Patents Assigned to JOHNSON MATTHEY CATALYSTS (GERMANY) GMBH
  • Patent number: 12024438
    Abstract: The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.
    Type: Grant
    Filed: April 29, 2022
    Date of Patent: July 2, 2024
    Assignees: Johnson Matthey Public Limited Company, Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Juergen Bauer, John Leonello Casci, Ralf Dotzel, Joerg Muench, Ralitsa Purova, Wilhelm Schwieger, Ameen Shahid, Selvam Thangaraj, Tobias Weissenberger
  • Patent number: 12011690
    Abstract: An exhaust system for the treatment of an exhaust gas comprising a species to be treated, the system comprising: a first gas inlet for providing a flow of exhaust gas; a second gas inlet for providing a flow of heated gas; a plurality of sorbent beds for releasably storing the species; one or more catalysts for decomposing the species; first and second exhaust gas outlets; and a valve system configured to establish independently for each sorbent bed fluid communication in a first or second configuration, wherein: i) in the first configuration the flow of the exhaust gas from the first gas inlet contacts a sorbent bed for storing the species and then passes to the first gas outlet; and ii) in the second configuration the flow of heated gas from the second gas inlet contacts a sorbent bed for releasing the species, passes to one of the one or more catalysts and then passes to the second exhaust gas outlet; wherein the valve system is configured to ensure that at least one sorbent bed is in the first configurati
    Type: Grant
    Filed: August 6, 2021
    Date of Patent: June 18, 2024
    Assignees: JOHNSON MATTHEY PUBLIC LIMITED COMPANY, JOHNSON MATTHEY CATALYSTS (GERMANY) GMBH
    Inventors: Joseph Fedeyko, Anthony Ferraro, Kenneth Koehler, Dirk Reichert, Harald Scherbel, Harald Schreiber, Andrew Scullard, Thomas Yeh
  • Patent number: 11634335
    Abstract: The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2.
    Type: Grant
    Filed: January 10, 2020
    Date of Patent: April 25, 2023
    Assignees: Johnson Matthey Public Limited Company, Johnson Matthey Catalysts (Germany) Gmbh
    Inventors: Juergen Bauer, John Leonello Casci, Ralf Dotzel, Joerg Muench, Ralitsa Purova, Wilhelm Schwieger, Ameen Shahid, Selvam Thangaraj, Tobias Weissenberger
  • Patent number: 11181029
    Abstract: An element frame for holding monoliths containing catalysts in the flow of exhaust gases from a combustion source, the element frame comprising two pairs of opposing walls, wherein the walls form a rectangular or square shape, an interior formed by the walls, an inlet end, an outlet end, at least one locking element, at least one mat and at least one monolith comprising an inlet, an outlet, four sides and at least one catalyst effective in reducing the concentration of one or more gases in the exhaust gas, wherein the at least one mat and the at least one monolith being positioned in the interior of the element frame so that there is at least one mat between the monolith and each adjacent wall, each locking element extending across the inlet end or outlet end of the element frame and being connected to two opposite sides of the element frame.
    Type: Grant
    Filed: November 22, 2019
    Date of Patent: November 23, 2021
    Assignee: Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Robert Kleuderlein, Dirk Reichert, Harald Scherbel
  • Patent number: 11179707
    Abstract: A composite material comprises a macroporous silicate-based material at least partially substituted with at least one microporous zeolite, wherein the microporous zeolite is functionalised with either copper, iron or both copper and iron, and wherein the composite material is in the form of particles. The composite material can be obtained using a method comprising the steps of: (i) providing a mixture comprising a silicate-containing scaffold having a macroporous structure, an aluminium source and an organic template; (ii) hydrothermally treating the mixture to form a microporous zeolite-containing structure substantially retaining the macroporous structure of the silicate-containing scaffold; (iii) incorporating copper, iron or both copper and iron into the zeolite. The silicate-containing scaffold can be a diatomaceous earth.
    Type: Grant
    Filed: May 18, 2020
    Date of Patent: November 23, 2021
    Assignee: Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench, Ralitsa Purova, Wilhelm Schwieger, Thangaraj Selvam, Ameen Shahid
  • Patent number: 10926251
    Abstract: A selective catalytic reduction catalyst composition for converting oxides of nitrogen (NOx) in an exhaust gas using a nitrogenous reductant, which catalyst composition comprising a mixture of a first component and a second component, wherein the first component is the H-form of an aluminosilicate chabazite zeolite (CHA); or an admixture of the H-form of an aluminosilicate mordenite zeolite (MOR) and the H-form of an aluminosilicate chabazite zeolite (CHA); and the second component is a vanadium oxide supported on a metal oxide support, which is titania, silica-stabilized titania or a mixture of titania and silica-stabilized titania, wherein the weight ratio of the first component to the second component is 10:90 to 25:75.
    Type: Grant
    Filed: March 26, 2018
    Date of Patent: February 23, 2021
    Assignee: Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Diana Biskupski, Joerg Muench, Irene Piras
  • Patent number: 10828626
    Abstract: A composite material comprises a macroporous silicate-based material at least partially substituted with at least one microporous zeolite, wherein the microporous zeolite is functionalised with either copper, iron or both copper and iron, and wherein the composite material is in the form of particles. The composite material can be obtained using a method comprising the steps of: (i) providing a mixture comprising a silicate-containing scaffold having a macroporous structure, an aluminium source and an organic template; (ii) hydrothermally treating the mixture to form a microporous zeolite-containing structure substantially retaining the macroporous structure of the silicate-containing scaffold; (iii) incorporating copper, iron or both copper and iron into the zeolite. The silicate-containing scaffold can be a diatomaceous earth.
    Type: Grant
    Filed: March 29, 2018
    Date of Patent: November 10, 2020
    Assignee: Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Werner Muench, Ralitsa Purova, Wilhelm Schwieger, Thangaraj Selvam, Ameen Shahid
  • Patent number: 10533475
    Abstract: An element frame for holding monoliths containing catalysts in the flow of exhaust gases from a combustion source, the element frame comprising two pairs of opposing walls, wherein the walls form a rectangular or square shape, an interior formed by the walls, an inlet end, an outlet end, at least one locking element, at least one mat and at least one monolith comprising an inlet, an outlet, four sides and at least one catalyst effective in reducing the concentration of one or more gases in the exhaust gas, wherein the at least one mat and the at least one monolith being positioned in the interior of the element frame so that there is at least one mat between the monolith and each adjacent wall, each locking element extending across the inlet end or outlet end of the element frame and being connected to two opposite sides of the element frame.
    Type: Grant
    Filed: December 7, 2016
    Date of Patent: January 14, 2020
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Robert Kleuderlein, Dirk Reichert, Harald Scherbel
  • Patent number: 10502116
    Abstract: An element frame for holding monoliths containing catalysts in the flow of exhaust gases from a combustion source, the element frame comprising two pairs of opposing walls, wherein the walls form a rectangular or square shape, an interior formed by the walls, an inlet end, an outlet end, at least one locking element, at least one mat and at least one monolith comprising an inlet, an outlet, four sides and at least one catalyst effective in reducing the concentration of one or more gases in the exhaust gas, wherein the at least one mat and the at least one monolith being positioned in the interior of the element frame so that there is at least one mat between the monolith and each adjacent wall, each locking element extending across the inlet end or outlet end of the element frame and being connected to two opposite sides of the element frame.
    Type: Grant
    Filed: December 7, 2016
    Date of Patent: December 10, 2019
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Robert Kleuderlein, Dirk Reichert, Harald Scherbel
  • Patent number: 10500575
    Abstract: A selective catalytic reduction catalyst composition for converting oxides of nitrogen (NOx) in an exhaust gas using a nitrogenous reductant comprises a mixture of a first component and a second component, wherein the first component is an admixture of the H-form of an aluminosilicate mordenite zeolite (MOR) and an iron-promoted aluminosilicate MFI zeolite; and the second component is a vanadium oxide supported on a metal oxide support, which is titania, silica-stabilized titania or a mixture of both titania and silica-stabilized titania, wherein the weight ratio of the first component to the second component is 10:90 to 25:75.
