Patents Assigned to L'Air Liquide Société Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
  • Patent number: 11874057
    Abstract: A process for the separation of nitrogen from a feed stream containing at least methane and nitrogen, with a methane content between 4 and 12% mol. consists of at least the following steps: separation of the feed stream by means of a rubbery-type membrane to produce a permeate enriched in methane at a pressure greater than 2 bara and a non-permeate which is a nitrogen-enriched residue gas at a pressure greater than 2 bara and processing of the high-pressure residue gas in a cryogenic separation unit to produce a methane rich liquid and a nitrogen-enriched gas wherein the pressure of the membrane permeate is controlled as a function of the nitrogen concentration in the nitrogen-enriched gas.
    Type: Grant
    Filed: July 16, 2021
    Date of Patent: January 16, 2024
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Martin Raventos, Paul Terrien
  • Patent number: 11872420
    Abstract: A device for regulating breathing gas delivered to a user, comprising a gas circuit comprising a main line having at least an upstream end intended to be connected to at least one gas source and a downstream end intended to be connected to at least one user station such as a mask, the main line comprising at least one electromechanical control valve configured to regulate the gas pressure between the upstream and the downstream, the circuit comprising a secondary line comprising an upstream end intended to be connected to at least one gas source and a downstream end intended to be connected to the same user station(s), the secondary line comprising at least one auxiliary member for regulating the gas flow, the device comprising a switching system configured to control the flow of gas between the upstream and the downstream of the circuit via the main line or via the secondary line, characterized in that the auxiliary member for regulating the secondary line is a pneumatic pressure regulator.
    Type: Grant
    Filed: August 9, 2018
    Date of Patent: January 16, 2024
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Aurelie Caillaud, Jean-Michel Cazenave, Alexandre Domenget, Alexandre Pentagora
  • Patent number: 11873949
    Abstract: A valve for pressurized fluid housing a fluid circuit having an upstream end and a downstream end and a valve for controlling the flow rate in the circuit that is controlled by a movable actuating member in order to control the opening or the closing, the valve having a lower end provided with movable coupling member(s) intended to cooperate with one or more complementary coupling members on a gas source or a circuit, the valve further comprising a member for locking the coupling member(s) that is mounted movably on the body of the valve between a first position not blocking the movement of the coupling member(s) and a second position blocking the movement of the coupling member(s).
    Type: Grant
    Filed: October 5, 2021
    Date of Patent: January 16, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Renaud Ligonesche, Olivier Ondo, Antoine Frenal, Johan Broechler, Morgan Lamiable, Arnaud Kaichinger
  • Patent number: 11865491
    Abstract: The invention relates to a method for managing a PSA unit having at least N adsorbers arranged in pairs, where each pair is designed to be able to be selectively isolated, a control device, and a plurality of interfaces for accessing the instrumentation of each adsorber. When a first pair is fluidically isolated, the first pair having a first and a second adsorber, the isolating of a third adsorber includes setting the control device to control N-4 adsorbers, fluidically isolating a second pair having the third and a fourth adsorber, isolating one of the first and second adsorbers and the third adsorber, configuring the interfaces so as to swap over the instrumentation of the other of the first and second adsorbers and the instrumentation of the fourth adsorber, placing the first and second pairs in fluidic communication, and setting the control device to control N-2 adsorbers.
    Type: Grant
    Filed: June 10, 2021
    Date of Patent: January 9, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Jan Matthyssen, Pascal Meerman, Luc Nelis
  • Patent number: 11857911
    Abstract: A unit for purifying a gas mixture by adsorption, including at least one adsorber having at least one cluster of N identical adsorbent modules operating in parallel, where N?2, each cluster of N adsorbent modules includes a common inlet manifold having a straight inlet duct of axis Xe supplying N inlet nozzles Tei, where i ranges from 1 to N, respectively connected to the inlets Ei, where i ranges from 1 to N, of the N modules of the cluster, a common outlet manifold having a straight outlet duct of axis Xs collecting the flow leaving the N outlet nozzles Tsi, where i ranges from 1 to N, respectively connected to the outlets Si, where i ranges from 1, of the N modules of the cluster.
    Type: Grant
    Filed: February 27, 2019
    Date of Patent: January 2, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christian Monereau, Benjamin Morineau, Guillaume Rodrigues
  • Patent number: 11857912
    Abstract: A process for producing a purified gas stream having impurities, using a production unit for producing a gas stream and a storage reservoir. The process includes producing a first gas stream by means of the production unit. Storing at least a portion of the first gas stream in the storage reservoir. Extracting, from the storage reservoir, a second gas stream corresponding to at least one portion of the first stream polluted by the impurities. Purifying the second gas stream by transfer of at least one portion of the impurities contained in the second gas stream into the first gas stream. And recovery of the purified gas stream at the output of the purification.
    Type: Grant
    Filed: March 7, 2019
    Date of Patent: January 2, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christian Monereau, David Frimat, Vincent Gueret, Pierre Petit
  • Patent number: 11859283
    Abstract: Methods for forming an Indium-containing film by a vapor deposition method using a heteroalkylcyclopentadienyl Indium (I) precursor having a general formula: In[R1R2R3R4CpL1] or In[CpL1L2y] wherein Cp represents a cyclopentadienyl ligand; R1 to R4 are each independently H, C1-C4 linear, branched or cyclic alkyls; L1 and L2 are each independently a substituent bonded to the Cp ligand and consisting of an alkyl chain containing at least one heteroatom, such as Si, Ge, Sn, N, P, B, Al, Ga, In, O, S, Se, Te, F, Cl, Br, I; and y=1-4. Examplary heteroalkylcyclopentadienyl Indium (I) precursors include In(Cp(CH2)3NMe2) or In(CpPiPr2).
    Type: Grant
    Filed: July 28, 2020
    Date of Patent: January 2, 2024
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Antoine Bruneau, Takashi Ono, Christian Dussarrat
  • Patent number: 11852408
    Abstract: In a method for separating air by cryogenic distillation using a column system consisting of a higher pressure column operating at a first pressure and a lower pressure column operating at a second pressure, a first air flow constituting between 75% and 98% of the air sent to the column system compressed to a third pressure above the first pressure, is sent to the higher pressure column, a second air flow constituting between 5% and 25% of the air sent to the column system is compressed to a fourth pressure above the second pressure but lower than the third pressure, is sent to the lower pressure column, a third column separates an argon-enriched flow and the air sent to the lower pressure column constitutes between 10% and 25% of the total air sent to the column system.
    Type: Grant
    Filed: May 5, 2021
    Date of Patent: December 26, 2023
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Jean-Pierre Tranier, Richard Dubettier-Grenier, Maxime Rozieres
  • Patent number: 11850537
    Abstract: The present invention relates to an insertion device for inserting at least one packing section for a gas/liquid separation column into a cylindrical casing, comprising a base provided with retaining means which are configured to grip a packing section and which are arranged uniformly around a main axis, characterized in that the insertion device comprises at least two fastening means secured to the base, said fastening means being configured to fasten the insertion device to the casing. The invention also covers an insertion system for inserting at least one packing section into a cylindrical casing, comprising such an insertion device, and a method for inserting at least one packing section into a cylindrical casing that is implemented by such an insertion system.
    Type: Grant
    Filed: February 7, 2023
    Date of Patent: December 26, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Cyrille Babinet, Eric Gallopin, Gilles Lebain
  • Patent number: 11845040
    Abstract: Method and installation for treating a CO2- and H2O-containing flue gas generated by an industrial process unit before CCUS, whereby the flue gas evacuated from the unit is subjected to cooling to a temperature T2 between 100 and 600° C., whereby the cooled flue gas is pretreated in one or more particle removal and/or gas cleaning and/or drying stages and the temperature of the cooled flue gas is further reduced to a temperature T3<T2, before a first part of pretreated flue gas is subjected to CCUS, a second part of the pretreated flue gas being recycled at temperature T3 as a cooling agent and mixed with the flue gas during the controlled cooling thereof, partially or fully purified CO2 from the CCUS may be recycled at temperature T4<T2 may be recycled as a cooling agent and mixed with the flue gas during the controlled cooling.
    Type: Grant
    Filed: January 12, 2022
    Date of Patent: December 19, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Fabrice Del Corso, Jean Caudal, Xavier Paubel
  • Publication number: 20230398496
    Abstract: A hollow fiber membrane bundle useful for manufacturing a wide variety of hollow fiber membrane modules having different flow configurations includes hollow fiber membranes arranged around a porous support tube, a cured resin tubesheet formed at first end of the bundle, and either a cured resin nub or a cured resin tubesheet formed at a second end of the bundle. The bore(s) of the hollow fiber membranes are open at a face of the tubesheet adjacent the first end of the bundle. The tubesheet has an annular structure that encapsulates the hollow fiber membranes and the porous support tube at the first end of the bundle but which does not completely block a bore of the porous support tube, wherein the collection tube has a plurality of orifices formed therein at least at positions adjacent the nub.
    Type: Application
    Filed: June 9, 2022
    Publication date: December 14, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep K. KARODE, Karl BEERS, Sudhir S. KULKARNI, Tim POLUDNIAK, Fan Z. WORLEY, Ed SANDERS, JR.
  • Patent number: 11831057
    Abstract: A method of integrating a fuel cell with a steam methane reformer is provided. The system includes at least one fuel cell including an anode and a cathode, and a steam methane reformer including a syngas stream, and a flue gas stream. The method includes introducing at least a portion of the flue gas stream to the cathode, thereby producing a CO2 depleted flue gas stream and introducing a hydrocarbon containing stream to the anode, thereby producing an electrical energy output and a carbon dioxide and hydrogen containing stream from the fuel cell.
    Type: Grant
    Filed: December 18, 2019
    Date of Patent: November 28, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Pierre-Philippe Guerif, Guillaume Rodriges
  • Patent number: 11828532
    Abstract: A method and apparatus for transferring a first liquid removed from an outlet of a first distillation column to an inlet of a second distillation column is provided. The second distillation column operates at a higher pressure than the first distillation column, and the inlet of the second distillation column is at higher elevation as compared to the outlet of the first distillation column. The method advantageously transfers the first liquid from the outlet to the inlet by mixing with a sufficient amount of a lower density second liquid that results in a mixed liquid having a reduced density as compared to the first liquid.
    Type: Grant
    Filed: December 31, 2020
    Date of Patent: November 28, 2023
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventor: Eric Day
  • Patent number: 11820654
    Abstract: Methods for producing halosilazane comprise halogenating a hydrosilazane with a halogenating agent to produce the halosilazane, the halosilazane having a formula (SiHa(NR2)bXc)(n+2)Nn(SiH(2?d)Xd)(n?1), wherein each a, b, c is independently 0 to 3; a+b+c=3; d is 0 to 2 and n?1; wherein X is selected from a halogen atom selected from F, Cl, Br or I; each R is selected from H, a C1-C6 linear or branched, saturated or unsaturated hydrocarbyl group, or a silyl group [SiR?3]; further wherein each R? of the [SiR?3] is independently selected from H, a halogen atom selected from F, Cl, Br or I, a C1-C4 saturated or unsaturated hydrocarbyl group, a C1-C4 saturated or unsaturated alkoxy group, or an amino group [—NR1R2] with each R1 and R2 being further selected from H or a C1-C6 linear or branched, saturated or unsaturated hydrocarbyl group, provided that when c=0, d?0; or d=0, c?0.
    Type: Grant
    Filed: August 23, 2021
    Date of Patent: November 21, 2023
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Jean-Marc Girard, Peng Zhang, Antonio Sanchez, Manish Khandelwal, Gennadiy Itov, Reno Pesaresi, Grigory Nikiforov, David Orban
  • Patent number: 11819796
    Abstract: A method for producing oxygen from air using vacuum swing adsorption by means of a unit including at least two adsorbers each following, with an offset a pressure cycle, with a decompression step including at least a co-current first decompression sub-step for the partial balancing of pressure with the other adsorber which is performing counter-current recompression by means of a balancing valve, and, at least for one cycle out of three, a dead time sub-step which succeeds the first decompression sub-step, the method including a pressure of X bar at the end of the first decompression sub-step for the cycles that do not have a dead time sub-step, and a pressure of X bar at the end of the dead time sub-step, opening the balancing valve identically during the first decompression sub-step and the dead time sub-step, for the cycles that do have a dead time sub-step.
    Type: Grant
    Filed: February 25, 2019
    Date of Patent: November 21, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Guillaume Rodrigues, François Darrigade, Patrick Le Bot, Pierre Petit, Stéphane Pusiol, Maxime Perez
  • Patent number: 11819838
    Abstract: The present invention provides a supply system enabling a precursor of a solid material or a precursor of a liquid material to be supplied to a latter process at no higher concentration than required and also at or above a predetermined concentration. A supply system 1 comprises: a vessel 11 for receiving a precursor material; a vessel heating unit for heating the vessel at a set temperature; a carrier gas heating unit which is disposed in an introduction line L1 and heats a carrier gas; a main measurement unit which is disposed in an outward conduction line L2 and obtains data relating to a gas of the precursor; and a carrier gas temperature control unit for controlling the temperature of the carrier gas heating unit in accordance with a measurement result of the main measurement unit.
    Type: Grant
    Filed: March 28, 2017
    Date of Patent: November 21, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Toshiyuki Nakagawa, Kouki Morimoto, Kazutaka Yanagita, Takashi Kameoka, Yuki Kumamoto, Kazuma Suzuki, Mikio Goto
  • Patent number: 11821080
    Abstract: A process for gas phase deposition of a metal or metal nitride film on a surface substrate comprises: reacting a metal-oxo or metal oxyhalide precursor with an oxophilic reagent in a reactor containing the substrate to deoxygenate the metal-oxo or metal oxyhalide precursor, and forming the metal or metal nitride film on the substrate through a vapor deposition process. The substrate is exposed to the metal oxyhalide precursor and the oxophilic reagent simultaneously or sequentially. The substrate is exposed to a reducing agent sequentially after deoxygenation.
    Type: Grant
    Filed: March 5, 2021
    Date of Patent: November 21, 2023
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Yumin Liu, Rocio Alejandra Arteaga Muller, Nicolas Blasco, Jean-Marc Girard, Feng Li, Venkateswara R. Pallem, Zhengning Gao
  • Publication number: 20230363334
    Abstract: A method for using hydrogen-rich water to increase the content of aromatic substances in fruits and vegetables comprises the step of keeping an outlet hydrogen concentration of hydrogen-rich water no lower than a set value within a period of time for which a filed is irrigated with hydrogen-rich water.
    Type: Application
    Filed: September 13, 2021
    Publication date: November 16, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, NANJING AGRICULTURAL UNIVERSITY
    Inventors: Webiao SHEN, Yan ZENG, Longna LI, M. SUNDAR, Shu WANG, Xu CHENG, Yuhao LIU
  • Patent number: 11815309
    Abstract: A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.
    Type: Grant
    Filed: November 7, 2018
    Date of Patent: November 14, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Mike Turney, Alain Guillard, Alexander Roesch
  • Patent number: D1008422
    Type: Grant
    Filed: September 16, 2020
    Date of Patent: December 19, 2023
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Renaud Ligonesche, Olivier Ondo