Abstract: A dry flowable additive for aqueous urea-based fertilizers made of solid urea formaldehyde polymer (UFP), N-(n-butyl)thiophosphoric triamide (NBPT), and, optionally, dicyandiamide (DCD), wherein the liquid fertilizer containing the additive provides reduced nitrogen loss from the soil. Optionally, the dry additive may also be blended with molten or solid urea to form a solid urea-based fertilizer with reduced nitrogen loss from the soil.
Abstract: Reaction products and methods for making and using the same are provided. The reaction products particularly may include adducts of two or more reactants. The adducts particularly can incorporate a nitrification inhibitor, such as DCD. In particular embodiments, reaction products may be formed from the reaction of formaldehyde, DCD, urea, and an ammonia source. The adducts may be included in agricultural products, including fertilizer compositions and nitrification inhibitor systems. Fertilizer compositions including the adducts can be beneficial for reducing leaching of nitrification inhibitors applied to soil.
Abstract: This invention relates to an improved urea-nitrogen stabilizer composition and methods, systems and apparatti for making thereof. The nitrogen stabilizer composition is incorporated into molten urea to result in a composition that contains less biuret, NMP, nitrogen stabilizer and/or impurities and provides an effective solid fertilizer. These compositions are useful in odor control.
Abstract: An improved composition comprising substantial spherical UFP particles and an active agent, such as NBPT, and optionally other components is used as an additive for liquid and solid fertilizers, typically containing urea. Methods of making the compositions and their use are also disclosed.
Type:
Application
Filed:
November 19, 2015
Publication date:
March 17, 2016
Applicant:
Koch Agronomic Services, LLC
Inventors:
Kurt D. Gabrielson, Stacey L. Wertz, Drew R. Bobeck, Allen R. Sutton
Abstract: The present invention provides improved solvent systems for the preparation of liquid formulations of urease or nitrification inhibitors, specifically NBPT, comprising alkylene glycol alkyl ethers. The solvent systems provided good solubility of the urease inhibitor as well as at least one of improved stability, lower flammability, lower toxicity, improved cold temperature storage, improved handling, improved adsorption onto and/or solubility with solid media such as UFP or urea. Methods of making and using the compositions are also provided.
Type:
Application
Filed:
November 25, 2015
Publication date:
March 17, 2016
Applicant:
Koch Agronomic Services, LLC
Inventors:
Kurt D. Gabrielson, Stacey L Wertz, Pablo G Dopico, Drew R. Bobeck
Abstract: Reaction products and methods for making and using the same are provided. In at least one specific embodiment, the fertilizer can include a nitrogen source comprising urea, ammonia, ammonium nitrate, or any combination thereof and a reaction product of formaldehyde, an ammonia source, and a nitrification inhibitor.
Abstract: The present invention provides improved solvent systems for the preparation of liquid formulations of urease inhibitors, specifically NBPT, comprising aryl alkyl alcohols. The solvent systems provided good solubility of the urease inhibitor as well as at least one of improved stability, lower flammability, lower toxicity, improved cold temperature storage, improved handling, improved adsorption onto and/or solubility with solid media such as urea. Methods of making and using the compositions are also provided.
Type:
Grant
Filed:
August 15, 2013
Date of Patent:
December 15, 2015
Assignee:
Koch Agronomic Services, LLC
Inventors:
Kurt D Gabrielson, Stacey L Wertz, Richard P Beatty, Drew R Bobeck
Abstract: The present invention provides improved solvent systems for the preparation of liquid formulations of urease or nitrification inhibitors, specifically NBPT, comprising alkylene glycol alkyl ethers. The solvent systems provided good solubility of the urease inhibitor as well as at least one of improved stability, lower flammability, lower toxicity, improved cold temperature storage, improved handling, improved adsorption onto and/or solubility with solid media such as UFP or urea. Methods of making and using the compositions are also provided.
Type:
Grant
Filed:
August 15, 2013
Date of Patent:
December 1, 2015
Assignee:
Koch Agronomic Services, LLC
Inventors:
Kurt D Gabrielson, Stacey L. Wertz, Pablo G Dopico, Drew R Bobeck
Abstract: A controlled release fertilizer composition and methods to produce the controlled release fertilizer composition. The controlled release fertilizer composition includes a fertilizer core that is coated with a polymeric layer, such as polyurethane, that includes an organic carbonate additive.
Type:
Grant
Filed:
April 30, 2014
Date of Patent:
October 13, 2015
Assignee:
Koch Agronomic Services, LLC
Inventors:
Garrard L. Hargrove, Sriramakrishna Maruvada
Abstract: The present invention relates to novel urea-formaldehyde polymers coated with an active ingredient, a method of making the same, and their use.
Abstract: An improved composition comprising substantial spherical UFP particles and an active agent, such as NBPT, and optionally other components is used as an additive for liquid and solid fertilizers, typically containing urea. Methods of making the compositions and their use are also disclosed.
Type:
Grant
Filed:
August 15, 2013
Date of Patent:
May 19, 2015
Assignee:
KOCH AGRONOMIC SERVICES, LLC
Inventors:
Kurt D Gabrielson, Stacey L Wertz, Drew R Bobeck, Allen R Sutton
Abstract: The present invention provides improved solvent systems for the preparation of liquid formulations of urease inhibitors, specifically NBPT, comprising aryl alkyl alcohols. The solvent systems provided good solubility of the urease inhibitor as well as at least one of improved stability, lower flammability, lower toxicity, improved cold temperature storage, improved handling, improved adsorption onto and/or solubility with solid media such as urea. Methods of making and using the compositions are also provided.
Type:
Application
Filed:
August 15, 2013
Publication date:
February 20, 2014
Applicant:
Koch Agronomic Services, LLC
Inventors:
Kurt D. Gabrielson, Stacey L. Wertz, Richard P. Beatty, Drew R. Bobeck
Abstract: The present invention provides improved solvent systems for the preparation of liquid formulations of urease or nitrification inhibitors, specifically NBPT, comprising alkylene glycol alkyl ethers. The solvent systems provided good solubility of the urease inhibitor as well as at least one of improved stability, lower flammability, lower toxicity, improved cold temperature storage, improved handling, improved adsorption onto and/or solubility with solid media such as UFP or urea. Methods of making and using the compositions are also provided.
Type:
Application
Filed:
August 15, 2013
Publication date:
February 20, 2014
Applicant:
Koch Agronomic Services, LLC
Inventors:
Kurt D. Gabrielson, Stacey L. Wertz, Pablo G. Dopico, Drew R. Bobeck
Abstract: An improved composition comprising substantial spherical UFP particles and an active agent, such as NBPT, and optionally other components is used as an additive for liquid and solid fertilizers, typically containing urea. Methods of making the compositions and their use are also disclosed.
Type:
Application
Filed:
August 15, 2013
Publication date:
February 20, 2014
Applicant:
Koch Agronomic Services, LLC
Inventors:
Kurt D. Gabrielson, Stacey L. Wertz, Drew R. Bobeck, Allen R. Sutton
Abstract: A dry flowable additive for aqueous urea-based fertilizers made of solid urea formaldehyde polymer (UFP), N-(n-butyl) thiophosphoric triamide (NBPT), and, optionally, dicyandiamide (DCD), wherein the liquid fertilizer containing the additive provides reduced nitrogen loss from the soil. Optionally, the dry additive may also be blended with molten or solid urea to form a solid urea-based fertilizer with reduced nitrogen loss from the soil.
Abstract: The present invention provides methods for preparing flowable urea-based granular fertilizers, wherein the urea-based granular fertilizer has become wet; comprising contacting the urea-based granular fertilizer with a conditioner; and optionally other components to form a more flowable urea-base granular fertilizer. Methods for preventing urea-based granular fertilizer caking and urea-based granular fertilizer compositions are also disclosed.
Abstract: A dry flowable additive for aqueous urea-based fertilizers made of solid urea formaldehyde polymer (UFP), N-(n-butyl) thiophosphoric triamide (NBPT), and, optionally, dicyandiamide (DCD), wherein the liquid fertilizer containing the additive provides reduced nitrogen loss from the soil. Optionally, the dry additive may also be blended with molten or solid urea to form a solid urea-based fertilizer with reduced nitrogen loss from the soil.
Abstract: A solid urea fertilizer prepared by mixing a solid, flowable, urea formaldehyde polymer with a urea source, such as molten or solid urea to form a fertilizer that has favorable crush strength characteristics, low biuret content, and/or desirable storage and handling properties. The urea fertilizer may contain additionally, an aqueous urea formaldehyde solution or mixture. Optionally, the fertilizer may contain a urease inhibitor and/or a nitrification inhibitor.
Abstract: A method of odor control comprising applying a urea formaldehyde polymer additive to manure in an amount sufficient to reduce or eliminate odor, wherein the polymer optionally contains NBPT and/or DCD, where the polymer can be a dry solid, or it can be suspended in a liquid and applied to unmanipulated liquid or solid manure.
Type:
Application
Filed:
July 19, 2012
Publication date:
January 24, 2013
Applicant:
KOCH AGRONOMIC SERVICES, LLC
Inventors:
Allen R. Sutton, Martin Case, Timothy J. Healey