Abstract: Methods of selectively synthesizing n-tetrasilane are disclosed. N-tetrasilane is prepared by catalysis of silane (SiH4), disilane (Si2H6), trisilane (Si3H8), or mixtures thereof. More particularly, the disclosed synthesis methods tune and optimize the n-tetrasilane:i-tetrasilane isomer ratio. The isomer ratio may be optimized by selection of process parameters, such as temperature and the relative amount of starting compounds, as well as selection of proper catalyst. The disclosed synthesis methods allow facile preparation of n-tetrasilane.
Type:
Grant
Filed:
May 10, 2019
Date of Patent:
August 2, 2022
Assignee:
L'Air Liaquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude