Patents Assigned to L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
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Patent number: 12194453Abstract: A gas processing vessel of cylindrical shape having a cylindrical shell of the vertical axis, a gas distribution device and a first particulate material, the distribution device being fixed in the vessel next to a gas inlet or outlet orifice recessed into a lower end wall, a cover being designed to be in contact without a weld with the lower end wall and having a diameter greater than or equal to one third of the diameter of the vessel, a second particulate material with an equivalent diameter De greater than or equal to 10 mm and greater than the dimensions of the openings in the cover, and a means for centering the cover above the inlet or outlet orifice, the means being fixed to the pipe that is connected to the orifice.Type: GrantFiled: June 2, 2020Date of Patent: January 14, 2025Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Lian-Ming Sun, Christian Monereau, Gregory Demar
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Patent number: 12196487Abstract: A plant for separating gases from the air comprises, in the direction of circulation of the stream of air: a compression means for compressing the stream of air to a pressure P1 of between 1.15 bar abs and 2 bar abs, a TSA adsorption unit, and a cryogenic distillation unit, with the adsorption unit comprising at least two adsorbers A1 and A2 each having a parallelepipedal casing arranged horizontally and comprising: an air stream inlet and outlet, two fixed bed adsorbent masses each likewise parallelepipedal with faces parallel to the faces of the casing, and a set of volumes allowing the stream of air to traverse the two adsorbent masses horizontally, in parallel, over the whole cross section of each of the adsorbent masses and throughout their thicknesses.Type: GrantFiled: February 12, 2020Date of Patent: January 14, 2025Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Benoit Davidian
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Patent number: 12196503Abstract: The invention relates to a plate and fin heat exchanger for bringing into a heat exchange relationship at least one refrigerant fluid and one calorigenic fluid, having a plurality of plates arranged parallel to a longitudinal direction so as to define a plurality of passages between said plates, at least one passage being formed between two adjacent plates and having at least one heat exchange structure equipped with at least one series of fins extending parallel to the longitudinal direction and following one another in a lateral direction, the fins, within the passage, defining channels for the flow of the fluids. According to the invention, at least one fin, over at least part of its surface, has a surface texturing in the form of striations arranged parallel to the longitudinal direction.Type: GrantFiled: September 27, 2022Date of Patent: January 14, 2025Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Frédéric Crayssac, Jacopo Seiwert, Marie-Adelaide Cremieux
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Patent number: 12187611Abstract: In a process for the separation of a mixture containing hydrogen and carbon monoxide to produce gaseous hydrogen, the mixture is cooled down to a temperature below ?180° C. and then separated at a temperature below ?100° C. to produce a gas enriched in hydrogen and a fluid enriched in carbon monoxide, at least a part of the gas enriched in hydrogen is sent to a pressure swing adsorption separation apparatus operating at a temperature above 0° C. to produce a gas rich in hydrogen at a pressure of at least 20 bars, and at least a part of the gas rich in hydrogen is cooled in the heat exchanger down to a temperature below ?100° C., reduced in pressure in a turbine down to a pressure of at least 8 bars and reheated in the heat exchanger to constitute a product rich in hydrogen at a pressure of at least 8 bars.Type: GrantFiled: May 4, 2022Date of Patent: January 7, 2025Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Bertrand Demolliens, Antoine Hernandez
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Patent number: 12187853Abstract: Disclosed is a SAM forming composition comprising a SAM monomer or precursor having a backbone with a surface reactive group, wherein the backbone contains no Si—C bonds and is selected from the group consisting of a Si—C bond-free polysilane and a trisilylamine. The surface reactive groups are disclosed for the surface to be covered being a dielectric surface and a metal surface, respectively. A process of forming a SAM on a surface and a process of forming a film on the SAM are also disclosed.Type: GrantFiled: June 18, 2021Date of Patent: January 7, 2025Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, American Air Liquide, Inc.Inventors: Venkateswara R. Pallem, Jean-Marc Girard, Nicolas Blasco, Claudia Fafard, Fabrizio Marchegiani
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Patent number: 12188621Abstract: A system for minimizing heat leaks to a liquid cryogen pump incorporating a bayonet includes a male bayonet portion received in a female bayonet portion, each having a circular cross-section and comprising an outer pipe surrounding an inner pipe and an annulus therebetween which is under vacuum, wherein a liquid cryogen pump is contained within an interior of the male bayonet portions.Type: GrantFiled: May 11, 2023Date of Patent: January 7, 2025Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes
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Patent number: 12189404Abstract: A method for filling a batch of gas bottles with a gas mixture, wherein the gas mixture may have of a single constituent in a matrix or a plurality of constituents in a matrix, which matrix has of one or more base gases, in which a real-time analysis of all the constituents of the gas mixture is carried out at the exit of a mixing chamber and before it enters a compression stage.Type: GrantFiled: June 15, 2023Date of Patent: January 7, 2025Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Erwann Le Gendre, Christian Daviet, Werner Weterings, Maurice Koch
