Abstract: A washcoat showerhead for depositing a washcoat onto a face of a substrate comprises a housing having an inlet for receiving the washcoat, a showerhead plate and a baffle. The housing and showerhead plate define a showerhead cavity with the baffle located within the showerhead cavity. The showerhead plate has a plurality of nozzle apertures for discharging the washcoat towards the face of the substrate. The baffle comprises an impermeable central body and a plurality of arms extending from the impermeable central body, the plurality of arms defining a plurality of flow apertures circumferentially arranged around the impermeable central body.

Abstract: A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first PGM component and a first alumina, wherein the first alumina is doped with a first dopant of at least 5 wt. %, and wherein the first dopant is selected from the group consisting of Zr, Ta, Mo, W, Ti, Nb, and a combination thereof.

Abstract: A compound of formula (I) wherein M is Pd(II) or Ni(II); X is a halide; R1 and R2 are independently organic groups having 1-20 carbon atoms, or R1 and R2 are linked to form a ring structure with the phosphorus atom; R3 is an organic group having 1-20 carbon atoms; provided that R1, R2, R3 are not each phenyl.

Abstract: Catalyst compositions and methods of preparation comprising: exchanging a rare earth element into a molecular sieve; incorporating a promoter metal into the molecular sieve; wherein the rare earth element exchanging step and the promoter metal incorporation step are performed as separate steps.

Abstract: A method of forming an inorganic oxide coating on a monolith article to produce a coated monolith article suitable for the treatment of an exhaust gas comprises spraying, as a dry particulate aerosol, inorganic particles and a silicone resin to form a coating layer. The present invention also provides an uncalcined porous monolith article for use in forming a monolith article for the treatment of an exhaust gas. The uncalcined monolith article comprises a dry particulate composition comprising inorganic particles and a silicone resin.

Abstract: A catalytic article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; a first catalytic region comprising a first platinum group metal (PGM) component and a support; a second catalytic region comprising a second PGM component on a support with low ammonia storage and a first SCR catalyst; and wherein the first catalytic region is covered by at least another catalytic region.

Abstract: A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; a first catalytic region comprising a first platinum group metal (PGM) component, wherein the first PGM component comprises Rh and Pt; a second catalytic region comprising a second PGM component, wherein the second PGM component comprises Pd; and wherein the first PGM component has a Pt to Rh ratio of at least 1:20.

Abstract: Disclosed herein is a method of reducing an aromatic nitro compound. In some embodiments the method comprises the step of contacting an aromatic nitro compound with a catalyst, wherein, the catalyst comprises, a disproportionation agent, and a biocatalyst. Also disclosed is a biocatalyst for use in the method, use of a disproportionation agent, and a biocatalyst, as a catalyst for reducing an aromatic nitro compound, and a kit comprising a disproportionation agent, and a biocatalyst.

Abstract: A system comprising (i) a vehicular compression ignition engine comprising one or more engine cylinders and one or more electronically-controlled fuel injectors therefor; (ii) an exhaust line for the engine comprising: a first emissions control device comprising a first honeycomb substrate, which comprises a hydrocarbon adsorbent component; and a second emissions control device comprising an electrically heatable element and a catalysed second honeycomb substrate, which comprises a rhodium-free platinum group metal comprising platinum, wherein the electrically heatable element is disposed upstream from the catalysed second honeycomb substrate and wherein both the electrically heatable element and the catalysed second honeycomb substrate are disposed downstream from the first honeycomb substrate; a third emissions control device, which is a third honeycomb substrate comprising an ammonia-selective catalytic reduction catalyst disposed downstream from the second emissions control device; and one or more tempera

Abstract: A catalyst gauze and gauze pack comprise a knitted catalyst gauze containing a first layer of a first wire material, wherein the first wire material is made from a platinum-rhodium alloy, and wherein the first layer contains an activator in the form of a second wire material which is knitted among the first wire material, and which is made from un-alloyed platinum.

Abstract: A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Jr and Pt.

Abstract: The present invention relates to improvements in known gold containing catalysts. In particular, the present invention relates to improving the stability and/or inhibition of deactivation of gold containing catalysts via the addition of an inorganic oxide, hydroxide, oxo-salt or oxo-acid. There is also disclosed a method for preparing said catalyst most suitably via an impregnation method. Such catalysts are useful in the production of vinyl chloride monomer.

Abstract: Provided is a composition comprising a ceria-zirconia mixed oxide, the ceria-zirconia mixed oxide being surface-modified with a perovskite type compound of formula (I); wherein formula (I) is defined by Ax-yA?yB1-zB?zO3; where: A is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; A? is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; B is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; B? is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; x is from 0.7 to 1; y is from 0 to 0.5; and z is from 0 to 0.5.

Abstract: Provided is a composition comprising alumina, the alumina being surface-modified with a perovskite type compound of formula (I); wherein formula (I) is defined by Ax-yA?yB1-z B?zO3; where: A is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; A? is an ion of a metal selected from the group consisting of Li, Na, K, Cs, Mg, Sr, Ba, Ca, Y, La, Ce, Pr, Nd, and Gd; B is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; B? is an ion of a metal selected from the group consisting of Cu, Mn, Mo, Co, Fe, Ni, Cr, Ti, Zr, Al, Ga, Sc, Nb, V, W, Bi, Zn, Sn, Pt, Rh, Pd, Ru, Au, Ag, and Ir; x is from 0.7 to 1; y is from 0 to 0.5; and z is from 0 to 0.5.

Abstract: Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.

Abstract: A close-coupled catalytic article, and its use in an exhaust system for internal combustion engines, is disclosed. The close-coupled catalytic article for the treatment of an exhaust gas comprising: an upstream substrate and a downstream substrate, wherein the upstream substrate is spaced apart from the downstream substrate, wherein the upstream substrate comprises a first three-way catalyst (TWC) composition and the downstream substrate comprises a second TWC composition, the first and second TWC compositions each comprising an oxygen storage component (OSC), wherein a loading of the OSC in the downstream substrate is greater than a loading of the OSC in the upstream substrate and is at least 2.2 g/in3.

Abstract: The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.

Abstract: An exhaust system for the treatment of an exhaust gas comprising a species to be treated, the system comprising: a first gas inlet for providing a flow of exhaust gas; a second gas inlet for providing a flow of heated gas; a plurality of sorbent beds for releasably storing the species; one or more catalysts for decomposing the species; first and second exhaust gas outlets; and a valve system configured to establish independently for each sorbent bed fluid communication in a first or second configuration, wherein: i) in the first configuration the flow of the exhaust gas from the first gas inlet contacts a sorbent bed for storing the species and then passes to the first gas outlet; and ii) in the second configuration the flow of heated gas from the second gas inlet contacts a sorbent bed for releasing the species, passes to one of the one or more catalysts and then passes to the second exhaust gas outlet; wherein the valve system is configured to ensure that at least one sorbent bed is in the first configurati

Abstract: The present invention relates to a method of preparing a catalyst article comprising steps: (a) preparing a washcoat composition by combining at least the following components: a support material comprising a mixed oxide, a mixture of oxides or a molecular sieve comprising (i) alumina and (ii) silica and/or zirconia; a metal oxide sol comprising at least one of titania, silica or zirconia; a liquid medium; (b) applying the washcoat composition to a substrate to form a washcoating; and (c) drying and/or calcining the washcoating; wherein the method further comprises a step of impregnating the support material with a platinum group metal component. The prepared catalyst article may be suitable for the treatment of emissions from an internal combustion engine or a gas turbine, for example, the treatment of carbon monoxide and/or formaldehyde emissions from a natural gas fueled internal combustion engine or gas turbine.

Abstract: A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end and an outlet end with an axial length L; and a first catalytic region on the substrate; wherein the first catalytic region comprises a first PGM component and a first alumina, wherein the first alumina is doped with a first dopant of at least 5 wt. %, and wherein the first dopant is selected from the group consisting of Zr, Ta, Mo, W, Ti, Nb, and a combination thereof.