Abstract: A composition of matter comprising organotitanates having one of the following formulas:(R0).sub.z Ti(A).sub.x (B).sub.y (I)(ro)ti(OCOR').sub.p (OAr).sub.q (II)wherein R is a monovalent alkyl, alkenyl, alkynyl, or aralkyl group having from 1 to 30 carbon atoms or substituted derivatives thereof; A is a thioaroxy, sulfonyl, sulfinyl, diester pyrophosphate, diester phosphate, or a substituted derivative thereof; OAr is aroxy; B is OCOR' or OAr; R' is hydrogen or a monovalent organic group having from 1 to 100 carbon atoms; x+y+z equal 4; p+q equal 3; x, z and q may be 1, 2 or 3; and y and p may be 0, 1 or 2; the reaction products of such organo-titanates and comminuted inorganic material; and polymeric materials containing such reaction products.
Abstract: The invention relates to epoxy resins admixed with cumylphenol or the carboxylic acid ester or the glycidyl ether thereof. The cumylphenol or its derivative serves as an accelerator for amine-cured epoxy systems, as a reactive diluent copolymerizable with epoxy resins, or as a non-reactive plasticizer.
Abstract: Novel organo-titanates, mixtures thereof, and products thereof and inorganic particulate surfaces and methods of making such reaction products. The reaction, which preferably occurs in an organic medium, modifies the inorganic surface by forming a monomolecular organic complex layer. The modified surface causes complete dispersion and improved compatibility of the inorganic particles or fibers in organic media and results in lower viscosity, high inorganic-to-organic ratios than heretofore obtainable, and improved physical properties in polymer systems, and more complete chemical utilization of reactive inorganic compounds.
Abstract: A composition of matter which consists of a filled polyester composition containing specific organo-titanate salts. These salts may be represented by the following formulas:(I) (RO).sub.z Ti(A).sub.x (B).sub.y and (II) (RO)Ti(OAr).sub.p (OCOR').sub.qwhere R is a monovalent alkyl, alkenyl, alkynyl or aralkyl group having from 1 to about 30 carbon atoms or a substituted derivative thereof; A is a monovalent sulfonic, diester pyrophosphate, diester phosphate or a substituted derivative thereof; B is OAr or OCOR'; R' is hydrogen or a monovalent organic group having 1 to about 100 carbon atoms; OAr is aryloxy; the sum of x, y and z equals 4; x and z may be 1, 2 or 3; y may be 0, 1 or 2; and p+q equals 3.Among the advantages of the invention are improved flex modulus, flexural strength, impact strength, better mold flow and higher gloss to molded products. The physical property improvements are maintained after aging even in the presence of steam or boiling water.
Abstract: A composition of matter comprising the reaction product of a comminuted inorganic material and an organo-titanate having the formula (RO)Ti(OCOR').sub.3 wherein R is a monovalent alkyl, alkenyl, alkynyl or aralkyl group having from 1 to 30 carbon atoms or a substituted derivative thereof, R' is a monovalent organic group the total number of carbon atoms in the three R' groups in a molecule being not more than 14; and polymeric materials containing such reaction products.
Abstract: New chelate compounds which are alpha,omega-alkylene titanates having two non-hydrolyzable groups. The compounds may be represented by the formula: ##STR1## where A represents a non-hydrolyzable group, B is an R.sub.2 C group or a carbonyl group, R may be hydrogen or alkyl groups having 1 to 6 carbon atoms and n may be 1 or 2. Preferably R is hydrogen. The R in a particular molecule may be the same or different.The compounds are particularly useful for treating inorganic fillers which are used to extend or modify the properties of polymeric materials. The compounds maintain high activity even when applied to filler containing free water.
Abstract: This invention relates to adducts of tetra-substituted titanates and di-substituted hydrogen phosphites; the use of such adducts for treating particular fillers, including pigments; the compositions of fillers and the aforesaid adducts with epoxy resins and other casting resins; the reaction product of said adducts with aromatic polyamines; the use of said reaction products for curing epoxide and urethane resins; and compositions of certain of the adducts and casting resins. The titanate-phosphite adducts serve to reduce the viscosity of filled epoxy resins, thereby permitting higher filler loading, to enhance the tinctorial power of pigments, and to render casting resins water-extendible. The titanate-phosphite adducts are the reaction products of one mole of a compound having the formula (RO).sub.4 Ti and two moles of di-substituted hydrogen phosphite, (R'O).sub.2 P(O)H, where R and R' are monovalent alkyl, alkenyl, aryl, aralkyl or alkaryl.
Abstract: This invention relates to the use of certain organo-titanium salts for use with fillers for the preparation of epoxy resins and other liquid thermosetting resins; the resulting filled resin compositions; and compositions of such salts and such liquid resins.The organo-titanate salts of the invention may be represented by the formulas:(RO).sub.z Ti(A).sub.x (OAr).sub.y, (I)roti(OAr).sub.3 (II)where R is a monovalent alkyl, alkenyl, alkynyl or aralkyl group having from 1 to about 30 carbon atoms or a substituted derivative thereof; A is a monovalent thioaryloxy, sulfonyl, sulfinyl, diester pyrophosphate, diester phosphate or a substituted derivative thereof; OAr is aroxy or a substituted derivative thereof; the sum of x, y and z equals 4; x and z may be 1, 2 or 3; and y may be 0, 1 or 2; or ##STR1## where A' represents a non-hydrolyzable group as defined above for A or an aryl group, B is an alkylene group (CR.sub.