Abstract: The present invention also includes an imageable element, comprising a substrate and a thermally imageable composition comprising a thermally sensitive polymer which exhibits an increased solubility in an aqueous developer solution upon heating. The thermally sensitive polymer includes at least one covalently bonded unit and at least one thermally reversible non-covalently bonded unit, which includes a two or more centered H-bond within each of the non-covalently bonded unit. The present invention also includes a method of producing the imaged element. The present invention still further includes a thermally imageable composition comprising comprising a thermally sensitive polymer according to the present invention and a process for preparing the thermally sensitive polymer, which is a supramolecular polymer.

Abstract: A positive working printing form precursor comprises a thermally imagable composition which includes a hydroxyl group-containing polymer, for example a novolak resin. The composition has a weight of less than 1.1 gm−2. It has been found that using a low weight of the composition on the precursor improves the properties of the precursor, in particular by rendering the sensitivity of the precursor to imaging radiation less variable over time.

Abstract: A method of producing a printing plate comprises: (a) providing a printing plate precursor comprising a topmost etchable first layer and a second layer located below the first layer, wherein the first and second layers have different affinities for at least one printing liquid; (b) imagewise providing atomized fluid particles in an interaction zone located above the surface of the first layer; and (c) imagewise directing laser energy into the interaction zone, wherein the laser energy has a wavelength which is substantially absorbed by the atomized fluid particles in the interaction zone, and the absorption of the laser energy causes the atomized fluid particles to imagewise impart kinetic energy to and etch the first layer. Lithographic and flexographic printing plates may be prepared according to this method, including waterless plates, negative-and positive-working plates, and processless plates.

Abstract: A process for making thermally imageable negative working compositions comprising the steps of:

Abstract: A negative-working image forming process which comprises the steps of:

Abstract: The present invention includes an imageable element, comprising a substrate and a thermally imageable composition which includes a graft copolymer having hydrophobic and hydrophilic segments. Upon imagewise exposure to thermal energy, the graft copolymer produces exposed regions that are less soluble in a developer than the unexposed regions. Also included is a method of producing an imaged element which includes a graft copolymer according to the present invention.

Abstract: The present invention provides an imageable composition, which includes an acid curable composition, an acid generator, an infrared absorber, optionally a colorant, such as, a colorant dye or colorant pigment, wherein at least one of the infrared absorber and the colorant has a counter anion derived from a non-volatile acid, and further optionally, a strong acid. The present invention further provides an imageable element, which includes a substrate and an imageable composition according to the present invention coated on a surface of the substrate. Also provided is method of producing an imaged element according to the present invention.

Abstract: A lithographic printing plate substrate is conditioned for imaging in a printer engine by an edge protector adhered along at least one edge of the plate substrate, the edge protector being of a flexible material, being coextensive with the edge, having face portions adhered to portions of the opposite faces adjacent the edge, and having an edge portion overlying the edge.

Abstract: A printing member, especially a planographic printing member, comprising a first layer which includes a fibrous material, especially a cellulosic fibrous material or a ceramic fibrous material, and a binder, for example a resin or the like, is described. An image defining means is provided over the first layer.

Abstract: The present invention provides an aluminum alloy support body for a presensitized plate in which the uniformity of the grained surface due to electrochemical etching is further improved, and a method of producing the same. The aluminum alloy support body for the presensitized plate according to the present invention has a composition comprising 0.1 to 0.7% by weight of Fe; 0.01 to 0.2% by weight of Si; 0.005 to 1.0% by weight of one or more rare earth elements; and the balance of Al and unavoidable impurities. In the present invention, the aluminum alloy support body may further contain 0.005 to 0.1% by weight of Ni and 0.005 to 0.3% by weight of one or more rare earth elements. One or more elements of Ce, La and Nd can be selected as the rare earth elements.

Abstract: A coating solution useful in the preparation of printing plate precursors comprises:

Abstract: A replenisher composition developing exposed radiation-sensitive printing plate precursors for plate/developer systems in which the electrical conductivity of the developer does not decrease to the same extend as the activity of the developer decreases or even increases is disclosed. A method for developing exposed radiation-sensitive printing plates using the replenisher composition is also disclosed.

