Patents Assigned to L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
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Publication number: 20240327215Abstract: The invention relates to a partial oxidation reactor (POX reactor) for producing a raw synthesis gas stream by partial oxidation of a carbon-containing input stream in gaseous form, in liquid form or in solid, particulate form dispersed in a carrier liquid or a carrier gas in the presence of an oxygen-containing oxidant stream and optionally a moderator stream containing steam and/or carbon dioxide. The invention further relates to a process for producing a raw synthesis gas stream. The partial oxidation reactor according to the invention provides for introducing a cylindrical or frustoconical inlet region having a constant diameter or a diameter that is smaller on the entrance side. The inlet region is arranged upstream of a cylindrical main reactor portion and represents a bottleneck-like section since the largest diameter of the inlet region is smaller than the diameter of the cylindrical main reactor portion.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Karsten COVELLA, Hongbin XU, Matthias MUELLER-HAGEDORN
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Publication number: 20240327216Abstract: The present invention relates to a process and plant for producing a hydrogen- and carbon oxides-having synthesis gas by partial oxidation of a carbonaceous feedstock having nitrogen compounds. The invention takes advantage of the different solubility of NH3 and CO2 as the synthesis gas stream is cooled. Water is condensed continuously throughout the cooling of the synthesis gas stream. NH3 preferentially dissolves or condenses into the liquid phase during cooling, but at relatively high temperatures, above about 80 to 100° C. Further condensation at lower temperatures then preferentially dissolves or condenses CO2 into the liquid phase. Thus, the formation of ammonium salts during cooling of the synthesis gas is prevented.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Bryce WILLIAMS, Stefan WALTER
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Patent number: 12107477Abstract: Electric machine, in particular an electric motor for driving at least one compressor or circulator, comprising a stator and a rotor that are disposed in a casing, the machine comprising a cooling device disposed around the stator and comprising a circulation circuit for a cooling fluid, characterized in that the cooling device comprises a circulation pipe for the cooling fluid, comprising a portion embedded in a mass of material with high thermal conductivity such as metal or a metal alloy.Type: GrantFiled: June 23, 2020Date of Patent: October 1, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Fabien Durand, Loic Brunet Manquat, Guillaume Delautre
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Patent number: 12104130Abstract: A method of maintaining a syngas composition ratio during an upset condition, including detecting a reduction in the import carbon dioxide flow rate with a carbon dioxide import stream flow sensor, evaluating the reduction in carbon dioxide flow rate or carbon dioxide pressure in a controller, performing one or more predetermined corrective actions as instructed by the controller. Wherein the predetermined corrective actions are chosen from the following: opening a CO2 import stream flow valve, opening a hydrocarbon and steam stream feed valve, opening a CO2 backup stream control valve, opening a syngas backup letdown valve, and starting a composition adjustment unit.Type: GrantFiled: November 18, 2020Date of Patent: October 1, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Yufeng Qian, Pierre-Philippe Guerif, Alexander Roesch
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Patent number: 12106940Abstract: A method for storage and supply of a F3NO-free FNO-containing gas comprises the steps of storing the F3NO-free FNO-containing gas in a NiP coated steel cylinder with a polished inner surface, releasing the F3NO-free FNO-containing gas from the cylinder to a manifold assembly by activating a cylinder valve in fluid communication with the cylinder and the manifold assembly, de-pressurizing the F3NO-free FNO-containing gas by activating a pressure regulator in the manifold assembly so as to divide the manifold assembly into a first pressure zone upstream of the pressure regulator and a second pressure zone downstream of the pressure regulator, and feeding the de-pressurized F3NO-free FNO-containing gas to a target reactor downstream of the second pressure zone.Type: GrantFiled: January 13, 2022Date of Patent: October 1, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Ayaka Nishiyama, Jiro Yokota, Chih-yu Hsu, Peng Shen, Nathan Stafford
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Patent number: 12097463Abstract: A gas stream is purified by a TSA adsorption scheme including at least two adsorbers following, in an offset manner, a cycle including an adsorption phase, and a subsequently, a regeneration phase. The regeneration phase includes a depressurization step, a pre-regeneration step and a regeneration step. A gas circulator is used to circulate the gas within the adsorber in the pre-regeneration step in a closed loop while the circulating gas is heated with a heater.Type: GrantFiled: February 3, 2022Date of Patent: September 24, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Golo Zick
