Patents Assigned to KRI, Inc.
  • Publication number: 20190367638
    Abstract: Sulfate ester modified cellulose nanofibers having an average fiber diameter in the range of 1 nm to 500 nm, and having sulfate ester modified hydroxyl groups on surfaces of the cellulose nanofibers. A method of producing cellulose nanofibers that are nanosized, that have a high crystallinity degree, and that have large aspect ratios, the method being a chemical method that does not require any physical pulverization, that is energy-saving, and that can be performed under mild reaction conditions. A method of producing modified cellulose nanofibers including modifying the surfaces of the cellulose nanofibers through esterification or urethanization. A method of producing cellulose nanofibers includes impregnating cellulose with a fibrillation solution containing dimethylsulfoxide, at least one carboxylic acid anhydride selected from acetic anhydride and propionic anhydride, and sulfuric acid to fibrillate the cellulose.
    Type: Application
    Filed: January 16, 2018
    Publication date: December 5, 2019
    Applicant: KRI, Inc..
    Inventors: Lianzhen LIN, Masanori HORI, Ayako MARUTA
  • Publication number: 20190194866
    Abstract: A method of producing cellulose fine fibers that are nanosized, that have a high crystallinity degree, and that are less vulnerable to fiber shape damage, the method including impregnating cellulose with a fibrillation solution containing formic acid to fibrillate the cellulose without vigorous mechanical crushing. The method of producing cellulose fine fibers including impregnating the cellulose with formic acid, a high-concentration formic acid aqueous solution, or a solution containing, in an aprotic solvent having a donor number of 26 or more, formic acid or a high-concentration formic acid aqueous solution serving as a fibrillation solution to fibrillate the cellulose. In addition, a method of producing surface-modified cellulose fine fibers including impregnating the cellulose with the fibrillation solution to modify the surfaces of cellulose fine fibers while fibrillating the cellulose.
    Type: Application
    Filed: March 28, 2017
    Publication date: June 27, 2019
    Applicant: KRI, INC.
    Inventors: Lianzhen LIN, Ayako MARUTA, Masanori HORI
  • Publication number: 20190093285
    Abstract: Provided is a method of producing fine cellulose fibers that are nanosized, that have a high crystallinity degree, and that are less vulnerable to fiber shape damage, the method including impregnating cellulose with a fibrillation solution to fibrillate the cellulose without mechanical crushing, and modifying the cellulose. The method of producing cellulose microfibrils of the present invention includes impregnating cellulose with a fibrillation solution containing a carboxylic acid vinyl ester or an aldehyde and an aprotic solvent having a donor number of 26 or more to fibrillate the cellulose. The aldehyde is at least one kind of aldehyde selected from the group consisting of an aldehyde represented by the following formula (1), paraformaldehyde, cinnamaldehyde, perillaldehyde, vanillin, and glyoxal: R1—CHO??(1) where R1 represents a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, an alkenyl group, a cycloalkyl group, or an aryl group.
    Type: Application
    Filed: March 16, 2017
    Publication date: March 28, 2019
    Applicant: KRI, INC.
    Inventors: Lianzhen LIN, Ayako MARUTA, Masanori HORI
  • Publication number: 20180362552
    Abstract: There is provided a betaine-based silicon compound which exhibits the effect of hydrophilizating and defogging a surface. The betaine-based silicon compound is represented by formula (1). X13-m(CH3)mSi—R1—(Y1—R2)n}o—N+(R3)p(R4)q—Y2COO?(1) {In the formula: X1 represents an alkoxy group with 1 to 5 carbon atoms or a halogen atom which may be identical to or different from one another; m represents 0 or 1; R1 represents an alkylene group with 1 to 5 carbon atoms; Y1 represents —NHCOO—, —NHCONH—, —S—, or —SO2—; n represents 0 or 1; R2 represents an alkylene group with 1 to 10 carbon atoms or —CH2CH2N+(CH3)(Y2COO?)CH2CH2OCH2CH2—; o represents 1, 2 or 3; R3 and R4 represent an alkyl group with 1 to 5 carbon atoms which may be identical to or different from one another; Y2 represents —CH2— or the like; p and q represent 0 or 1; provided that o+p+q equals 3.
