Abstract: In some variations, this disclosure provides a surface-modified hydrophobic clay composition for an ink formulation, the composition comprising up to 99 wt % clay particles with a particle-size distribution characterized in that at least 10% are smaller than 0.2 microns, at least 25% are smaller than 0.5 microns, and at least 95% are less than 5 microns; and from about 1 wt % to about 10 wt % of one or more organic compounds selected from quaternary ammonium compounds, organic acids, fatty acids, organic silanes, or organic polysilanes. The surface-modified hydrophobic clay composition may be produced by various methods, including a slurry method or a dry-mixing method. Ink clay loadings in heatset ink formulations may be increased to 10-15% without losing ink gloss. Inks may be produced with lower solvent, resin, and/or pigment concentrations, thereby reducing cost.

Abstract: The present disclosure teaches improved processes to produce high-brightness kaolins at high yields from various natural sources of crude kaolin. In some embodiments, a process for treating mined kaolin comprises: blunging kaolin material with water at high shear to form a slurry; introducing the slurry to one or more beneficiation units for flocculation of titania (e.g., anatase) and titania-associated impurities (e.g., iron); introducing a sodium silicate composition, or precursors thereof, to the beneficiation units, wherein the sodium silicate composition is characterized by a Na2O/SiO2 ratio selected from about 0.25 to about 2.5; and recovering a suspension comprising at least 70% of the kaolin clay. The selected sodium silicate composition enhances flocculation of the titania while maintaining dispersion of the kaolin clay in the slurry. One or more chemical leaching reactions generate a treated kaolin that is characterized by a brightness of about 90 or higher.

Abstract: In some variations, this disclosure provides compositions for reducing fluid permeability through a polymer membrane, the composition comprising a polymer (e.g., bromobutyl rubber) and mineral particles (e.g., kaolin particles) including fine particles with particle sizes between about 0.05 ?m and about 1 ?m and coarse particles with particle sizes between about 3 ?m and about 20 ?m. Applications for these improved-barrier polymers include tire innerliners, paint and paper coatings, films, adhesives, liners, paints, and hoses, for example. Methods of making and use these polymers are also disclosed.