Abstract: A polymerizable liquid crystal composition for obtaining a retardation film that has high front contrast; and a liquid crystal polymer. A polymerizable liquid crystal composition which is characterized by containing a compound represented by formula (1). Exemplified are embodiments wherein in formula (1), W1 represents an alkyl group having 1-5 carbon atoms, an alkoxy group having 1-5 carbon atoms, an alkoxycarbonyl group having 1-5 carbon atoms or an alkanoyl group having 1-5 carbon atoms; Z1 represents —CH2CH2COO—; Z2 represents —OCOCH2CH2—; each of Y1 and Y2 represents a linking group; each of Q1 and Q2 represents a spacer; and each of P1 and P2 represents a polymerizable functional group.
Abstract: The purpose of the invention is to control, by using a colorless alignment control monomer, the alignment of liquid crystal molecules of a liquid crystal display element that does not include an alignment film, and to provide a liquid crystal composition with which the colorless alignment control monomer exhibits excellent compatibility. The invention uses a liquid crystal display element that comprises an alignment control monomer including an aromatic ester that undergoes photo-Fries rearrangement by light irradiation, and that employs a liquid crystal composition having a negative dielectric anisotropy. The invention also uses the liquid crystal composition.
Abstract: Provided is a compound represented by formula (1) described below. In formula (1), a and b are independently 0, 1 or 2, and expressions: 0?a+b?3 hold, ring A1, ring A2, ring A3 and ring A4 are independently 1,4-cyclohexylene, for example, Z1, Z2, Z3, Z4 and Z3 are independently a single bond, alkylene having 1 to 10 carbons, or the like, Sp1 and Sp2 are independently a single bond, alkylene having 1 to 10 carbons, or the like, and P1 and P2 are independently a specific polymerizable group.
Abstract: A liquid crystal composition without requiring an alignment film or alignment treatment on a substrate. The problem is solved by a low molecular weight polar compound capable of homogeneously aligning a liquid crystal medium relative to the substrate, for example, a low molecular weight polar compound represented by formula (1): M-P??(1) In formula (1), M is a nonpolar group having 1 or more carbons, and P is a polar group.
Abstract: A polymerizable liquid crystal compound represented by formula (1). In formula (1), A1 is 1,4-phenylene, 1,4-cyclohexylene, 1,4-cyclohexenylene, pyridine-2,5-diyl, 1,3-dioxane-2,5-diyl or naphthalene-2,6-diyl, Z1 is a connecting group, m and n are independently an integer from 0 to 5, in which an expression: 1?m+n?8 holds, X1 is alkylene having 1 to 5 carbons, in which an atom thereof may be replaced by a hetero atom, and at least one of R1 is a polymerizable functional group.
Abstract: A negative electrode active material for the lithium ion secondary battery contains silicon oxide that is obtained by heat-treating, under an inert gas atmosphere, a hydrogen silsesquioxane polymer (HPSQ) obtained by allowing hydrolysis of a silicon compound represented by formula (1) and then a condensation reaction of the resulting material, contains Si, O and H, and has, in an infrared spectrum, a ratio (I1/I2) in the range of 0.01 to 0.35 with regard to intensity (I1) of peak 1 at 820 to 920 cm?1 due to a Si—H bond to intensity (I2) of peak 2 at 1000 to 1200 cm?1 due to a Si—O—Si bond, and is represented by general formula SiOxHy (1<x<1.8, 0.01<y<0.4): HSi(R)3 (1), in which R is groups selected from hydrogen, alkoxy having 1 to 10 carbons and the like.
Abstract: There is provided an element which has large dielectric anisotropy and low dielectric loss in a high frequency range, has high reliability, and is used for phase control of an electromagnetic wave signal with a frequency of 1 MHz to 400 THz. An element in which a liquid crystal composition contains a compound represented by the following Formula (1) and has a refractive index anisotropy of 0.
Abstract: A liquid crystal display device having a liquid crystal composition, requiring neither an alignment film nor alignment treatment on a substrate. The problem is solved by a low molecular weight polar compound for homogeneously aligning a liquid crystal medium relative to the substrate, for example, the low molecular weight polar compound represented by formula (1). Formula 95 M-P??(1) In formula (1), M is a nonpolar group having 1 or more carbons, and P is a polar group.
Abstract: A device using a liquid crystal medium exhibiting an optically isotropic liquid crystal phase, particularly, a blue phase liquid crystal medium for polarized light control application, in which reduction of an effective dielectric constant in a high frequency region is suppressed. A liquid crystal composition contains achiral component T, and has a liquid crystal phase optically exhibiting isotropy, in which achiral component T contains at least one compound selected from the group of compounds represented by formula (1) as a first component, at least one compound selected from the group of compounds represented by formula (2) and formula (3) as a second component, and is used for optical switching for controlling retardation by electric field-induced birefringence.
Abstract: The problem is to provide a polymerizable compound having suitable polymerization reactivity, a high conversion ratio, low polymerization starting temperature, and high solubility in a liquid crystal composition; a liquid crystal composition containing the compound; and a liquid crystal display device including the composition. A means thereof includes a compound represented by formula (1) and a liquid crystal composition containing the compound. In formula (1), R1, R2 and R3 are independently alkyl or the like; n is 0 or the like; ring A1 is phenyl or the like, and ring A2 and ring A3 are independently 1,4-phenylene or the like; Z1 and Z2 are independently a single bond or the like; Sp1 to Sp4 are a single bond or the like; a is 1 or the like; c, d and e are independently 0 or 1, and a sum of c, d and e is 1 or the like; and P1 to P4 are a polymerizable group, and at least one of P1 to P4 is a polymerizable group represented by formula (P-1).
Abstract: The subject is to provide liquid crystal display device having a short response time, a large voltage holding ratio, a low threshold voltage, a large contrast ratio, a long service life and a small flicker rate. The liquid crystal display device having a liquid crystal alignment film formed on the opposing surfaces of a pair of substrates, and a liquid crystal composition therebetween, wherein the liquid crystal alignment film includes a polymer derived from a polyamic acid having a photodegradable group, and the liquid crystal composition includes at least one compound represented by formula (1) as a first component: R1 is alkyl having 1 to 12 carbons or the like; ring A is 1,4-cyclohexylene, 1,4-phenylene or the like; Z1 is a single bond or the like; X1 and X2 are hydrogen or fluorine; Y1 is fluorine or the like; and a is 1, 2, 3 or 4.
Abstract: A method for producing a negative electrode active material for lithium ion secondary batteries containing a silicon-titanium oxide composite, which is characterized in that: the silicon-titanium oxide composite contained in the negative electrode active material for lithium ion secondary batteries is obtained by coating a silicon oxide by a titanium oxide; the silicon oxide is obtained by subjecting a polymerized silsesquioxane (PSQ), which has a structure of formula (1) and is obtained by subjecting a silicon compound to hydrolysis and a condensation polymerization reaction, to a heat treatment in an inert gas atmosphere, and is represented by general formula SiOxCyHz (wherein 0.5<x<1.8, 0?y<5 and 0?z<0.4); and after coating the silicon oxide with a titanium oxide, the resulting product is subjected to a heat treatment in a reducing gas atmosphere.
Abstract: Provided are a liquid crystal composition satisfying at least one of characteristics such as high maximum temperature, low minimum temperature, small viscosity, suitable optical anisotropy, large negative dielectric anisotropy, large specific resistance, high stability to ultraviolet light and high stability to heat, or has a suitable balance regarding at least two of the characteristics; and an AM device having characteristics such as a short response time, a large voltage holding ratio, low threshold voltage, a large contrast ratio and a long service life. The liquid crystal composition may contain a specific compound having large negative dielectric anisotropy as a first component, a specific compound having high maximum temperature as a second component, a specific compound having negative dielectric anisotropy as a third component, or a specific compound having a polymerizable group as an additive component.