Abstract: A method of manufacturing a selectively relief-treated image member that comprises: (a) providing a precursor of the image member, the precursor comprising a surface having an image-forming layer comprising a photosensitive resist composition comprising: (i) a polymerizable material, and (ii) a binder; (b) delivering radiation image-wise to the precursor; (c) developing the precursor in a developer in order to selectively remove the image-forming layer in regions to which said radiation was not delivered image-wise in step (b); and (d) contacting the image-wise exposed precursor with a relief-treatment material, in order to selectively relief-treat regions of the surface of the precursor in which the image-forming layer was removed on development in step (c).

Abstract: A method for developing exposed lithographic printing plate precursors using a developer and replenisher is disclosed. The replenisher contains a higher concentration of a coating attack-suppressing agent than the developer, so that the aggressiveness of the developer remains substantially constant during the developer loading cycle.

Abstract: This invention is directed to a precursor for preparing a resist pattern by heat mode imaging, the precursor comprising a heat sensitive composition, the solubility of which in an aqueous alkaline developer is arranged to increase in heated areas, and a means for increasing the resistance of non-heated areas of the heat sensitive composition to dissolution in an aqueous alkaline developer (the “developer resistance means”), wherein said developer resistance means comprises one or more compounds selected from the group consisting of: (A) compounds which include a poly(alkylene oxide) unit; (B) siloxanes; and (C) esters, ethers and amides of polyhydric alcohols, wherein said heat-sensitive composition comprises an aqueous alkaline developer soluble polymeric substance (i.e. the “active polymer”) and a compound which reduces the aqueous alkaline developer solubility of the polymeric substance (i.e.

Abstract: A precursor which may be imaged by heat is made up of a substrate, for example a copper board, and a composite layer structure composed of two layers. Preferably, the first layer is composed of an aqueous developable polymer mixture containing a photothermal conversion material which is contiguous to the substrate. The second layer of the composite is composed of one or more non-aqueous soluble polymers which are soluble or dispersible in a solvent which does not dissolve the first layer. The precursor is exposed with an infrared laser or a thermal print head, and upon aqueous development, the exposed regions are removed, revealing regions of the substrate surface able to be etched or otherwise treated. The second layer may also contain a photothermal conversion material. Alternatively, the composite layer may be free of photothermal conversion material when thermal imaging is carried out using a thermal print head. The precursor may be used, for example, as a mask precursor or electronic part precursor.

Abstract: Imagable precursors for masks and for electronic parts comprise a polymeric layer applied to a substrate. The layer comprises at least one polymer having infra-red absorbing groups carried as pendent groups on the polymer backbone. Certain infra-red absorbing groups may also act to insolubilize the polymer in a developer, until it is imagewise exposed to infra-red radiation. Imagewise application of heat, resulting from imagewise exposure of the precursor to infra-red radiation, renders the polymer layer more soluble in the developer than prior to exposure to the infra-red radiation.

Abstract: The present invention provides a thermally imageable composition, which includes an acid curable composition, an acid generator, a strong acid and optionally an infrared absorber. The present invention further provides an imageable element, which includes a substrate and a thermally imageable composition according to the present invention coated on a surface of the substrate. Also provided are methods of producing an imaged element according to the present invention.

Abstract: Thermally imageable elements useful as lithographic printing plates, and methods for forming an image using the thermally imageable elements are disclosed. The element contains a support with a hydrophilic surface, an underlayer over the hydrophilic surface, and a top layer over the underlayer. The top layer contains a polymeric material, such as a novolac resin, a resol resin, or a mixture thereof, but does not require a compound that functions as a solubility-suppressing component for the polymeric material. Consequently, the top layer is free of materials that function as solubility-suppressing components for the polymeric material. In one embodiment, the element, preferably the underlayer, absorbs infrared radiation. Following thermal exposure, the element is developed with an aqueous alkaline developer having a pH of at least 7 to about 11, typically about 10.

Abstract: A printing plate is prepared by the process comprising: (a) providing a substrate; and (b) applying by ink jetting to the substrate a fluid composition comprising a cationic polymer and an anionic polymer, in non-aqueous solvent. The ionic polymers interact and adhere to the substrate, so that after drying a durable printing plate is formed, without chemical development. The printing plate of this invention is capable of extended press run length and advantageously avoids the need of chemical development.