L. Dabadie, Alexandra N Wolfe, Anand Sundararaman, David J Hill, David Piran