Abstract: A composition for a secondary battery negative electrode including a carbonaceous material (a) and a silicon oxide structure (b), wherein the silicon oxide structure (b) includes a silicon oxide framework containing Si and O in its atomic composition and silicon-based nanoparticles that are chemically bonded to the silicon oxide framework as components, wherein the silicon oxide structure (b) is contained in a proportion of 15 mass % or more with respect to a total amount of the carbonaceous material (a) and the silicon oxide structure (b), and wherein the silicon oxide structure (b) satisfies the following conditions (i) to (iii): (i) having an atomic composition represented by a general formula SiOx2Hy2 (0.3<x2<1.5, 0.01<y2<0.35), (ii) having Si—H bonds, and (iii) being essentially free of carbon.
Abstract: There are provided a material for a negative electrode active material exhibiting a favorable capacity retention rate and Coulomb efficiency, a method of producing the material, a negative electrode composition using the material, a negative electrode, and a secondary battery. A SiOC structure, includes (A) at least one silicon-based fine particles; and (B) a SiOC coating layer containing at least Si (silicon), O (oxygen), and C (carbon) as constituent elements, wherein the at least one silicon-based fine particles are covered with the SiOC coating layer, and the average particle size based on a volume-based particle size distribution is in a range of 1 nm to 999 ?m.
Abstract: To provide a polar compound having high chemical stability, a high ability to align liquid crystal molecules, and high solubility in a liquid crystal composition, and a high voltage holding ratio of a liquid crystal display element. A compound represented by Formula (1): R1 is a hydrogen atom or an alkyl group that may be substituted; a is 2 to 12; and R2 is Formula (1-a), Formula (1-b), and Formula (1-c); Sp1 to Sp3 are a single bond or an alkylene group that may be substituted; M1 and M2 are H, F, Cl, or an alkyl group that may be substituted; and X1 is —OH, —NH2, —OR3, —N(R3)2, —COOH, —SH or —Si(R3)3.
Abstract: A liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature, a low minimum temperature, a wide temperature range of a liquid crystal phase, a small viscosity, a large optical anisotropy, a large positive or negative dielectric anisotropy, a large specific resistance, a high stability to light, a high stability to heat and a large elastic constant or that is suitably balanced between at least two of these characteristics. The means is use of a liquid crystal composition that includes a specific compound having a high maximum temperature or a small viscosity as a first component, and that may include a specific compound having a large positive dielectric anisotropy as a second component, or a specific compound having a large negative dielectric anisotropy as a third component or a specific compound having a polymerizable group as a first additive.
Abstract: A polar compound having high chemical stability, high capability of aligning liquid crystal molecules, high solubility in a liquid crystal composition, and a large voltage holding ratio when the compound is used in a liquid crystal display device; and a composition containing the compound. The compound is represented by formula (1).
Abstract: The disclosure provides a liquid crystal composition having favorable characteristics and excellent characteristic balance as a material used for an element used for phase control of an electromagnetic wave signal having a frequency of 1 MHz to 400 THz. A liquid crystal composition which is used for phase control of an electromagnetic wave signal having a frequency of 1 MHz to 400 THz, and which includes a compound selected from the group represented by Formula (1), in Formula (1), the ring A0 to the ring A4 are each independently 1,4-phenylene and the like; Z0 to Z3 are each independently a single bond or —CF2O—, where —CF2O— is one or less in Z0 to Z3; p is 0 or 1; and R1 is alkyl having 1 to 12 carbon atoms and the like, and R11 is —CN and the like.
Abstract: The liquid crystal composition having a negative dielectric anisotropy contains two ring compound having a large optical anisotropy and a negatively large dielectric anisotropy as the first component, three ring compound having a large maximum temperature and a large dielectric anisotropy as the second component, three ring compound having a large optical anisotropy and a large dielectric anisotropy as the third component, and two ring compound having a small viscosity as the fourth component. The liquid crystal display device contains the compositions.