Patents Assigned to Kroff Chemical Company
  • Patent number: 9308474
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Grant
    Filed: June 23, 2014
    Date of Patent: April 12, 2016
    Assignees: KROFF CHEMICAL COMPANY, DOW AGROSCIENCES, LLC
    Inventors: Paul Rey, David M. Sunderlik, Steven P. Ceplecha
  • Patent number: 9034804
    Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for use in fracturing subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: May 19, 2015
    Assignees: KROFF CHEMICAL COMPANY, NABORS COMPLETION & PRODUCTION SERVICES CO.
    Inventors: Paul Rey, Susan Rey, Michael John Seyman, Matthew E. Blauch
  • Patent number: 9034805
    Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of calcium salts in an aqueous composition using the fluid treatment systems or compositions also are provided.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: May 19, 2015
    Assignees: KROFF CHEMICAL COMPANY, NABORS COMPLETION & PRODUCTION SERVICES CO.
    Inventors: Paul Rey, Susan Rey, Michael John Seyman, David Grottenthaler, Matthew E. Blauch
  • Patent number: 8940667
    Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof; and (c) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: January 27, 2015
    Assignees: Kroff Chemical Company, Nabors Completion & Production Services Co.
    Inventors: Paul Rey, Susan Rey, Michael John Seyman, Matthew E. Blauch
  • Patent number: 8871691
    Abstract: Methods of treating flowback water from a subterranean formation penetrated by a well bore are provided, comprising: (a) providing remediated flowback water having a ferrous iron (Fe+2) ion concentration of less than about 100 milligrams of ferrous iron ion per liter of flowback water, a barium ion (Ba+2) concentration of less than about 500 milligrams of barium ion per liter of flowback water, and a calcium ion (Ca+) concentration of at least about 1,000 milligrams of calcium ion per liter of remediated flowback water; and (b) treating the flowback water with: (i) at least one friction reducing agent; and (ii) at least one scale formation inhibiting agent and/or at least one iron precipitation control agent to provide treated flowback water which can be reused as fracturing fluid in a well drilling operation.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: October 28, 2014
    Assignee: Kroff Chemical Company
    Inventors: Paul Rey, Susan Rey, David Grottenthaler
  • Patent number: 8796433
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Grant
    Filed: September 5, 2012
    Date of Patent: August 5, 2014
    Assignees: Kroff Chemical Company, Dow Agrosciences LLC
    Inventors: Paul Rey, David M. Sunderlik, Steven P. Ceplecha
  • Publication number: 20120329915
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Application
    Filed: September 5, 2012
    Publication date: December 27, 2012
    Applicants: Dow Agroscienses LLC, Kroff Chemical Company
    Inventors: Paul Rey, Steven P. Ceplecha, David M. Sunderlik
  • Patent number: 8268975
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: September 18, 2012
    Assignees: DOW Agrosciences LLC, Kroff Chemical Company
    Inventors: Paul Rey, Steve P. Ceplecha, David M. Sunderlik
  • Publication number: 20100256244
    Abstract: The present invention provides compositions, systems and methods for demulsifying an emulsion including an aqueous phase and an organic phase by adding an effective amount of a composition comprising at least one quaternary organopolysiloxane or salt thereof to the emulsion, the composition optionally including at least one of quaternary epihalohydrin/polyamine copolymers or salts, and/or (poly)diallyldimethylammonium halides.
    Type: Application
    Filed: April 3, 2009
    Publication date: October 7, 2010
    Applicants: Kroff Chemical Company, Dow AgroSciences, LLC
    Inventors: Paul Rey, Steven P. Ceplecha, David M. Sunderlik
  • Patent number: 7531600
    Abstract: A storage stable water-in-oil emulsion composition that includes 5% to 99% by weight of a water-in-oil emulsion polymer including a polymer or copolymer containing repeat units from an acrylamide monomer; 0.1% to 10% by weight of one or more inorganic microparticles; 0.5% to 90% by weight of a carrier solvent; and 0 to 90% by weight of a fluidizing agent. The compositions can be used to treat aqueous systems including paper processing, sludge dewatering and for fracturing fluids for subterranean formations.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: May 12, 2009
    Assignee: Kroff Chemical Company
    Inventor: Paul Rey
  • Patent number: 7482310
    Abstract: A method of treating a subterranean formation penetrated by a well bore including: (a) preparing a fracturing fluid containing a mixture resulting from: (I) providing a water-in-oil emulsion composition that includes: (i) 5% to 99% by weight of a water-in-oil emulsion polymer comprising a polymer or copolymer containing repeat units from an acrylamide monomer; (ii) 0.5% to 90% by weight of a carrier solvent; and (iii) 0 to 90% by weight of a fluidizing agent; and adding (iv) 0.1% to 10% by weight of one or more inorganic microparticles, where the total of all components is 100% by weight; and (II) adding the water-in-oil emulsion composition to water; and (b) contacting the subterranean formation with the fracturing fluid.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: January 27, 2009
    Assignees: Kroff Chemical Company, Inc., Superior Well Services, Inc.
    Inventors: Rhys R. Reese, Paul Rey
  • Patent number: 7115201
    Abstract: A method of treating mine drainage water including the step of adding a scale control agent to the mine drainage water and, optionally, adding an oxidizing agent to the mine drainage water and/or precipitating and settling the metals in their hydroxide form from the water. The treated water may be safely returned to the environment.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: October 3, 2006
    Assignee: Kroff Chemical Company, Inc.
    Inventor: Paul Rey
  • Patent number: 6932909
    Abstract: A method of treating mine drainage water including the step of adding a scale control agent to the mine drainage water and, optionally, adding an oxidizing agent to the mine drainage water and/or precipitating and settling the metals in their hydroxide form from the water. The treated water may be safely returned to the environment.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: August 23, 2005
    Assignee: Kroff Chemical Company, Inc.
    Inventor: Paul Rey
  • Publication number: 20050145574
    Abstract: A method of treating mine drainage water including the step of adding a scale control agent to the mine drainage water and, optionally, adding an oxidizing agent to the mine drainage water and/or precipitating and settling the metals in their hydroxide form from the water. The treated water may be safely returned to the environment.
    Type: Application
    Filed: March 7, 2005
    Publication date: July 7, 2005
    Applicant: Kroff Chemical Company, Inc.
    Inventor: Paul Rey