    Type: Application
    Filed: March 25, 2016
    Publication date: December 20, 2018
    Applicant: KRI, Inc.
    Inventors: Masahiro Satoh, Satsuki Kitajima
  • Patent number: 9200085
    Abstract: There is provided a solvent that can uniformly dissolve a polysaccharide within a short time period regardless of the crystal form of the polysaccharide and without requiring any special pretreatment. The solvent includes a tetraalkylammonium acetate represented by the below-indicated formula; and an aprotic polar solvent. A content of the aprotic polar solvent is 35 wt % or more. In the formula, R1, R2, R3, and R4 each independently represent an alkyl group having 3 to 6 carbon atoms.
    Type: Grant
    Filed: March 22, 2012
    Date of Patent: December 1, 2015
    Assignee: KRI, INC.
    Inventors: Lianzhen Lin, Hideki Yamaguchi, Kaname Tsuchii
  • Patent number: 9147876
    Abstract: A predoping technique considered as highly practicable is an electrochemical method in which predoping is performed by assembling a battery such that an active material (electrode) and lithium are brought into direct contact with each other or short-circuited therebetween via an electric circuit, and by filling an electrolytic solution in the battery. However, in this case, much time is required, and there are problems such as the handling and the thickness accuracy of an extremely thin lithium metal foil that is not greater than 30 ?m thick. By mixing a lithium-dopable material and lithium metal together in the presence of a solvent, such problems can be solved.
    Type: Grant
    Filed: February 11, 2013
    Date of Patent: September 29, 2015
    Assignee: KRI, Inc.
    Inventors: Hisashi Satake, Masanori Fujii, Hajime Kinoshita, Shizukuni Yata
  • Patent number: 9017476
    Abstract: Disclosed is a modified metal oxide sol that has a large hydrophilizing effect and antistatic effect, can be produced at low cost and is capable of being a coating. Specifically disclosed is a modified metal oxide sol characterized by modification by a functional group represented by formula (1) at 0.55-5.5 mmol per 1 g of metal oxide sol. MOS(?O)2—R1—Si(CH3)n(—O—)3-n (1) {In the formula, M is a hydrogen ion, C1-4 alkyl group, metal ion or ammonium (NR24) group; Rl is a C1-10 alkylene group (may have urethane bonds or urea bonds in the main alkylene chain); R2 may be the same or different and is a C1-5 alkyl group or a hydrogen atom; and n represents 0 or 1}.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: April 28, 2015
    Assignee: KRI, Inc.
    Inventors: Masahiro Satoh, Satsuki Kitajima, Daisaku Shojo
  • Patent number: 8778227
    Abstract: The present invention provides an organic/inorganic composite containing an inorganic phase dispersed in an organic polymer, the inorganic phase comprises one or more metal atoms that are coordinated to at least one rare earth metal atom via oxygen. The composite contains at least 5 mass % of rare earth metal. This rare earth metal is dispersed in the inorganic phase.
    Type: Grant
    Filed: April 9, 2012
    Date of Patent: July 15, 2014
    Assignee: KRI, Inc.
    Inventors: Hiroshi Mataki, Toshimi Fukui
  • Publication number: 20140024823
    Abstract: There is provided a solvent that can uniformly dissolve a polysaccharide within a short time period regardless of the crystal form of the polysaccharide and without requiring any special pretreatment. The solvent includes a tetraalkylammonium acetate represented by the below-indicated formula; and an aprotic polar solvent. A content of the aprotic polar solvent is 35 wt % or more. [Chem. 1] In the formula, R1, R2, R3, and R4 each independently represent an alkyl group having 3 to 6 carbon atoms.
    Type: Application
    Filed: March 22, 2012
    Publication date: January 23, 2014
    Applicant: KRI, INC.
