Patents Assigned to L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
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Patent number: 12163627Abstract: Method for delivering liquefied gas, especially hydrogen, by means of at least one mobile storage facility, especially a storage facility transported by lorry, comprising a step of filling the mobile storage facility with liquefied gas at a source plant, the mobile storage facility containing, after filling, liquefied gas and a fraction of the vaporized gas, the method comprising a movement of the mobile storage facility from the source plant to a receiving station and a transfer of liquefied gas from the mobile storage facility to the receiving station, characterized in that it comprises a step of interim cooling of the liquefied gas contained in the mobile storage facility between the source plant and the receiving station by means of a cooling device comprising a liquefied gas tank and a refrigerating element.Type: GrantFiled: February 5, 2021Date of Patent: December 10, 2024Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Laurent Allidieres, Thomas Fayer, Pierre Barjhoux
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Patent number: 12163741Abstract: A heat exchanger having multiple plates which are mutually parallel and parallel to a longitudinal direction, the exchanger having a length measured in the longitudinal direction, the plates being stacked with spacing so as to define a first series of passages for the flow, in a general flow direction parallel to the longitudinal direction, of at least a first refrigerant fluid and a second refrigerant fluid, at least one passage of the first series being defined between two adjacent plates.Type: GrantFiled: July 23, 2020Date of Patent: December 10, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Natacha Haik-Beraud, Sophie Lazzarini
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Patent number: 12158244Abstract: A device for filling pressurized gas tanks, including a fluid transfer circuit having an upstream end connected to a plurality of sources of pressurized fluid and a downstream end having at least one dispenser intended to be connected to a tank to be filled, the sources being connected in parallel, each source has a fluid outlet connected to a respective outlet valve, the transfer lines being connected in parallel to the at least one dispenser and each having a respective transfer valve, the transfer lines and the transfer valves being dimensioned so as to transfer a maximum transfer gas flow which is smaller than the maximum filling gas flow, the sum of a plurality of maximum transfer gas flows provided by a plurality of outlet valves and a plurality of transfer lines being greater than or equal to the maximum filling gas flow.Type: GrantFiled: March 23, 2021Date of Patent: December 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Benjamin Fischer, Herve Paoli
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Patent number: 12158242Abstract: A tank for storing liquefied gas, having a shell delimiting a storage volume extending in a main direction which is horizontal in the use configuration of the tank, the tank comprising multiple deflecting walls in the storage volume which extend in an offset manner in the main direction configured to force the fluid to perform at least one back-and-forth movement in the main direction as the fluid passes between the lower end and the upper end of the storage volume, wherein a plurality of these deflecting walls are located in the lower half of the storage volume.Type: GrantFiled: May 3, 2021Date of Patent: December 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Jean-Marc Bernhardt
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Patent number: 12158245Abstract: A cryogen storage vessel at an installation is filled with liquid cryogen from a liquid cryogen storage tank that has a pressure lower than that of the vessel. After headspaces of the vessel and tank are placed in fluid communication with another via a gas transfer vessel and are pressure-balanced, a pump in a liquid transfer line connected between the tank and the vessel is operated to transfer amounts of liquid cryogen from the tank to the vessel via the liquid transfer line and pump as amounts of gaseous cryogen are transferred, through displacement by the pumped cryogenic liquid, from the vessel to the tank. Following filling, the tank is disconnected and then driven to another location to repeat the filling process with a second vessel that is at a different location.Type: GrantFiled: November 22, 2022Date of Patent: December 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
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Patent number: 12152834Abstract: A system and method for supplying a backup product in an air separation device, as well as a system and method for supplying a lower-pressure product to a user by means of pressurization of a cryogenic liquid pump during normal operation of an air separation device, i.e., when the cryogenic liquid pump is in the cold standby state. By means of the system and method, a cryogenic liquid product taken from a storage tank is pressurized by the cryogenic liquid pump to produce a lower-pressure product by taking full advantage of the low-speed operation of the cryogenic liquid pump in the cold standby state, and the lower-pressure product is transmitted to product supply lines of a user, to achieve the function of supplying the lower-pressure product to the user.Type: GrantFiled: December 26, 2017Date of Patent: November 26, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Haozhuan Zheng, Fei Gao
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Patent number: 12135165Abstract: A method for liquefying a hydrocarbon stream using a heat exchanger having a plurality of plates parallel to each other and to a longitudinal direction that is substantially vertical, the exchanger having a length measured in the longitudinal direction, the plates being stacked with spacing so as to define between them at least one first series of passages for the flow of at least part of a two-phase cooling stream vaporizing by exchanging heat with at least the hydrocarbon stream.Type: GrantFiled: July 21, 2020Date of Patent: November 5, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Natacha Haik-Beraud, Jean-Marc Peyron, Sophie Lazzarini, Thomas Morel
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Furnace for endothermic process and process for operating a furnace with improved burner arrangement