    Type: Grant
    Filed: March 26, 2018
    Date of Patent: December 10, 2019
    Assignee: JOHNSON MATTHEY CATALYSTS (GERMANY) GMBH
    Inventors: Diana Biskupski, Joerg Muench, Irene Piras
  • Patent number: 10500572
    Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibres.
    Type: Grant
    Filed: March 22, 2018
    Date of Patent: December 10, 2019
    Assignee: Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
  • Patent number: 10137433
    Abstract: A catalyst with a porous, ceramic support body having a porosity which is formed by pores in at least a part of the ceramic support body, and which furthermore has a catalytically active washcoat coating applied to the ceramic support body, which catalytically active washcoat coating having a layer thickness, comprises a permanent catalytically inactive impregnation comprising at least one catalytically inactive inorganic component, and wherein the permanent inactive impregnation has a layer thickness and is present at least partially between a surface of the porous ceramic support body and the catalytically active washcoat coating is present in the pores of the ceramic support body in a region with reduced porosity underneath the surface of the ceramic support body.
    Type: Grant
    Filed: December 2, 2016
    Date of Patent: November 27, 2018
    Assignee: JOHNSON MATTHEY CATALYSTS (GERMANY) GMBH
    Inventors: Rainer Leppelt, Jõrg Werner Münch, Dominic Santi
  • Patent number: 9999854
    Abstract: The catalyst module is designed for use in an emission control system of a stationary incinerator. It comprises a stack frame, into which several mounting units are inserted strung together. The mounting units have a peripheral side wall as well as several partitions, which are entangled with one another and form a lattice with a plurality of mounting shafts, in which in each case one catalyst is inserted. The catalysts are pressed into position preferably with the interposition of an elastic fitting element.
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: June 19, 2018
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Robert Kleuderlein, Udo Klumpp
  • Patent number: 9937488
    Abstract: An extruded, solid honeycomb body comprises a copper-promoted, small pore, crystalline molecular sieve catalyst for converting oxides of nitrogen in the presence of a reducing agent, wherein the crystalline molecular sieve contains a maximum ring size of eight tetrahedral atoms, which extruded, solid honeycomb body comprising: 20-50% by weight matrix component comprising diatomaceous earth, wherein 2-20 weight % of the extruded, solid honeycomb body is diatomaceous earth; 80-50% by weight of the small pore, crystalline molecular sieve ion-exchanged with copper; and 0-10% by weight of inorganic fibers.
    Type: Grant
    Filed: January 23, 2015
    Date of Patent: April 10, 2018
    Assignee: Johnson Matthey Catalysts (Germany) GmbH
    Inventors: Juergen Bauer, Ralf Dotzel, Joerg Walter Jodlauk, Rainer Leppelt, Joerg Werner Muench
  • Patent number: 9879584
    Abstract: The catalytic converter apparatus has at least one element box which extends in a longitudinal direction and which has a first pair of first side walls which lie opposite one another, and a second pair of second side walls which lie opposite one another, and two open end sides which lie opposite one another in the longitudinal direction. A plurality of catalytic converter plates are arranged in the element box, which catalytic converter plates are oriented parallel to the first side walls, merely one part of the side walls having a rail which extends transversely with respect to the longitudinal direction on at least one of the end sides, on which rail the catalytic converter plates are supported. As a result, the flow properties of the element box are improved and the risk of dust deposits is avoided.
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: January 30, 2018
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventor: Kai Klinder
  • Patent number: 9803529
    Abstract: A compact Selective Catalytic Reduction (SCR) system comprising a system inlet, a gas flow system and a plurality of catalyst clusters is described. The system inlet is configured to utilize heat of the cleaned exhaust to vaporize a solution of a reductant, or a precursor of a reductant, and to mix the vaporized reductant with exhaust gas to form a mixed gas. The gas flow system is configured to provide the mixed gas from the system inlet to a plurality of catalyst clusters and to provide heat from the exhaust gas to assist in vaporization of the reductant/precursor and to assist in the conversion of the precursor to the reductant. The plurality of catalyst clusters comprise SCR and ASC catalysts but can also include filter functionality.
    Type: Grant
    Filed: March 10, 2015
    Date of Patent: October 31, 2017
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Dirk Reichert, Ilir Piluri
  • Patent number: 9803531
    Abstract: The catalyst module is designed for use in an emission control system of an industrial scale combustion system. It comprises a stack frame, in which several mounting units, especially element boxes are inserted. Each of these is provided with several catalysts. In order to make a simple installation possible and, at the same time, a reliable sealing, the stack frame is assembled from side frame parts, which are connected and especially bolted to one another via mechanical connecting elements, a sealing element, which is inserted during the installation before the connection of the at least one side frame part and pressed against at least one element box with the help of the connecting element, being present at least at a side frame part.
    Type: Grant
    Filed: February 27, 2015
    Date of Patent: October 31, 2017
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Robert Kleuderlein, Udo Klumpp
  • Patent number: 9695725
    Abstract: A compact Selective Catalytic Reduction (SCR) system comprising a gas flow inlet system, a vaporizer module and an SCR reactor is described. The inlet flow system is configured to provide heat to the vaporizer module, to mix reductant with the exhaust gas and to provide an approximately uniform flow of the exhaust gas through the catalyst. The vaporizer module is configured to vaporize reductant from a solution of a reductant or a precursor of a reductant and to transfer the vaporized reductant into the gas flow inlet system, where it is mixed with exhaust gas. The SCR reactor contains and SCR catalyst is in fluid communication with the inlet flow system and the vaporizer module.
    Type: Grant
    Filed: March 10, 2015
    Date of Patent: July 4, 2017
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Dirk Reichert, Daniel Kuegel, Ilir Piluri
  • Patent number: 9616383
    Abstract: A very compact Selective Catalytic Reduction (SCR) system with a very low footprint comprising an SCR reactor, an inlet flow system, and a vaporizer module is described. The SCR reactor comprises at least one SCR catalyst which is in communication with the inlet flow system and the vaporizer module. The inlet flow system is configured to provide an approximately uniform flow of the exhaust gas through the catalyst and to provide heat to the vaporizer module. The vaporizer module is configured to allow for the conversion of urea to ammonia and to contact the ammonia with the exhaust gases in the SCR reactor upstream of the SCR catalyst.
    Type: Grant
    Filed: February 4, 2015
    Date of Patent: April 11, 2017
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Dirk Reichert, Daniel Kuegel, Ilir Piluri
  • Patent number: 9550182
    Abstract: An SCR-active zeolite catalyst and a method for producing same. To produce the catalyst, an Fe ion-exchanged zeolite is initially subjected to a first temperature treatment within a range of 300 to 600° C. in a reducing hydrocarbon atmosphere such that the oxidation state of the Fe ions decreases and/or the dispersity of the Fe ions on the zeolite increases, whereupon the reduced zeolite is subjected to a second temperature treatment within a range of 300 to 600° C. in an oxidizing atmosphere such that hydrocarbon residues or carbon residues are oxidatively removed, the zeolite being calcined to obtain a catalyst material during the two temperature treatments. Iron contained in the zeolite is stabilized in an oxidation state of less than +3 and/or the dispersity of the Fe ions on the zeolite is permanently increased such that a high SCR activity is achieved within a temperature range of less than 300° C.
    Type: Grant
    Filed: August 21, 2010
    Date of Patent: January 24, 2017
    Assignee: Johnson Matthey Catalysts (Germany) GMBH
    Inventors: Jorg Werner Munch, Ralf Dotzel