Abstract: The photosensitive printing plate of the present invention comprises a substrate, a photosensitive layer formed on the substrate, and mat particles formed on the photosensitive layer, wherein the mat particles contain a copolymer which contains at least one (meth)acrylamides as a unit. The method of producing the photosensitive printing plate of the present invention is a method which comprises the steps of forming a photosensitive layer on a substrate, and coating the photosensitive layer with a solution prepared by dissolving a copolymer containing at least one (meth)acrylamides as a unit in a solvent to form mat particles. The photosensitive printing plate of the present invention has excellent vacuum contact properties and resistance to friction and pressure and is free from tack on the surface when used, avoids problems in developing properties during long storage times, and is superior in terms of solubility in an exhausted developer.
Abstract: A lithographic printing form precursor comprises an imagable coating on a roughened and anodized aluminum support. The precursor is prepared by a process comprising:
(a) anodising an aluminum sheet; and
(b) without having effected a chemical treatment step after the anodising step, applying a composition comprising a polymeric substance to the anodised surface of the aluminum sheet and drying the composition to form the imagable coating thereon, wherein the coating contains a pigment and does not contain a dye.
Undesired staining of the lithographic printing form during development is avoided by using the precursor in the lithographic printing process.
Abstract: A novel fluorinated aromatic acetal polymer comprises at least one unit of A and at least one unit of B or C, or at least one unit of each of A, B and C and optionally further comprises at least one unit of either D or E or at least one unit of each of D and E, wherein the units A and B and/or C, and optionally D and/or E are linked together by single covalent C—C bonds and have the formulae:
wherein RA is H or C1-C11 alky, or an aryl group that does not contain fluorine, and RB and RC are an aryl groups that contain fluorine. The polymer is prepared by reacting a hydrolyzed polyvinyl acetate polymer or copolymer with at least one non-fluorinated aldehyde component, and at least one fluorinated aromatic component. The polymer is useful is preparing a photosensitive composition which comprises at least one diazo resin and at least one such fluorinated aromatic acetal polymer.
Type:
Grant
Filed:
March 8, 2001
Date of Patent:
October 1, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Stephan Platzer, Paul Perron, Melinda Alden
Abstract: A thermally sensitive imaging member can be imaged using thermal energy such as from an IR-emitting laser and then used for lithographic printing. The imaging member includes a support having an ink-repellant subbing layer and a thermally sensitive, ink-repellant surface imaging layer. Imaging causes a “switching” in the exposed surface regions to a more oleophilic or ink-accepting nature. Post-imaging processing is unnecessary in this imaging system. The surface imaging layer includes a thermally sensitive copolymer of silicone “soft” segments and thermally sensitive “hard” segments as well as a photothermal conversion material that is IR radiation sensitive.
Abstract: A radiation-sensitive composition comprises: (i) at least one component capable of absorbing IR radiation; and (ii) a diazonium polycondensation product soluble in an organic solvent; with the proviso that the composition does not contain components capable of reacting with decomposition products produced from IR radiation exposure of the diazonium polycondensation product. The composition may additionally comprise a polymeric binder of the type useful for conventional negative-working printing plates. The composition is suitable for preparing thermally imageable printing plate precursors and printing plates and may also be used in a method for providing an image on such plate precursors and printing plates.
Abstract: A fluid composition suitable for ink jetting upon a substrate, which includes a copolymer having a low surface energy and a plurality of tertiary amine sites, where the tertiary amine sites are at least partially neutralized with an acid; a nonionic or cationic surfactant; and water. The fluid composition may be used to prepare a printable media comprised of a substrate and an ink receptive thermoplastic image layer supported on the substrate; where the ink receptive layer contains a copolymer having a low surface energy and a plurality of tertiary amine sites, the amine sites being at least partially neutralized with an acid.
Type:
Grant
Filed:
February 4, 1999
Date of Patent:
September 24, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Patrice M. Aurenty, Edward Stone, William P. Keaveney
Abstract: A printing plate is prepared by the method comprising: (a) providing a substrate; and (b) applying by ink jetting to the substrate a fluid composition comprising a compound which comprises at least one nitrogen-containing heterocyclic moiety, providing a printing plate that is ready-to-use on a press without having to develop it. The printing plate of this invention is capable of extended press run length and advantageously avoids the need of chemical development.
Type:
Grant
Filed:
January 27, 2000
Date of Patent:
September 17, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Patrice M. Aurenty, Alexander Grant, Jen-Chi Huang, William P. Keaveney, Edward Stone
Abstract: A precursor for electronic parts, for example printed circuit boards, has a negative-working thermally-imagable layer on a substrate, for example a copper board or semiconductor. The layer comprises a cross-linking agent, a thermally-activated acid generator, and a polymeric substance containing polyvinylphenol units and alkyl acrylate units. Such as layer has improved mechanical properties with maintenance of good imaging properties.
Abstract: An imageable element comprises: (A) a substrate; and (B) an imageable composition applied to the substrate comprising: (1) a first layer, comprising: (a) a photosensitive composition capable of absorbing actinic radiation; and (b) a photothermal converter; and (2) an ablatable second layer contiguous to the first layer, wherein the second layer is opaque to the actinic radiation.
This imageable element advantageously is useful in both positive and negative working printing plate applications, increases the efficiency of use of mask-generating radiation such as IR radiation and eliminates the need for chemicals and additional time to create a mask.
