Abstract: Methods and systems for producing hydrogen are provided. In one embodiment, a method of producing hydrogen comprises reacting a feed source with steam to produce a gas mixture containing hydrogen and a residue gas; introducing the gas mixture into a purification unit; adsorbing the residue gas; and discharging at least a portion of the hydrogen. The method further comprises depressurizing the purification unit; discharging at least a portion of the residue gas during the depressurization; recycling the residue gas to the feed source; and discharging the residue gas remaining in the purification unit. In another embodiment, the method includes discharging a portion of the residue gas during the depressurization such that the residue gas discharged has a higher hydrocarbon content than the secondary product remaining in the purification unit.

Abstract: A composition and method for a Catalytic Partial Oxidation (CPO) of methane to synthesis gas. The catalyst allows the process to proceed at low residence time providing a long time thermal stability. The perovskite structure [AzA?1-z][B1-x-yNix Rhy] O3-? of the catalyst is obtained using mainly La, Sr, as A and A? cation sites (A, A?: actinide and/or lanthanide, elements and/or elements from Group I and II) and mainly Fe, Ni, as B cation sites (B: transition metal element and/or element from Group III to V).