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Patent number: 12098883Abstract: An air gas separation plant comprising, in the direction of circulation of the air stream: a compression means that makes it possible to compress the air stream to a pressure P1 of between 1.15 bar abs and 2 bar abs, an adsorption unit of TSA type, and a cryogenic distillation unit, with the adsorption unit comprising at least two adsorbers A and B each having a parallelepipedal casing arranged horizontally and comprising: an air stream inlet and an air stream outlet, a fixed bed adsorbent mass, likewise of parallelepipedal shape, the faces of which are parallel to the faces of the casing; and a set of volumes allowing the air stream to pass through the adsorbent mass horizontally, over the entire cross-section and throughout the entire thickness thereof.Type: GrantFiled: February 12, 2020Date of Patent: September 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Benoit Davidian
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Patent number: 12098805Abstract: A cryogenic fluid transfer device comprising a first tank, a second tank, and a fluid transfer circuit, wherein the first tank comprises a cryogenic fluid distribution tank configured to store a cryogenic fluid in a liquid phase in a lower part thereof and in a gaseous phase in an upper part thereof, wherein the second tank comprises a cryogenic receiving tank configured to house the cryogenic fluid in liquid phase in a lower part thereof and in gaseous phase in an upper part thereof, wherein the fluid transfer circuit is configured to connect the first and second tanks, the fluid transfer circuit comprising a first pipe connecting the upper parts of the first and second tanks and comprising at least one valve, and a second pipe connecting the lower part of the first tank to the second tank that comprises a pump that has an inlet connected to the first tank and an outlet connected to the second tank, wherein: the pump and the at least one valve of the first line are configured so as to ensure a fluidic connecType: GrantFiled: November 22, 2022Date of Patent: September 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
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Mono-substituted cyclopentadienes and metal cyclopentadienyl complexes and synthesis methods thereof
Patent number: 12091374Abstract: A metal cyclopentadienyl complex has the formula: wherein m?0; M is a Group I, II or III main group metal, alkali or transition metal; C5H4 represents a Cp ring where two hydrogens are substituted by M and R(F)m; R(F)m is connected to any one of the carbon atoms of the Cp and selected from a hydrocarbyl, fluorohydrocarbyl, silyl group [SiR?3], or amino group [—NR1R2]. The metal cyclopentadienyl complexes include Li(C5H4-2-C5H11) (CAS No: 2413046-23-6), K(C5H4-2-C5H11), Na(C5H4-2-C5H11), K(C5H4-1-F—C4H10), K(C5H4-1,1,1-3F—C4H6), Li(C5H4-2-C4H9), or In(C5H4-2-C5H11) (CAS No.: 2364634-67-1). A mono-substituted cyclopentadiene has the formula: wherein m?0; C5H5 represents the Cp ring where one hydrogen is substituted R(F)m; R(F)m is connected to any one of the carbon atoms of the Cp and selected from a hydrocarbyl, fluorohydrocarbyl, silyl group [SiR?3], or amino group [—NR1R2]. The mono-substituted cyclopentadienes include C5H5-1-F—C4H10, C5H5-2-C5H11, C5H5-2-C4H9, or C5H5-1,1,1-3F—C4H6.Type: GrantFiled: January 19, 2022Date of Patent: September 17, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Grigory Nikiforov -
Patent number: 12092394Abstract: A plate fin heat exchanger assembly (S) for a cryogenic air separation unit, comprising: a heat exchanger having at least two cryogenic liquid inlets (B,C) at least two cryogenic liquid outlets (B,C), at least one nitrogen-rich stream inlet (D) at a first end of the heat exchanger and at least one nitrogen-rich stream outlet at a second end of the heat exchanger, the heat exchanger configured to receive a flow of at least one nitrogen-rich stream (WN,LPGAN) of the air separation unit at the at least one nitrogen-rich stream inlet and separate flows of at least two cryogenic liquids (LOX,LIN,LR) at the at least two cryogenic liquid inlets; wherein the inlet of the first of the cryogenic liquids is closer to the first end than the outlet of the second of the cryogenic liquids.Type: GrantFiled: October 26, 2018Date of Patent: September 17, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jian-Wei Cao, Eric Day, Sophie Lazzarini
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Patent number: 12083528Abstract: A plant for grinding a product, which includes a grinder in which the product is ground, which plant also includes a hopper for supplying the grinder with product to be ground, configured to be supplied with product to be ground; a means for bringing a cryogenic fluid into the hopper; and a means for discharging product from the hopper into the grinder. Wherein the hopper is provided in a lower part with a hollow screw provided with turns allowing the product to be discharged out of the hopper, into the grinder; and the means for bringing a cryogenic fluid into the hopper comprise an injection lance which is positioned inside the turns of the hollow screw, extending in a direction substantially parallel to the axis of the screw.Type: GrantFiled: December 23, 2019Date of Patent: September 10, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alban Poirier, Alain Cloarec, Etienne Charve, Olivier Pouchain
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Patent number: 12085334Abstract: A method for liquefying a stream of hydrocarbons from a feed stream, including introducing the feed stream and a first cooling stream into a first heat exchanger, extracting a plurality of partial cooling streams obtained from the first cooling stream from the heat exchanger via separate outlets, introducing each partial cooling stream into an expansion element to produce a plurality of biphasic cooling streams at different pressures, introducing each biphasic cooling stream into a phase separator element to produce a gaseous cooling stream which is diverted from the first exchanger and a liquid cooling stream which is introduced into the first exchanger via respective inlets, evaporating each liquid cooling stream by heat exchange with at least the feed stream and the first cooling stream so as to extract a cooled hydrocarbon stream at the outlet from the first heat exchanger and to extract a plurality of evaporated cooling streams.Type: GrantFiled: July 20, 2020Date of Patent: September 10, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Marc Peyron, Sophie Lazzarini, Sébastien Lichtle, Thomas Morel
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Patent number: 12084347Abstract: The present invention relates to a process for producing hydrogen and for separating carbon dioxide from synthesis gas using a physical absorption medium. The process comprises the steps where the synthesis gas and the absorption medium are cooled; carbon dioxide is removed from the cooled synthesis gas via the cooled absorption medium in a physical absorption step at elevated pressure; laden absorption medium is treated in a plurality of flash stages, wherein co-absorbed carbon monoxide, hydrogen and carbon dioxide are separately removed from the laden absorption medium; hydrogen is separated from synthesis gas freed of carbon dioxide in a physical separation step, wherein hydrogen as product gas and an offgas comprising hydrogen, carbon monoxide and carbon dioxide are obtained; product gas hydrogen and carbon dioxide are discharged from the process. The invention further relates to a plant for performing the process.Type: GrantFiled: November 11, 2021Date of Patent: September 10, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Sophia Schmidt, Matthias Linicus
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Patent number: 12076690Abstract: The invention relates to a process for removal of unwanted, in particular acidic gas constituents, for example carbon dioxide and hydrogen sulfide, from a crude synthesis gas by gas scrubbing with a scrubbing medium. According to the invention the flash gases obtained during the decompression of the laden scrubbing medium are supplied to a recompressor in order to recycle these to the crude synthesis gas and thus utilize them materially after the recompression. Alternatively or in addition the flash gases may also be supplied to a decompression turbine to recover refrigeration and mechanical work. If the recompressor and/or the decompression turbine are/is designed to have multiple stages, the flash gases obtained at different pressure levels are preferably supplied to a corresponding pressure level of the recompressor and/or of the decompression turbine.Type: GrantFiled: May 29, 2019Date of Patent: September 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alfred Gubrinski, Sharon Corbet, Dorit Rappold, Pankaj Puri
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Patent number: 12078294Abstract: The invention relates to a gas container having a gas distribution valve and an electronic measurement device arranged on the gas distribution valve. The electronic measurement device having an electronic display screen which is electrically connected, via an electrical connecting connector, to a circuit board having at least one microprocessor. The electrical connecting connector having a connector body in the shape of an elongate bar through which a plurality of electrically conductive elements passes extending between two opposite faces of the connector body. The electrically conductive elements are separated from one another by regions made of insulating material.Type: GrantFiled: January 7, 2022Date of Patent: September 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alexis Mary, Maximilien Bonamarte, Philippe Rudnianyn, Taraq Bechikhi
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Patent number: 12078295Abstract: The invention relates to a container (1) for pressurized fluid, in particular a gas cylinder, having a given internal volume (2), having a fluid distribution valve (3) having a member for selecting the flow rate (12) able to adopt a plurality of distinct positions each corresponding to a given fluid flow rate, and an electronic device (7) having means for measuring pressure, microprocessor (15)-based data processing means (5) for processing the pressure measurements, and display means (6) for displaying the remaining fluid calculated by the data processing means (5).Type: GrantFiled: April 6, 2022Date of Patent: September 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alexis Mary, Bertrand Morin, Valerie Pateau
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Patent number: 12078415Abstract: An apparatus for the separation of air by cryogenic distillation comprises a column system, a heat exchanger, a turbine, means for sending compressed and purified air at a first pressure to be cooled at the first pressure in the heat exchanger, means for sending a first gaseous stream having a nitrogen content at least that of air to be cooled and liquefied or pseudo liquefied in the heat exchanger to form a liquefied stream, means for sending at least part of the liquefied stream to be warmed and vaporized in the heat exchanger to a first intermediate temperature of the heat exchanger to form a vaporized stream, means for removing the vaporized stream from an intermediate section of the heat exchanger, a conduit for sending the vaporized stream to be expanded, in the turbine to form an expanded stream, a conduit for sending at least part of the expanded stream to the column system, a conduit for sending a second gaseous stream having the same nitrogen content as the first stream to be cooled in the heat exchType: GrantFiled: July 26, 2019Date of Patent: September 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Alain Briglia, Fengjie Xue, Jianwei Cao, Baptiste Fara
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Patent number: 12076703Abstract: A process for installing a section of packing in a casing by means of a device to assist installation of a section of packing, the casing comprising at least one tubular wall extending in a longitudinal direction (L) between two longitudinal ends, and an inner face of which participates in delimiting a receptacle for the section of packing, the casing being positioned horizontally during the process for installing the section of packing, the process comprising a step of fitting of the device to assist installation on the casing, during which the device to assist installation is secured in the vicinity of the input opening of the casing, a step of positioning of the section of packing relative to the device to assist installation and to the input opening, and at least one step of pushing during which the section of packing is pushed into the receptacle of the casing.Type: GrantFiled: December 19, 2022Date of Patent: September 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges ClaudeInventors: Vincent Faucher, Manuel Dos Reis, Vincent Maret, Luis Torbado, Alain Appel, Eric Biret, Laurent Leclerc
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Patent number: 12076688Abstract: Certain embodiments of the invention relate to a method and facility for purifying a high-flow gas stream by absorption, the purification facility comprising at least one absorber having a parallelepipedal enclosure arranged horizontally and comprising: a gas stream inlet and outlet, two fixed-bed absorbent masses each having a likewise parallelepipedal shape, the surfaces of which are parallel to the surfaces of the enclosure, and a set of volumes allowing the traversing of the two absorbent masses by the gas streams, in parallel but opposite directions, the traversing occurring horizontally over the entire cross-section of each of the absorbent masses and over their entire thicknesses.Type: GrantFiled: February 12, 2020Date of Patent: September 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Benoit Davidian, Christian Monereau
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Publication number: 20240290627Abstract: An etching method for forming a high aspect ratio aperture by selectively etching one or more silicon-containing films in a substrate using a patterned mask layer deposited on top of the one or more silicon-containing films comprises: mounting the substrate in a processing chamber; introducing an etching gas containing a vapor of an oxygen-containing hydrofluorocarbon into the processing chamber; converting the etching gas to a plasma; and allowing an etching reaction to proceed between the plasma and the one or more silicon-containing films so that the one or more silicon-containing films are selectively etched versus the patterned mask layer to form the high aspect ratio aperture, wherein the oxygen-containing hydrofluorocarbon has a general formula CxHyFzOn, where 2?x?13, 1?y?15, 1?z?21, 1?n?3.Type: ApplicationFiled: February 24, 2023Publication date: August 29, 2024Applicants: American Air Liquide, Inc., L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Tomo HASEGAWA, Vladislav GAMALEEV, Nicolas GOSSET