    Inventors: Lianzhen Lin, Hideki Yamaguchi, Kaname Tsuchii
  • Publication number: 20130055927
    Abstract: Disclosed is a modified metal oxide sol that has a large hydrophilizing effect and antistatic effect, can be produced at low cost and is capable of being a coating. Specifically disclosed is a modified metal oxide sol characterized by modification by a functional group represented by formula (1) at 0.55-5.5 mmol per 1 g of metal oxide sol. MOS(?0)2—R1—Si(CH3)n(—O—)3-n (1) {In the formula, M is a hydrogen ion, C1-4 alkyl group, metal ion or ammonium (NR24) group; Rl is a C1-10 alkylene group (may have urethane bonds or urea bonds in the main alkylene chain); R2 may be the same or different and is a C1-5 alkyl group or a hydrogen atom; and n represents 0 or 1.
    Type: Application
    Filed: May 11, 2011
    Publication date: March 7, 2013
    Applicant: KRI, INC.
    Inventors: Masahiro Satoh, Satsuki Kitajima, Daisaku Shojo
  • Patent number: 8153026
    Abstract: The present invention provides an organic/inorganic composite containing a rare earth metal or/and Period IV transition metal in which the aforementioned rare earth metal or/and Period IV transition metal is doped at a high concentration, and control of quenching and optical transparency are assured thereby; and an optical amplifier, a light control optical element, and luminescent device utilizing the same. The organic/inorganic composite containing a rare earth metal or/and Period IV transition metal is one in which at least one species of rare earth metal or/and Period IV transition metal is dispersed in an organic polymer, with the aforementioned composite containing an optically transparent organic polymer and an inorganic dispersion phase comprising: (1) a rare earth metal and (2) another element coordinated thereto via an oxygen atom(s).
    Type: Grant
    Filed: March 23, 2010
    Date of Patent: April 10, 2012
    Assignee: KRI Inc.
    Inventors: Hiroshi Mataki, Toshimi Fukui
  • Patent number: 8110303
    Abstract: The invention provides a non-aqueous secondary battery having positive and negative electrodes and non-aqueous electrolyte containing lithium salt which has an energy capacity of 30 Wh or more, a volume energy density of 180 Wh/l or higher, which battery has a flat shape and is superior in heat radiation characteristic, used safely and particularly preferably used for a energy storage system. The invention also provides a control method of the secondary battery.
    Type: Grant
    Filed: August 14, 2006
    Date of Patent: February 7, 2012
    Assignee: KRI Inc.
    Inventors: Shizukuni Yata, Haruo Kikuta, Hajime Kinoshita, Hiroyuki Tajiri, Shiro Kato
  • Publication number: 20100320897
    Abstract: The present invention provides an organic/inorganic composite containing a rare earth metal or/and Period IV transition metal in which the aforementioned rare earth metal or/and Period IV transition metal is doped at a high concentration, and control of quenching and optical transparency are assured thereby; and an optical amplifier, a light control optical element, and luminescent device utilizing the same. The organic/inorganic composite containing a rare earth metal or/and Period IV transition metal is one in which at least one species of rare earth metal or/and Period IV transition metal is dispersed in an organic polymer, with the aforementioned composite containing an optically transparent organic polymer and an inorganic dispersion phase comprising: (1) a rare earth metal and (2) another element coordinated thereto via an oxygen atom(s).
    Type: Application
    Filed: March 23, 2010
    Publication date: December 23, 2010
    Applicant: KRI, INC.
    Inventors: Hiroshi Mataki, Toshimi Fukui
  • Patent number: 7838150
    Abstract: A nonaqueous lithium secondary battery comprising a positive electrode, a negative electrode, and a nonaqueous electrolyte, wherein: 1) the positive electrode comprises a porous carbonaceous material whose BET specific surface area is at least 500 m2/g, or a mixture of a porous carbonaceous material whose BET specific surface area is at least 500 m2/g and a material capable of electrochemically occluding and releasing lithium; and 2) the negative electrode comprises a carbonaceous material whose BET specific surface area is 20 to 1000 m2/g.
    Type: Grant
    Filed: November 7, 2001
    Date of Patent: November 23, 2010
    Assignee: KRI, Inc.