Type:
Grant
Filed:
August 4, 2000
Date of Patent:
September 17, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Jayanti Patel, Ken-Ichi Shimazu, Jianbing Huang, Nishith Merchant, S. Peter Pappas
Abstract: An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared using a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer that comprises recurring units comprising quaternary ammonium carboxylate groups. These quaternary ammonium carboxylate groups include at least one substituted-alkylene(C1-C3)-phenyl group. The imaging member can also include an infrared radiation sensitive material to provide added sensitivity to heat that can be supplied by laser irradiation in the IR region. The heat-sensitive polymer is considered “switchable” in response to heat, and provides a lithographic image without wet processing.
Abstract: A thermal imaging member can be imaged using infrared radiation such as from an IR-emitting laser and used for lithographic printing. The imaging member includes a support having an ink-repellant thermally sensitive imaging layer and an ink-repellant surface layer that is swellable in waterless ink solvents. Imaging ablates the imaging and surface layers, but minimal debris is generated so wiping or washing is not required. The imaging layer including a thermally sensitive copolymer of silicone “soft” segments and thermally sensitive “hard” segments, as well as a photothermal conversion material that is IR radiation sensitive.
Abstract: An imaging member, such as a negative-working printing plate or on-press cylinder, can be prepared using a hydrophilic imaging layer comprised of a heat-sensitive hydrophilic polymer that comprises recurring units comprising quaternary ammonium carboxylate groups. The imaging member can also include an infrared radiation sensitive material to provide added sensitivity to heat that can be supplied by laser irradiation in the IR region. The heat-sensitive polymer is considered “switchable” in response to heat, and provides a lithographic image without wet processing.
Abstract: A lithographic printing plate substrate is conditioned for imaging in a printer engine by attaching a leader to the leading edge. The leader is sufficiently flexible to be drawn into the printer engine and is adapted to pull the plate substrate through the printer engine.
Abstract: A method for correcting mistakes and other imperfections in printing members is disclosed. Ink accepting areas of the printing member are rendered non-ink accepting by treatment with a deletion fluid. Deletion fluids include, for example, acids, alkalis, and oxidizing formulations. A preferred deletion fluid is concentrated sulfuric acid.
Type:
Grant
Filed:
November 16, 1999
Date of Patent:
August 6, 2002
Assignee:
Kodak Polychrome Graphics, LLC
Inventors:
Harjit S. Bhambra, Robert M. Organ, Kelvin Dickinson
Abstract: The present invention relates to a planographic printing plate employed in the field of offset printing, and more particularly, to a preparation method for a printing plate employing a conventional planographic printing original plate with a novel light source. In this method, an image is formed to a planographic printing original plate, in which at least one photosensitive layer sensitive in the region of 300 nm˜450 nm is provided on a substrate, by scan irradiating the plate with high density energy light in the form of the image, and then performing wet development and a post-treatment. This preparation method for the printing plate is characterized in that the output wavelength of the high density energy light is within the range of 300 nm or more, but less than 370 nm, and the high density energy light is high density energy light of the second or third harmonic obtained from a solid-state semiconductor or a solid-state exited by semiconductor.
Type:
Grant
Filed:
September 22, 2000
Date of Patent:
July 30, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Shinji Shimizu, Yasuhiko Kojima, Koji Oe
Abstract: A composition used as a resist in the manufacture of electronic parts, for example printed circuits, and which is rendered soluble in a developer by patternwise delivery of heat, comprises a polymer of general formula (I), wherein R1 represents a hydrogen atom or alkyl group, R2 represents a hydrogen atom or alkyl group, R3 represents a hydrogen atom or alkyl group, and R4 represents hydroxyalkyl group, and wherein the ratio n/m is in the range 10/1 to 1/10.
Type:
Grant
Filed:
April 9, 2001
Date of Patent:
July 23, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Anthony Paul Kitson, Peter Andrew Reath Bennett, Kevin Barry Ray
Abstract: An improved hydrophilized substrate for planographic printing is disclosed. The substrate contains a support and a hydrophilic layer over the support. The hydrophilic layer contains titanium dioxide (titania) particles. In one embodiment, the hydrophilic layer contains a mixture of coated and uncoated titanium dioxide particles, and, optionally, alumina particles. A method for preparation of the substrate and a printing member comprising the substrate are also disclosed.
Type:
Grant
Filed:
July 11, 2001
Date of Patent:
July 16, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Joanne Ray, Greg Turner, John Hearson, Denise Howard
Abstract: A positive working lithographic plate precursor comprising a support having a hydrophilic surface and a coating thereon comprising a positive working, photosensitive composition and an aryl alkyl polysiloxane. A method of preparing a positive working lithographic plate precursor comprising coating on a support having a hydrophilic surface a coating comprising, in admixture, a positive working photosensitive composition and an aryl alkyl polysiloxane.
Type:
Grant
Filed:
April 30, 1999
Date of Patent:
July 16, 2002
Assignee:
Kodak Polychrome Graphics LLC
Inventors:
Peter A. R. Bennett, John A. Hearson, Carole-Anne Smith
Abstract: The present invention relates to a printing plate precursor with an overcoat, where the printing plate precursor is preferably developable on a printing press after imagewise exposure. The printing plate precursor comprises the following components:
(a) at least one polymeric organic binder, soluble in water or in organic solvents having a water content of at least 50 wt.