Abstract: An apparatus for the production of formaldehyde is disclosed. The apparatus comprises a cooled tubular reactor section (8, 108, 208, 308, 408, 508) having a first inlet, a first outlet and a plurality of tubes each having a first end in fluid communication with the first inlet and a second end in fluid communication with the first outlet. The plurality of tubes contain a first catalyst for the production of formaldehyde by oxidative dehydrogenation. The apparatus is characterised in that the apparatus further comprises a pre-reactor section (7, 107, 207, 307, 407, 507). The pre-reactor section (7, 107, 207, 307, 407, 507) has an inlet. The pre-reactor section (7, 107, 207, 307, 407, 507) has an outlet in fluid communication with the first inlet of the cooled tubular reactor section (8, 108, 208, 308, 408, 508). The pre-reactor section (7, 107, 207, 307, 407, 507) is configured to contain, in use, an adiabatic catalyst bed.

Abstract: The present disclosure is directed to novel forms of apremilast and pharmaceutical compositions comprising any of the novel forms of apremilast. Also provided are processes for the preparation of novel forms of apremilast.

Abstract: JMZ-5, an aluminosilicate having an SZR framework type and a sea-urchin type morphology is described. A calcined product, JMZ-5C, formed from JMZ-5 is also described. JMZ-6, an aluminosilicate having an SZR framework type and a needle, aggregate morphology is described. A calcined product, JMZ-6C, formed from JMZ-6 is also described. Methods of preparing these zeolites and their metal-containing calcined counterparts are described along with methods of using these zeolites and their metal containing calcined counterparts in treating exhaust gases.

Abstract: A process is described for removing halogen compounds, particularly chlorine compounds, from a process fluid, comprising the steps of (i) passing a process fluid containing hydrogen halide over a first sorbent to remove hydrogen halide and generate a hydrogen halide depleted process fluid and then, (ii) passing the hydrogen halide depleted process fluid over a second different sorbent to remove organic halide compounds therefrom. A purification system suitable for removing hydrogen halide and organic halide compounds from process fluids is also described.

Abstract: A tracer-liner portion comprises an inner tube and an outer tube, each including at least one wall having an internal surface and an external surface, the walls of the inner tube and the outer tube being impermeable to fluid flow, the outer tube having an internal diameter which is larger than the outer diameter of the inner tube, the inner tube being arranged coaxially within the outer tube such that at least a portion of the external surface of the inner tube is covered by the outer tube; the internal diameter of the outer tube exceeds the outer diameter of the inner tube by an amount sufficient to form a space between the external surface of the inner tube and the internal surface of the outer tube, and a tracer material containing a tracer compound is present in the space.

Abstract: A Lithium-transition-metal-phosphate compound of formula Li0.9+xFe1-yMyPO4) in the form of secondary particles made of agglomerates of spherical primary particles wherein the primary particles have a size in the range of 0.02-2 pm and the secondary particles a mean size in the range of 10-40 pm and a BET surface of 16-40 m2/g, a process for its manufacture and the use thereof.

Abstract: A subsea apparatus and method for scanning a subsea structure to detect differences in density between different parts of the subsea structure is described. A source of gamma radiation and a plurality of detectors arranged to detect gamma radiation emitted by the source are provided. The subsea structure is positioned between the source and the detectors, and the detectors and the source rotated in a fixed relationship to each other about an axis of rotation located between the detectors and the source. The plurality of detectors are arranged in a linear array, the linear array being substantially parallel to the axis of rotation. A pixelated detector array and a source container are also disclosed.

Abstract: A process for preparing oxycodone hydrochloride, said process comprising hydrogenating 14-hydroxycodeinone in an alcoholic solvent and hydrochloric acid to form oxycodone hydrochloride, wherein (a) the hydrogenation is carried out in the presence of a heterogeneous platinum group metal (PGM) catalyst and hydrogen gas, (b) the hydrogenation is carried out at one or more temperatures greater than ambient temperature in the presence of a hydrogenation catalyst and hydrogen gas, wherein the solution of 14-hydroxycodeinone and hydrochloric acid is heated to temperature before it is exposed to the hydrogen gas, (c) the oxycodone hydrochloride comprises 6a-oxycodol in an amount < about 0.300 area % as determined by HPLC, characterized in that (d) the pH of the solution of 14-hydroxycodeinone and hydrochloric acid is in the range of about ?2.5 to about ?4.5; (e) the process is carried out in one pot, and (f) the oxycodone hydrochloride precipitates out of the solution.

Abstract: A catalysed substrate monolith 12 for use in treating exhaust gas emitted from a lean-burn internal combustion engine, which catalysed substrate monolith 12 comprising a first washcoat coating 16 and a second washcoat coating 18, wherein the first washcoat coating comprises a catalyst composition comprising at least one platinum group metal (PGM) and at least one support material for the at least one PGM, wherein at least one PGM in the first washcoat coating is liable to volatilise when the first washcoat coating is exposed to relatively extreme conditions including relatively high temperatures, wherein the second washcoat coating comprises at least one metal oxide for trapping volatilised PGM and wherein the second washcoat coating is oriented to contact exhaust gas that has contacted the first washcoat coating.

Abstract: Provided are a novel synthesis technique for producing pure phase aluminosilicate zeolite and a catalyst comprising the phase pure zeolite in combination with a metal, and methods of using the same.

Abstract: The present invention relates to improved processes for the preparation of ruthenium or osmium complexes comprising P and N donor ligands, in particular, ruthenium complexes.

Abstract: A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone comprises a passive NOx adsorber (PNA) comprising a platinum group metal and a base metal, both on a molecular sieve, and an ammonia slip catalyst (ASC) comprising an oxidation catalyst comprising a platinum group metal on a support, and a first SCR catalyst; where the second zone comprises a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer including a blend of: (1) the oxidation catalyst and (2) the first SCR catalyst; and a top layer including a second SCR catalyst, the top layer located over the bottom layer.

Abstract: Alkylated aromatic products are produced in a process comprising the steps of pyrolysing a pyrolysable raw material in a pyrolysis process to obtain a pyrolysis product stream containing a phenolic product and aromatics products; separating the pyrolysis product stream into a first product stream containing phenolic products and a second product stream containing aromatics products; subjecting the first product stream to a hydrogenation reaction to hydrogenate the phenolic product to obtain an aliphatic alcohol; then reacting the aliphatic alcohol with the aromatics products in the presence of a transalkylation catalyst comprising a solid acid catalyst to form an alkylated aromatic product. The alkylated aromatic product may be subjected to further treatment such as hydroprocessing. The alkylated aromatics product may be used in the production of fuels from biomass.

Abstract: The present invention relates to systems and methods for controlling the atmosphere in the cabin (1) of a vehicle. The system comprises a carbon dioxide removal conduit (2) comprising a regenerable carbon dioxide removal chamber (5,6) containing a carbon dioxide sorbent material and a regeneration circuit (7) arranged to expel the desorbed carbon dioxide at a location exterior (8) of the cabin (1) The system is operable to maintain a carbon dioxide level below 1000 ppm in the passenger cabin for a period of at least 5 minutes while restricting the flow of air from outside the vehicle into the passenger cabin to 10 L/s or less.

Abstract: The invention discloses a scanning method and apparatus suitable for scanning a pipeline or process vessel in which a beam of gamma radiation from a source is emitted through the vessel to be detected by an array of detectors which are each collimated to detect radiation over a narrow angle relative to the width of the emitted radiation beam.

Abstract: A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone comprises a passive NOx adsorber (PNA) comprising a platinum group metal and a base metal, both on a molecular sieve, and an ammonia slip catalyst (ASC) comprising an oxidation catalyst comprising a platinum group metal on a support, and a first SCR catalyst; where the second zone comprises a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer including a blend of: (1) the oxidation catalyst and (2) the first SCR catalyst; and a top layer including a second SCR catalyst, the top layer located over the bottom layer.

Abstract: An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.

Abstract: A catalytic wall-flow monolith for use in an emission treatment system comprises a porous substrate and a three-way catalyst (TWC), wherein the TWC is distributed substantially throughout the porous substrate and wherein the TWC comprises: (i) alumina; (ii) one or more platinum group metals; and (iii) an oxygen storage component (OSC), wherein the OSC comprises ceria or one or more mixed oxides comprising cerium and is present in a ratio by weight of OSC to alumina of from 65:35 to 85:15.

Abstract: Exhaust gas catalysts are disclosed. One exhaust gas catalyst comprises a noble metal and a molecular sieve, and has an infrared spectrum having a characteristic absorption peak from 750 cm?1 to 1050 cm?1 in addition to the absorption peaks for the molecular sieve itself. The exhaust gas catalyst also comprises a noble metal and a molecular sieve, having greater than 5 percent of the noble metal amount located inside pores of the molecular sieve. The exhaust gas catalyst also comprises a first and second molecular sieve catalyst. The first molecular sieve catalyst comprises a first noble metal and a first molecular sieve, and the second molecular sieve catalyst comprises a second noble metal and a second molecular sieve. The first and second molecular sieves are different. The invention also includes exhaust systems comprising the exhaust gas catalysts, and a method for treating exhaust gas utilizing the exhaust gas catalysts.

Abstract: Articles comprising a catalyst film comprising VOx, MoO3 or WO3, and TiO2 deposited on a substrate are disclosed. The articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases. Methods for producing such articles deposit a catalyst film on the substrate to form a coated substrate, which is then calcined. When used in an SCR process, the coated articles have enhanced activity for NOx conversion, reduced activity for SOx conversion, or both. Light-weight, coated articles having high catalyst loads can be fabricated at the same or reduced dimensions when compared with laminated articles, and increased kNOx/kSOx ratios are available even from coated articles having relatively thin catalyst films. The articles should have particular value for power plant operations, where coal and high-sulfur fuels are commonly used and controlling sulfur trioxide generation is critical.