Abstract: The invention relates to a process for wetting a paper web in a calendering step by using water-containing microcapsules in the surface structure layer of the paper web, said microcapsules being ruptured in the calendering step whereby water is released. The invention also relates to microcapsules comprising a water-impermeable shell and an interior substantially comprising water, and having a diameter of 0.1 to 100 .mu.m and a shell thickness of 0.01 to 5 .mu.m.