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Patent number: 12188461Abstract: The invention relates to a fluid compression apparatus having a plurality of compression stages, comprising a first compression chamber, a second compression chamber, an intake system communicating with the first compression chamber which is configured to allow fluid to be compressed into said first compression chamber, a transfer system configured to allow in an open position the transfer of fluid from the first compression chamber to the second compression chamber, a mobile piston for ensuring the compression of the fluid in the first and second compression chambers.Type: GrantFiled: October 21, 2020Date of Patent: January 7, 2025Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Cyril Benistand-Hector, Guillaume Petitpas
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Publication number: 20250001379Abstract: A reactor for the catalytic production of methanol having two or more reaction zones arranged and surrounded by a heat exchange fluid. The reaction zones are preferably reaction tubes, and each reaction zone has at least one cleaning layer and at least one catalyst layer, where the cleaning layer is arranged upstream, and the catalyst layer is arranged downstream. A method for the catalytic production of methanol from synthesis gas using the reactor is also described.Type: ApplicationFiled: September 20, 2022Publication date: January 2, 2025Applicants: CLARIANT INTERNATIONAL LTD., L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDEInventors: Stéphane HAAG, Nga Thi Quynh DO, Veronika GRONEMANN, Tobias OELMANN, Markus REICHINGER, Stephan J. REITMEIER, Heiner SCHWARZ
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Patent number: 12181107Abstract: The present invention relates to a method for improving stability of a hydrogen gaseous dispensing system. An example of such system is hydrogen powered vehicle fuel filling station. Vehicle is filled by multiple high pressure gaseous hydrogen tubes, usually one tube at a time. For safety and reliability reasons a control requirement for such system is to be able to deliver the hydrogen at constant rate to the fuel tank so that its rate of pressure increase stays constant during entire filling process. A dual pressure regulator arrangement is proposed to better maintain flow continuity and/or pressure during tube switching.Type: GrantFiled: November 16, 2021Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pierre-Philippe Guerif, Paul Kong, Wendy May Yee Yip, Aaron Harris, Jorge Lopez
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Patent number: 12178214Abstract: A method for stunning animals and a respective stunning system is disclosed. Animals are lowered in a cradle into a pit filled with anoxic stunning gas. The cradle is provided with a heat sink, preferably comprising solid carbon dioxide, for cooling the stunning gas in the pit resulting in a density increase of the stunning gas in the pit. This reduces demixing of the stunning gas and rising of components such as nitrogen (N2) usually having a lower density than the air surrounding the stunning system.Type: GrantFiled: May 24, 2023Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Nadia Mayoufi Ouerghemmi, Ansgar Rinklake, Marcel Brouns
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Patent number: 12181217Abstract: An apparatus for separation of air by cryogenic distillation comprising: a system of columns; a first turbine; a warm compressor coupled to the first turbine; a second turbine; a cold compressor coupled to the second turbine; a heat exchanger; means for sending air cooled in the heat exchanger at an intermediate temperature of the heat exchanger to the cold compressor; means for sending expanded air from the second turbine to the system of columns; means for sending air compressed in the cold compressor to an intermediate point of the heat exchanger and then at least in part to the system of columns via a first valve; means for sending air compressed in the cold compressor to the inlet of the first turbine via a second valve without passing through the heat exchanger, wherein the means for sending air compressed in the cold compressor to the inlet of the first turbine via the second valve without passing through the heat exchanger is also connected to the inlet of the first turbine; means for sending a fractiType: GrantFiled: August 3, 2018Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Cavagne Patrice, Benedicte Dos Santos, Yann-Pierrick Lemaire
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Patent number: 12181110Abstract: A method for delivering a liquid cryogen from a liquid cryogen source to a storage tank can include the steps of: providing a bayonet system having an in-line pump disposed therein, the bayonet system having an upstream end and a downstream end; attaching the bayonet system to an upstream conduit, wherein the upstream conduit is in fluid communication with a liquid cryogen source, attaching the bayonet system to a downstream conduit, wherein the downstream conduit is in fluid communication with the storage tank; purging and cooling the upstream conduit and the downstream conduit; and flowing the liquid cryogen from the liquid cryogen source to the storage tank.Type: GrantFiled: May 11, 2023Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes
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Patent number: 12180073Abstract: The invention relates to a process and a plant for producing hydrogen by steam reforming and high-temperature electrolysis. Steam reforming produces a synthesis gas from a carbon-containing starting material and steam. Process heat generated in the context of the steam reforming is utilized for producing steam from water. Thus-produced steam is utilized as reactant for producing an electrolysis product in a high-temperature electrolysis step, wherein the electrolysis product includes at least hydrogen and oxygen. Hydrogen is separated from the synthesis gas produced by steam reforming and from the electrolysis product produced by high-temperature electrolysis.Type: GrantFiled: September 10, 2021Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Swatantra Kumar Shrivastava
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Patent number: 12173854Abstract: A cryogen storage vessel at an installation is filled with liquid cryogen from a liquid cryogen storage tank that has a pressure lower than that of the vessel. After headspaces of the vessel and tank are placed in fluid communication with another via a gas transfer vessel and are pressure-balanced, a pump in a liquid transfer line connected between the tank and the vessel is operated to transfer amounts of liquid cryogen from the tank to the vessel via the liquid transfer line and pump as amounts of gaseous cryogen are transferred, through displacement by the pumped cryogenic liquid, from the vessel to the tank.Type: GrantFiled: November 22, 2022Date of Patent: December 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
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Patent number: 12173403Abstract: Disclosed are Group 6 transition metal-containing thin film forming precursors to deposit Group 6 transition metal-containing films on one or more substrates via vapor deposition processes.Type: GrantFiled: April 30, 2021Date of Patent: December 24, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Rocio Alejandra Arteaga Muller, Raphael Rochat, Antonio Sanchez, Jean-Marc Girard, Nicolas Blasco, Santiago Marques-Gonzalez, Clément Lansalot-Matras, Jooho Lee, Zhiwen Wan
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Patent number: 12173409Abstract: A process for the deposition of a coating on at least a part of a metallic substrate, a) mixing a liquid and a powder having particles of a metallic material to be deposited and particles of a pickling agent, so as to prepare a suspension, b) application of the suspension prepared in step a) to at least a part of the surfaces of the metallic substrate, so as to obtain a substrate-suspension assembly, c) carrying out a heat treatment of the assembly which includes heating at a first temperature of at least 500° C. and heating at a second temperature greater than the first temperature, and d) recovery of a substrate coated, at least in part, with a coating, the pickling agent being a halogenated compound and the suspension having from 10% to 60% of the pickling agent, with respect to the total weight of the powder.Type: GrantFiled: October 16, 2020Date of Patent: December 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Sébastien Doublet, Nicolas Ramenatte, Stéphane Mathieu, Michel Vilasi, Léo Portebois
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Patent number: 12163741Abstract: A heat exchanger having multiple plates which are mutually parallel and parallel to a longitudinal direction, the exchanger having a length measured in the longitudinal direction, the plates being stacked with spacing so as to define a first series of passages for the flow, in a general flow direction parallel to the longitudinal direction, of at least a first refrigerant fluid and a second refrigerant fluid, at least one passage of the first series being defined between two adjacent plates.Type: GrantFiled: July 23, 2020Date of Patent: December 10, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Natacha Haik-Beraud, Sophie Lazzarini
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Patent number: 12163627Abstract: Method for delivering liquefied gas, especially hydrogen, by means of at least one mobile storage facility, especially a storage facility transported by lorry, comprising a step of filling the mobile storage facility with liquefied gas at a source plant, the mobile storage facility containing, after filling, liquefied gas and a fraction of the vaporized gas, the method comprising a movement of the mobile storage facility from the source plant to a receiving station and a transfer of liquefied gas from the mobile storage facility to the receiving station, characterized in that it comprises a step of interim cooling of the liquefied gas contained in the mobile storage facility between the source plant and the receiving station by means of a cooling device comprising a liquefied gas tank and a refrigerating element.Type: GrantFiled: February 5, 2021Date of Patent: December 10, 2024Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Laurent Allidieres, Thomas Fayer, Pierre Barjhoux
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Patent number: 12158245Abstract: A cryogen storage vessel at an installation is filled with liquid cryogen from a liquid cryogen storage tank that has a pressure lower than that of the vessel. After headspaces of the vessel and tank are placed in fluid communication with another via a gas transfer vessel and are pressure-balanced, a pump in a liquid transfer line connected between the tank and the vessel is operated to transfer amounts of liquid cryogen from the tank to the vessel via the liquid transfer line and pump as amounts of gaseous cryogen are transferred, through displacement by the pumped cryogenic liquid, from the vessel to the tank. Following filling, the tank is disconnected and then driven to another location to repeat the filling process with a second vessel that is at a different location.Type: GrantFiled: November 22, 2022Date of Patent: December 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector