Patents Assigned to L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude
  • Publication number: 20220357103
    Abstract: Plant and method for liquefying a flow of gas, comprising a cooling circuit which is provided with an upstream end which is intended to be connected to a source of pressurised gas to be liquified and a downstream end which is intended to be connected to a user member, the plant comprising, between the upstream and downstream ends, a set of members which are intended to liquefy the gas and comprise at least one exchanger for cooling the gas, and at least one expansion turbine which is mounted on a rotary axle which is supported by at least one bearing of the gas-static type, the cooling circuit comprising a pressurised gas injection conduit having an upstream end which is intended to receive pressurised gas supplied by the source and a downstream end which is connected to the bearing in order to provide support to the rotary axle, the plant comprising a conduit for recovering the gas which has been used in the bearing, the conduit for recovering the gas comprising an upstream end which is connected to the bear
    Type: Application
    Filed: June 8, 2020
    Publication date: November 10, 2022
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Pierre BARJHOUX, Fabien DURAND, Franck DELCAYRE
  • Patent number: 11491437
    Abstract: A process for the production of a hydrogen gas stream having a CO content of less than 1 ppm having a production cycle comprising two phases: phase 1 includes a) purifying a synthesis gas in a PSA unit, b) recovering a hydrogen gas stream comprising a CO content of greater than 1 ppm, c) purifying the gas stream by adsorption in a TSA unit, and recovery a hydrogen gas stream exhibiting a CO content of less than 1 ppm, and phase 2 includes e) purifying the synthesis gas in a PSA unit, f) recovering a hydrogen gas stream having a CO content of less than 1 ppm, where throughout steps e) and f), the TSA unit is bypassed by the hydrogen gas stream and is regenerated.
    Type: Grant
    Filed: July 13, 2018
    Date of Patent: November 8, 2022
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Daniel Gary, Laurent Allidieres
  • Patent number: 11493175
    Abstract: A hydrogen refilling station for filling tanks of fuel cell electric vehicles includes a liquid hydrogen tank that feeds liquid hydrogen to an upstream end of a filling circuit that also includes a heat exchanger. The heat exchanger exchanges heat between the liquid hydrogen and heat transfer fluid flows to thereby cool the heat transfer fluid and vaporize the liquid hydrogen to provide a supply of high pressure hydrogen gas for filling hydrogen-fueled vehicle tanks at a downstream end of the circuit. Because the liquid hydrogen is surrounded by the heat transfer fluid inside the heat exchanger, little if any fogging occurs.
    Type: Grant
    Filed: December 22, 2020
    Date of Patent: November 8, 2022
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Vincent Fairy
  • Patent number: 11484826
    Abstract: The invention relates to a gas scrubbing process for purifying crude synthesis gas with methanol as a physical absorption medium, wherein an acid gas comprising at least hydrogen sulfide (H2S) is produced. The acid gas is produced in a hot regenerator arranged downstream of an absorption apparatus and subsequently separated from gaseous methanol in an acid gas separator by cooling and condensation. The acid gas separator has a condensation region and an absorption region, wherein both regions are separated from one another by a gas-permeable tray. This has the result that impurities such as hydrogen cyanide and/or ammonia outgassing from a first acid gas substream are not reabsorbed in the condensation region of the acid gas separator, thus avoiding an accumulation of impurities in the hot regenerator or other parts of the gas scrubbing plant. The invention further relates to an acid gas separator and to the use of the acid gas separator according to the invention in a process according to the invention.
    Type: Grant
    Filed: September 27, 2019
    Date of Patent: November 1, 2022
    Assignee: L'Air Liquide, Société Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Sharon Corbet, Alfred Gubrinski, Pankaj Puri, Dorit Rappold, Sophia Schmidt
  • Patent number: 11485634
    Abstract: Method and plant for generation of synthesis gas, comprising the steps of air fractionation to give oxygen, nitrogen and tail gas, gasification of a hydrocarbonaceous fuel to give crude synthesis gas and cleaning of the crude synthesis gas by removal of acid gas by means of cryogenic absorption, wherein the absorbent is cooled by means of a compression coolant circuit and the cooling water used is cooled by evaporative cooling by means of the tail gas obtained in the air fractionation.
    Type: Grant
    Filed: November 20, 2017
    Date of Patent: November 1, 2022
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Lucie Chaubet, Frederic Bonne, Camille Bouet, Holger Schlichting, Marc Wagner
  • Patent number: 11480301
    Abstract: Cryogenic fluid storage tank comprising a pipe for drawing off vaporized gas, which pipe is connected to a first casing and comprises a vaporizer and at least one control valve, a first filling pipe connected to the lower portion of the first casing, a second pipe for filling a downstream end connected to the upper portion of the first casing, a distribution valve assembly configured to enable distribution of the fluid from the fluid source in the filling pipes, a pressurization pipe connected to the lower end of the first casing and a second end connected to the upper portion of the first casing and at least one control valve and a heater, the tank further comprising an air vent regulator, the valve assembly for distribution in the filling circuit, the valve for controlling the pressurization pipe, the valve for controlling the drawing-off circuit and the air vent regulator being integrated into the same valve module, which shares at least one valve element.
    Type: Grant
    Filed: November 25, 2019
    Date of Patent: October 25, 2022
    Assignee: L'Air Liquide, Société Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Olivier Beuneken, Didier Geneste, Regis Pointeau
  • Patent number: 11482414
    Abstract: Disclosed is a method for forming Si-containing films, such as SiN film, by PEALD using trisilylamine (TSA) at ultralow temperature, such as a temperature below 250° C.
    Type: Grant
    Filed: December 18, 2019
    Date of Patent: October 25, 2022
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Naoto Noda, Ivan Oshchepkov, Jean-Marc Girard
  • Publication number: 20220333828
    Abstract: Low-temperature refrigeration device arranged in a frame and comprising a working circuit forming a loop and containing a working fluid, the working circuit forming a cycle comprising in series: a compression mechanism, a cooling mechanism, an expansion mechanism and a heating mechanism, the device comprising a refrigeration heat exchanger intended to extract heat from at least one member by exchanging heat with the working fluid, the mechanisms for cooling and reheating the working fluid comprising a common heat exchanger in which the working fluid transits in counter-flow in two separate transit portions of the working circuit, the compression mechanism comprising at least two compressors and at least one motor for driving the compressors, the working fluid expansion mechanism comprising at least one rotary turbine, the device comprising at least one drive motor comprising a drive shaft, one end of which drives a compressor and the other end of which is coupled to a turbine, the motor being attached to the
    Type: Application
    Filed: July 8, 2020
    Publication date: October 20, 2022
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Fabien DURAND, Guillaume DELAUTRE
  • Publication number: 20220333830
    Abstract: Refrigeration device intended to extract heat from at least one member by heat exchange with a working fluid circulating in the working circuit comprising in series: a fluid compression mechanism a fluid cooling mechanism, preferably isobaric or substantially isobaric, a fluid expansion mechanism, and a fluid heating mechanism, in which device the compression mechanism is of the centrifugal compression type and consists of two compression stages arranged in series in the circuit, the device comprising two respective electric drive motors driving the two compression stages, the expansion mechanism consisting of a turbine coupled to the motor of one of the compression stages, the turbine of the expansion mechanism being coupled to the drive motor of the first compression stage.
    Type: Application
    Filed: July 5, 2022
    Publication date: October 20, 2022
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Fabien DURAND
  • Publication number: 20220333859
    Abstract: Disclosed is a low-temperature refrigeration device which is arranged in a frame and comprises a working circuit that forms a loop and contains a working fluid, the working circuit forming a cycle comprising, connected in series: a compression mechanism, a cooling mechanism, an expansion mechanism and a heating mechanism, wherein the mechanisms for cooling and heating the working fluid comprise a common heat exchanger in which the working fluid flows in opposite directions in two separate transit portions of the working circuit, the device further comprising a refrigeration heat exchanger for extracting heat from at least one member by exchanging heat with the working fluid flowing in the working circuit, the compression mechanism comprising two separate compressors, the mechanism for cooling the working fluid comprising two cooling heat exchangers which are arranged respectively at the outlet of the two compressors and ensure heat exchange between the working fluid and a cooling fluid, wherein the frame exte
    Type: Application
    Filed: July 8, 2020
    Publication date: October 20, 2022
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Fabien DURAND, Guillaume DELAUTRE
  • Publication number: 20220325853
    Abstract: A liquefied fuel cryogenic tank has an inner jacket delimiting a fluid storage volume and an outer jacket disposed around the inner jacket with a vacuum thermal insulation gap therebetween. A withdrawal circuit has an assembly of one or more valves and a withdrawal line that has a first heating heat exchanger located outside the inner jacket and a second heating heat exchanger located inside the inner jacket. Fluid flows through the withdrawal line via the first heat exchanger and then the second heat exchanger or via the first heat exchanger without entering the second heat exchanger.
    Type: Application
    Filed: April 13, 2022
    Publication date: October 13, 2022
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Laurent ALLIDIERES, Jerome LOSCO
  • Publication number: 20220325952
    Abstract: An apparatus for producing product nitrogen gas and product argon, comprising: a first rectification column into which raw air is introduced; a second rectification column from which product nitrogen gas is drawn; a third rectification column from which product argon gas is drawn; and a first condenser configured to perform heat exchange between a gas accumulated in a column top portion of the first rectification column, and a liquid accumulated in a column bottom portion of the second rectification column, wherein an intermediate portion gas containing nitrogen is drawn from an intermediate portion of the second rectification column and merged with a condenser gas drawn from the first condenser. The merged gases are expanded and cooled by means of an expansion turbine whereby the cold thereof is utilized.
    Type: Application
    Filed: June 27, 2022
    Publication date: October 13, 2022
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Kenji HIROSE, Maxime RANCHOUX, Shinji TOMITA, Loic JOLY
  • Patent number: 11465127
    Abstract: An adsorbent bed, including at least one elementary composite structure that includes adsorbent particles in a polymer matrix, wherein the adsorbent bed has a bed packing, ?bed, defined as a volume occupied by the at least one elementary composite structure Vecs divided by a volume of the adsorbent bed Vbed where ?bed is greater than 0.60.
    Type: Grant
    Filed: July 11, 2020
    Date of Patent: October 11, 2022
    Assignees: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Philippe A. Coignet, Dean W. Kratzer, Antoine Pruvot, Federico Brandani, Matthew Metz, Elise Renou
  • Patent number: 11460336
    Abstract: A method of providing electrical energy to a dewar containing a cryogenic liquid including introducing an insulated heat pipe, with a distal end and a proximal end, into a cryogenic dewar comprising an exterior surface. And providing a Seebeck module, with a cold junction and a hot junction. The distal end is in thermodynamic contact with a cryogenic fluid and the proximal is thermodynamically connected to the cold junction. The hot junction is thermodynamically connected to the exterior surface of the dewar, thereby producing an electrical flow in the Seebeck module. A level probe may be calibrated by taking a first capacitance reading with the dewar full, and a second capacitance reading when the cryogenic liquid level is within a calibration gap. The level probe is calibrated by utilizing the first capacitance reading and the second capacitance reading.
    Type: Grant
    Filed: October 16, 2020
    Date of Patent: October 4, 2022
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Alizent USA, Inc.
    Inventors: Alain Lecours, Celine Tranquillin, Felix H. Tang
  • Patent number: 11460422
    Abstract: The invention provides a method for on-site monitoring of the quality of the gases delivered to a consumer site, the monitoring being carried out during the delivery, in order to declare the delivery compliant or non-compliant with specifications, being characterized in that, during the delivery, a monitoring of the gas(es) delivered is carried out by the thermal conductivity technique.
    Type: Grant
    Filed: January 30, 2019
    Date of Patent: October 4, 2022
    Assignees: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, CARBAGAS
    Inventor: Heinz Peyer
  • Publication number: 20220297055
    Abstract: Process and plant for membrane permeation treatment of a carbon dioxide and methane-containing biogas stream in which the biogas stream is compressed with a compressor and the compressed biogas stream is fed to a membrane separation unit comprising first and second modules each containing at least one membrane selective for carbon dioxide over methane. The first module separates the compressed biogas stream into a first, second, and third methane-deficient permeates (in comparison to the biogas stream) and a first methane-enriched retentate (in comparison to the biogas stream). The first permeate being richer in methane than the second or third permeates. The second module separates the first permeate into a fourth methane-deficient permeate and a second methane-enriched retentate. The second and third retentates are recycled back to an inlet of the compressor.
    Type: Application
    Filed: March 22, 2022
    Publication date: September 22, 2022
    Applicant: L'Air Liquide Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventor: Francois BARRAUD
  • Publication number: 20220298443
    Abstract: Methane and carbon dioxide-containing feed gas stream is compressed and cooled to condense and remove a portion of water therein, separated with a membrane separation unit into a permeate enriched in carbon dioxide and a biomethane stream scrubbed of CO2 that is subsequently scrubbed of water in an adsorption purification unit.
    Type: Application
    Filed: March 22, 2022
    Publication date: September 22, 2022
    Applicant: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Youssef TAZI, Laura AYRAULT, Veronique GRABIE
  • Patent number: 11441839
    Abstract: According to an embodiment of the invention, nitrogen gas of an air separation unit is used to cool the gas formed in a reservoir of liquid from an MEOH unit that is supplied with oxygen by said air separation unit.
    Type: Grant
    Filed: August 31, 2017
    Date of Patent: September 13, 2022
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Alexis Asse, Tobias Oelmann
  • Patent number: 11441840
    Abstract: Plant for the production of argon by cryogenic distillation, comprising an argon separation column, means for sending a gas containing argon and oxygen to the argon separation column, means for extracting a fluid enriched in argon at the top of the argon separation column, means for extracting a liquid enriched in oxygen at the bottom of the argon separation column and at least two storage tanks, positioned one above the other, each storage tank being connected to two different intermediate levels of the argon separation column by two pipes, the two storage tanks being contiguous.
    Type: Grant
    Filed: July 31, 2019
    Date of Patent: September 13, 2022
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Alain Briglia, Frederic Staine, Mathieu Leaute, Ingrid Berthaume, Benedicte Dos Santos
  • Patent number: 11441841
    Abstract: A heat exchanger assembly and a method for assembling the heat exchanger assembly is provided.
    Type: Grant
    Filed: December 21, 2019
    Date of Patent: September 13, 2022
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation des Procedes Georges Claude
    Inventor: Remy Kurtz