    Inventors: Hajime Kinoshita, Shizukuni Yata
  • Patent number: 7695641
    Abstract: The present invention provides an organic/inorganic composite containing a rare earth metal or/and Period IV transition metal in which the aforementioned rare earth metal or/and Period IV transition metal is doped at a high concentration, and control of quenching and optical transparency are assured thereby; and an optical amplifier, a light control optical element, and luminescent device utilizing the same. The organic/inorganic composite containing a rare earth metal or/and Period IV transition metal is one in which at least one species of rare earth metal or/and Period IV transition metal is dispersed in an organic polymer, with the aforementioned composite containing an optically transparent organic polymer and an inorganic dispersion phase comprising: (1) a rare earth metal and (2) another element coordinated thereto via an oxygen atom(s).
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: April 13, 2010
    Assignee: KRI, Inc.
    Inventors: Hiroshi Mataki, Toshimi Fukui
  • Publication number: 20090270555
    Abstract: The present invention provides a functional filler which is excellent in dispersibility or interaction with polylactic acid as a matrix polymer and can improve heat resistance, moldability and mechanical strength of the polylactic acid; and a resin composition containing the functional filler. The functional filler of the present invention is characterized in including a raw material filler and polylactic acid, wherein a surface or end the raw material filler is modified by the polylactic acid.
    Type: Application
    Filed: September 29, 2006
    Publication date: October 29, 2009
    Applicant: KRI, INC.
    Inventors: Masahiro Satoh, Fengzhe Jin, Yoshikazu Kondo
  • Publication number: 20080287583
    Abstract: The present invention provides an organic/inorganic composite containing a rare earth metal or/and Period IV transition metal in which the aforementioned rare earth metal or/and Period IV transition metal is doped at a high concentration, and control of quenching and optical transparency are assured thereby; and an optical amplifier, a light control optical element, and luminescent device utilizing the same. The organic/inorganic composite containing a rare earth metal or/and Period IV transition metal is one in which at least one species of rare earth metal or/and Period IV transition metal is dispersed in an organic polymer, with the aforementioned composite containing an optically transparent organic polymer and an inorganic dispersion phase comprising: (1) a rare earth metal and (2) another element coordinated thereto via an oxygen atom(s).
    Type: Application
    Filed: June 30, 2005
    Publication date: November 20, 2008
    Applicant: KRI, INC.
    Inventors: Hiroshi Mataki, Toshimi Fukui
  • Patent number: 6921623
    Abstract: A photosensitive resin composition for using in combination with a photosensitizer comprises an active component selected from an active metal alkoxide represented by the formula (1) or a polycondensate thereof and a particle represented by the formula (2), (X)m-n-Mm-[(U1)p—(U2-Z)t]n??(1) P—[(Y)s—{(U1)p—(U2-Z)t}]k??(2) wherein, X shows a hydrogen, a halogen, an alkoxy group or an alkoxycarbonyl group, M shows a metal atom whose valence m is not less than 2, U1 shows a first connecting unit, U2 shows a second connecting unit and Z shows a group causing a difference in solubility by light exposure, P shows a fine particle carrier, Y shows a coupling residue, n shows an integer of not less than 1 and m>n, p shows 0 or 1, t shows 1 or 2, k shows an integer of not less than 1, and s shows 0 or 1).
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: July 26, 2005
    Assignee: KRI, Inc.
    Inventors: Makoto Hanabata, Masahiro Sato, Junko Katayama, Satsuki Kitajima
  • Patent number: 6774541
    Abstract: An element having certain superior piezoelectric characteristics at all times and of which process control in production of the element is relatively easy. In a piezoelectric element in which electrodes 6, 8 are arranged on both face sides of a piezoelectric film 7 respectively, the piezoelectric film is provided with an oxide layer 7a containing 0 or not more than 15 weight percent of Pb arranged on a face of the piezoelectric film, the face being in contact with the electrode, and the oxide layer being formed of a composite oxide expressed by a chemical formula ABO3 or of a solid solution of one or not less than two kinds of composite oxides respectively expressed by the chemical formula ABO3.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: August 10, 2004
    Assignee: KRI, Inc.
    Inventor: Toshimi Fukui