Patent number: 12130012Abstract: The invention relates to a furnace for performing an endothermic process, the furnace including a plurality of process tubes containing a catalyst for converting a gaseous feed, wherein the process tubes are arranged in rows within the furnace, each row of process tubes thereby defining a process tube row, a plurality of inner burners arranged in rows, each row of inner burners being arranged between and parallel to process tube rows, thereby defining an inner burner row, and a plurality of outer burners arranged in rows, each row of outer burners being arranged between and parallel to a process tube row and a furnace wall, thereby defining an outer burner row. A number of burners of an outer burner row is smaller than a number of burners of an inner burner row. The invention also relates to a process for operating a furnace for performing an endothermic process.Type: GrantFiled: October 28, 2019Date of Patent: October 29, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Philippe Tadiello, Diana Tudorache -
Patent number: 12123645Abstract: An installation and method for purifying and liquefying natural gas having, arranged in series, an adsorption purification unit, a unit for separating hydrocarbons by refrigeration, and a liquefier. The installation has a gas power plant for combined production of heat and electricity by hydrocarbon combustion. The installation has at least one electrical member, with the power plant being electrically connected to at least one of the electrical members in order to supply them with electrical energy.Type: GrantFiled: September 12, 2019Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Marc Bernhardt, Golo Zick, Rémi Nicolas
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Patent number: 12123418Abstract: In a compression process in a dynamic compressor having at least one first and one second compression stages, a first gas having a first molecular weight of less than 10 g/mol is compressed, at least one second fluid having a second molecular weight greater than 50 g/mol is mixed with the first gas to form a third gas to be compressed having a molecular weight greater than 10 g/mol, the third gas is sent to the first compression stage, the third gas is cooled in a first heat exchanger downstream of the first compression stage, where it is partially condensed, the partially condensed third gas is sent to a first phase separator to form a fourth gas having a lower molecular weight than the third gas and a first condensed liquid having a higher molecular weight than the third gas, the fourth gas is sent from the first phase separator to the second compression stage, the fourth gas compressed in the second compression stage is sent to cool in a second heat exchanger where it partially condenses, and the partiallyType: GrantFiled: July 20, 2020Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Patrick Le Bot
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Patent number: 12123540Abstract: A detachable coupling device with automatic closure for the transport of fluid, including two fluid transport pipes extending in a longitudinal direction and each having, at one connection end, a valve mechanism, the device also including an external tube disposed around each transport pipe and, in the coupled position, the two connection ends are configured to be relatively longitudinally displaceable between a first configuration, in which the valve mechanisms are closed, and a second configuration, in which the valve mechanisms are open, the transition from the first configuration to the second configuration being realized by a relative longitudinal movement of the two valve mechanisms close to one another.Type: GrantFiled: November 15, 2022Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Gaëtan Coleiro, Yan Pennec
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Patent number: 12121931Abstract: An ultraviolet curing apparatus having: a roller for guiding a film coated with a resin; a first nitrogen gas introduction port and a second nitrogen gas introduction port for introducing nitrogen gas; a UV irradiation portion for irradiating the film with ultraviolet rays from between the first nitrogen gas introduction port and the second nitrogen gas introduction port; an oxygen concentration meter for measuring an oxygen concentration between the film and the UV irradiation portion; an air introduction port for introducing air between the film and the UV irradiation portion; and a controller for controlling at least any one of: an amount of air introduced from the air introduction port, an amount of nitrogen gas introduced from the first nitrogen gas introduction port, and an amount of nitrogen gas introduced from the second nitrogen gas introduction port, so that the oxygen concentration is within a preset oxygen concentration set range.Type: GrantFiled: August 9, 2022Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Kohei Nakatani, Tadasu Nakatani, Eiichi Mizutani
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Patent number: 12117127Abstract: A conditioning device for engaging with a filling and/or tapping connector of a pressurized-fluid container cock, including a body bearing at least one coupling member arranged about a longitudinal axis, a locking member which is movable with respect to the body and with respect to the coupling member, a valve pusher which is movable in a gas transfer duct, and a blocking member, wherein the upstream face of the blocking member includes a tightness seal arranged about the longitudinal axis to form sealing between the gas transfer duct and an internal circuit of a filling connector.Type: GrantFiled: September 8, 2020Date of Patent: October 15, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Antoine Frenal
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Patent number: 12117240Abstract: A process for the production of a liquid oxygen stream by the cryogenic rectification of an inlet air stream, including dividing the inlet air stream into a first portion, and a second portion. Cooling the first portion, and the second portion against a cooled multicomponent refrigerant circuit, thereby producing a first cooled portion, and a second cooled portion. Condensing the first cooled portion, thereby producing a condensed first portion, then introducing the condensed first portion into one or more distillation columns. Expanding the second cooled portion in a turbo-expander, thereby producing an expanded second portion, then introducing the expanded second portion within the one or more distillation columns. Producing within the one or more distillation columns at least a waste nitrogen stream, a nitrogen enriched stream, and an oxygen enriched stream. Withdrawing the oxygen enriched stream from the one or more distillation columns as a liquid oxygen stream.Type: GrantFiled: July 19, 2022Date of Patent: October 15, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Michael A. Turney, Alain Guillard
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Publication number: 20240335786Abstract: The invention relates to a process for separating carbon dioxide from a raw hydrogen product stream to produce a hydrogen product stream and a carbon dioxide product stream. The process includes the absorption of carbon dioxide in an absorption stage in an absorption medium and subsequent desorption of the carbon dioxide from the laden absorption medium in a plurality of decompression stages. According to the invention carbon dioxide substreams withdrawn from the decompression stages are combined into a carbon dioxide total stream and compressed in a plurality of serially arranged compression stages. Each compression stage having a suction pressure value is assigned at least one decompression stage with a corresponding desorption pressure value and the number of decompression stages corresponds at least to the number of compression stages.Type: ApplicationFiled: April 4, 2024Publication date: October 10, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Sophia SCHMIDT, Matthias LINICUS
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Patent number: 12109527Abstract: A process for separating two gaseous streams, including purifying a first gaseous stream in a first acid gas removal absorber, purifying in a first temperature swing adsorption unit, and then separating at a cryogenic temperature in a separation unit to produce a stream of fluid enriched in carbon monoxide and a stream of fluid enriched in hydrogen, sending a second gaseous stream containing at least carbon monoxide, hydrogen and at least one acid gas to a shift reaction unit, the shifted second stream is purified in a second acid gas removal absorber to remove carbon dioxide and the purified second stream is sent as a feed stream to a pressure swing adsorption unit to produce a hydrogen enriched stream, and sending at least part of the stream enriched in hydrogen from the separation unit as a feed stream to the pressure swing adsorption unit to produce the hydrogen-enriched stream.Type: GrantFiled: May 30, 2019Date of Patent: October 8, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Antoine Hernandez, Wei Guan
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Patent number: 12109528Abstract: Process and plant for membrane permeation treatment of a carbon dioxide and methane-containing biogas stream in which the biogas stream is compressed with a compressor and the compressed biogas stream is fed to a membrane separation unit comprising first and second modules each containing at least one membrane selective for carbon dioxide over methane. The first module separates the compressed biogas stream into a first, second, and third methane-deficient permeates (in comparison to the biogas stream) and a first methane-enriched retentate (in comparison to the biogas stream). The first permeate being richer in methane than the second or third permeates. The second module separates the first permeate into a fourth methane-deficient permeate and a second methane-enriched retentate. The second and third retentates are recycled back to an inlet of the compressor.Type: GrantFiled: March 22, 2022Date of Patent: October 8, 2024Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Francois Barraud
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Publication number: 20240327216Abstract: The present invention relates to a process and plant for producing a hydrogen- and carbon oxides-having synthesis gas by partial oxidation of a carbonaceous feedstock having nitrogen compounds. The invention takes advantage of the different solubility of NH3 and CO2 as the synthesis gas stream is cooled. Water is condensed continuously throughout the cooling of the synthesis gas stream. NH3 preferentially dissolves or condenses into the liquid phase during cooling, but at relatively high temperatures, above about 80 to 100° C. Further condensation at lower temperatures then preferentially dissolves or condenses CO2 into the liquid phase. Thus, the formation of ammonium salts during cooling of the synthesis gas is prevented.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Bryce WILLIAMS, Stefan WALTER
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Publication number: 20240327215Abstract: The invention relates to a partial oxidation reactor (POX reactor) for producing a raw synthesis gas stream by partial oxidation of a carbon-containing input stream in gaseous form, in liquid form or in solid, particulate form dispersed in a carrier liquid or a carrier gas in the presence of an oxygen-containing oxidant stream and optionally a moderator stream containing steam and/or carbon dioxide. The invention further relates to a process for producing a raw synthesis gas stream. The partial oxidation reactor according to the invention provides for introducing a cylindrical or frustoconical inlet region having a constant diameter or a diameter that is smaller on the entrance side. The inlet region is arranged upstream of a cylindrical main reactor portion and represents a bottleneck-like section since the largest diameter of the inlet region is smaller than the diameter of the cylindrical main reactor portion.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Karsten COVELLA, Hongbin XU, Matthias MUELLER-HAGEDORN
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Patent number: 12104130Abstract: A method of maintaining a syngas composition ratio during an upset condition, including detecting a reduction in the import carbon dioxide flow rate with a carbon dioxide import stream flow sensor, evaluating the reduction in carbon dioxide flow rate or carbon dioxide pressure in a controller, performing one or more predetermined corrective actions as instructed by the controller. Wherein the predetermined corrective actions are chosen from the following: opening a CO2 import stream flow valve, opening a hydrocarbon and steam stream feed valve, opening a CO2 backup stream control valve, opening a syngas backup letdown valve, and starting a composition adjustment unit.Type: GrantFiled: November 18, 2020Date of Patent: October 1, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Yufeng Qian, Pierre-Philippe Guerif, Alexander Roesch