Patents Assigned to L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation
des Procedes Georges Claude
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Patent number: 12135165Abstract: A method for liquefying a hydrocarbon stream using a heat exchanger having a plurality of plates parallel to each other and to a longitudinal direction that is substantially vertical, the exchanger having a length measured in the longitudinal direction, the plates being stacked with spacing so as to define between them at least one first series of passages for the flow of at least part of a two-phase cooling stream vaporizing by exchanging heat with at least the hydrocarbon stream.Type: GrantFiled: July 21, 2020Date of Patent: November 5, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Natacha Haik-Beraud, Jean-Marc Peyron, Sophie Lazzarini, Thomas Morel
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Furnace for endothermic process and process for operating a furnace with improved burner arrangement
Patent number: 12130012Abstract: The invention relates to a furnace for performing an endothermic process, the furnace including a plurality of process tubes containing a catalyst for converting a gaseous feed, wherein the process tubes are arranged in rows within the furnace, each row of process tubes thereby defining a process tube row, a plurality of inner burners arranged in rows, each row of inner burners being arranged between and parallel to process tube rows, thereby defining an inner burner row, and a plurality of outer burners arranged in rows, each row of outer burners being arranged between and parallel to a process tube row and a furnace wall, thereby defining an outer burner row. A number of burners of an outer burner row is smaller than a number of burners of an inner burner row. The invention also relates to a process for operating a furnace for performing an endothermic process.Type: GrantFiled: October 28, 2019Date of Patent: October 29, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Philippe Tadiello, Diana Tudorache -
Patent number: 12123645Abstract: An installation and method for purifying and liquefying natural gas having, arranged in series, an adsorption purification unit, a unit for separating hydrocarbons by refrigeration, and a liquefier. The installation has a gas power plant for combined production of heat and electricity by hydrocarbon combustion. The installation has at least one electrical member, with the power plant being electrically connected to at least one of the electrical members in order to supply them with electrical energy.Type: GrantFiled: September 12, 2019Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Marc Bernhardt, Golo Zick, Rémi Nicolas
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Patent number: 12123540Abstract: A detachable coupling device with automatic closure for the transport of fluid, including two fluid transport pipes extending in a longitudinal direction and each having, at one connection end, a valve mechanism, the device also including an external tube disposed around each transport pipe and, in the coupled position, the two connection ends are configured to be relatively longitudinally displaceable between a first configuration, in which the valve mechanisms are closed, and a second configuration, in which the valve mechanisms are open, the transition from the first configuration to the second configuration being realized by a relative longitudinal movement of the two valve mechanisms close to one another.Type: GrantFiled: November 15, 2022Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Gaëtan Coleiro, Yan Pennec
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Patent number: 12123418Abstract: In a compression process in a dynamic compressor having at least one first and one second compression stages, a first gas having a first molecular weight of less than 10 g/mol is compressed, at least one second fluid having a second molecular weight greater than 50 g/mol is mixed with the first gas to form a third gas to be compressed having a molecular weight greater than 10 g/mol, the third gas is sent to the first compression stage, the third gas is cooled in a first heat exchanger downstream of the first compression stage, where it is partially condensed, the partially condensed third gas is sent to a first phase separator to form a fourth gas having a lower molecular weight than the third gas and a first condensed liquid having a higher molecular weight than the third gas, the fourth gas is sent from the first phase separator to the second compression stage, the fourth gas compressed in the second compression stage is sent to cool in a second heat exchanger where it partially condenses, and the partiallyType: GrantFiled: July 20, 2020Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Patrick Le Bot
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Patent number: 12121931Abstract: An ultraviolet curing apparatus having: a roller for guiding a film coated with a resin; a first nitrogen gas introduction port and a second nitrogen gas introduction port for introducing nitrogen gas; a UV irradiation portion for irradiating the film with ultraviolet rays from between the first nitrogen gas introduction port and the second nitrogen gas introduction port; an oxygen concentration meter for measuring an oxygen concentration between the film and the UV irradiation portion; an air introduction port for introducing air between the film and the UV irradiation portion; and a controller for controlling at least any one of: an amount of air introduced from the air introduction port, an amount of nitrogen gas introduced from the first nitrogen gas introduction port, and an amount of nitrogen gas introduced from the second nitrogen gas introduction port, so that the oxygen concentration is within a preset oxygen concentration set range.Type: GrantFiled: August 9, 2022Date of Patent: October 22, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Kohei Nakatani, Tadasu Nakatani, Eiichi Mizutani
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Patent number: 12117127Abstract: A conditioning device for engaging with a filling and/or tapping connector of a pressurized-fluid container cock, including a body bearing at least one coupling member arranged about a longitudinal axis, a locking member which is movable with respect to the body and with respect to the coupling member, a valve pusher which is movable in a gas transfer duct, and a blocking member, wherein the upstream face of the blocking member includes a tightness seal arranged about the longitudinal axis to form sealing between the gas transfer duct and an internal circuit of a filling connector.Type: GrantFiled: September 8, 2020Date of Patent: October 15, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Antoine Frenal
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Patent number: 12117240Abstract: A process for the production of a liquid oxygen stream by the cryogenic rectification of an inlet air stream, including dividing the inlet air stream into a first portion, and a second portion. Cooling the first portion, and the second portion against a cooled multicomponent refrigerant circuit, thereby producing a first cooled portion, and a second cooled portion. Condensing the first cooled portion, thereby producing a condensed first portion, then introducing the condensed first portion into one or more distillation columns. Expanding the second cooled portion in a turbo-expander, thereby producing an expanded second portion, then introducing the expanded second portion within the one or more distillation columns. Producing within the one or more distillation columns at least a waste nitrogen stream, a nitrogen enriched stream, and an oxygen enriched stream. Withdrawing the oxygen enriched stream from the one or more distillation columns as a liquid oxygen stream.Type: GrantFiled: July 19, 2022Date of Patent: October 15, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Michael A. Turney, Alain Guillard
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Publication number: 20240335786Abstract: The invention relates to a process for separating carbon dioxide from a raw hydrogen product stream to produce a hydrogen product stream and a carbon dioxide product stream. The process includes the absorption of carbon dioxide in an absorption stage in an absorption medium and subsequent desorption of the carbon dioxide from the laden absorption medium in a plurality of decompression stages. According to the invention carbon dioxide substreams withdrawn from the decompression stages are combined into a carbon dioxide total stream and compressed in a plurality of serially arranged compression stages. Each compression stage having a suction pressure value is assigned at least one decompression stage with a corresponding desorption pressure value and the number of decompression stages corresponds at least to the number of compression stages.Type: ApplicationFiled: April 4, 2024Publication date: October 10, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Sophia SCHMIDT, Matthias LINICUS
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Patent number: 12109528Abstract: Process and plant for membrane permeation treatment of a carbon dioxide and methane-containing biogas stream in which the biogas stream is compressed with a compressor and the compressed biogas stream is fed to a membrane separation unit comprising first and second modules each containing at least one membrane selective for carbon dioxide over methane. The first module separates the compressed biogas stream into a first, second, and third methane-deficient permeates (in comparison to the biogas stream) and a first methane-enriched retentate (in comparison to the biogas stream). The first permeate being richer in methane than the second or third permeates. The second module separates the first permeate into a fourth methane-deficient permeate and a second methane-enriched retentate. The second and third retentates are recycled back to an inlet of the compressor.Type: GrantFiled: March 22, 2022Date of Patent: October 8, 2024Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Francois Barraud
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Patent number: 12109527Abstract: A process for separating two gaseous streams, including purifying a first gaseous stream in a first acid gas removal absorber, purifying in a first temperature swing adsorption unit, and then separating at a cryogenic temperature in a separation unit to produce a stream of fluid enriched in carbon monoxide and a stream of fluid enriched in hydrogen, sending a second gaseous stream containing at least carbon monoxide, hydrogen and at least one acid gas to a shift reaction unit, the shifted second stream is purified in a second acid gas removal absorber to remove carbon dioxide and the purified second stream is sent as a feed stream to a pressure swing adsorption unit to produce a hydrogen enriched stream, and sending at least part of the stream enriched in hydrogen from the separation unit as a feed stream to the pressure swing adsorption unit to produce the hydrogen-enriched stream.Type: GrantFiled: May 30, 2019Date of Patent: October 8, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Antoine Hernandez, Wei Guan
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Publication number: 20240327216Abstract: The present invention relates to a process and plant for producing a hydrogen- and carbon oxides-having synthesis gas by partial oxidation of a carbonaceous feedstock having nitrogen compounds. The invention takes advantage of the different solubility of NH3 and CO2 as the synthesis gas stream is cooled. Water is condensed continuously throughout the cooling of the synthesis gas stream. NH3 preferentially dissolves or condenses into the liquid phase during cooling, but at relatively high temperatures, above about 80 to 100° C. Further condensation at lower temperatures then preferentially dissolves or condenses CO2 into the liquid phase. Thus, the formation of ammonium salts during cooling of the synthesis gas is prevented.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Bryce WILLIAMS, Stefan WALTER
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Publication number: 20240327215Abstract: The invention relates to a partial oxidation reactor (POX reactor) for producing a raw synthesis gas stream by partial oxidation of a carbon-containing input stream in gaseous form, in liquid form or in solid, particulate form dispersed in a carrier liquid or a carrier gas in the presence of an oxygen-containing oxidant stream and optionally a moderator stream containing steam and/or carbon dioxide. The invention further relates to a process for producing a raw synthesis gas stream. The partial oxidation reactor according to the invention provides for introducing a cylindrical or frustoconical inlet region having a constant diameter or a diameter that is smaller on the entrance side. The inlet region is arranged upstream of a cylindrical main reactor portion and represents a bottleneck-like section since the largest diameter of the inlet region is smaller than the diameter of the cylindrical main reactor portion.Type: ApplicationFiled: March 28, 2024Publication date: October 3, 2024Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Karsten COVELLA, Hongbin XU, Matthias MUELLER-HAGEDORN
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Patent number: 12104130Abstract: A method of maintaining a syngas composition ratio during an upset condition, including detecting a reduction in the import carbon dioxide flow rate with a carbon dioxide import stream flow sensor, evaluating the reduction in carbon dioxide flow rate or carbon dioxide pressure in a controller, performing one or more predetermined corrective actions as instructed by the controller. Wherein the predetermined corrective actions are chosen from the following: opening a CO2 import stream flow valve, opening a hydrocarbon and steam stream feed valve, opening a CO2 backup stream control valve, opening a syngas backup letdown valve, and starting a composition adjustment unit.Type: GrantFiled: November 18, 2020Date of Patent: October 1, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Yufeng Qian, Pierre-Philippe Guerif, Alexander Roesch
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Patent number: 12106940Abstract: A method for storage and supply of a F3NO-free FNO-containing gas comprises the steps of storing the F3NO-free FNO-containing gas in a NiP coated steel cylinder with a polished inner surface, releasing the F3NO-free FNO-containing gas from the cylinder to a manifold assembly by activating a cylinder valve in fluid communication with the cylinder and the manifold assembly, de-pressurizing the F3NO-free FNO-containing gas by activating a pressure regulator in the manifold assembly so as to divide the manifold assembly into a first pressure zone upstream of the pressure regulator and a second pressure zone downstream of the pressure regulator, and feeding the de-pressurized F3NO-free FNO-containing gas to a target reactor downstream of the second pressure zone.Type: GrantFiled: January 13, 2022Date of Patent: October 1, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Ayaka Nishiyama, Jiro Yokota, Chih-yu Hsu, Peng Shen, Nathan Stafford
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Patent number: 12107477Abstract: Electric machine, in particular an electric motor for driving at least one compressor or circulator, comprising a stator and a rotor that are disposed in a casing, the machine comprising a cooling device disposed around the stator and comprising a circulation circuit for a cooling fluid, characterized in that the cooling device comprises a circulation pipe for the cooling fluid, comprising a portion embedded in a mass of material with high thermal conductivity such as metal or a metal alloy.Type: GrantFiled: June 23, 2020Date of Patent: October 1, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Fabien Durand, Loic Brunet Manquat, Guillaume Delautre
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Patent number: 12097463Abstract: A gas stream is purified by a TSA adsorption scheme including at least two adsorbers following, in an offset manner, a cycle including an adsorption phase, and a subsequently, a regeneration phase. The regeneration phase includes a depressurization step, a pre-regeneration step and a regeneration step. A gas circulator is used to circulate the gas within the adsorber in the pre-regeneration step in a closed loop while the circulating gas is heated with a heater.Type: GrantFiled: February 3, 2022Date of Patent: September 24, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Golo Zick
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Patent number: 12098805Abstract: A cryogenic fluid transfer device comprising a first tank, a second tank, and a fluid transfer circuit, wherein the first tank comprises a cryogenic fluid distribution tank configured to store a cryogenic fluid in a liquid phase in a lower part thereof and in a gaseous phase in an upper part thereof, wherein the second tank comprises a cryogenic receiving tank configured to house the cryogenic fluid in liquid phase in a lower part thereof and in gaseous phase in an upper part thereof, wherein the fluid transfer circuit is configured to connect the first and second tanks, the fluid transfer circuit comprising a first pipe connecting the upper parts of the first and second tanks and comprising at least one valve, and a second pipe connecting the lower part of the first tank to the second tank that comprises a pump that has an inlet connected to the first tank and an outlet connected to the second tank, wherein: the pump and the at least one valve of the first line are configured so as to ensure a fluidic connecType: GrantFiled: November 22, 2022Date of Patent: September 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
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Patent number: 12098883Abstract: An air gas separation plant comprising, in the direction of circulation of the air stream: a compression means that makes it possible to compress the air stream to a pressure P1 of between 1.15 bar abs and 2 bar abs, an adsorption unit of TSA type, and a cryogenic distillation unit, with the adsorption unit comprising at least two adsorbers A and B each having a parallelepipedal casing arranged horizontally and comprising: an air stream inlet and an air stream outlet, a fixed bed adsorbent mass, likewise of parallelepipedal shape, the faces of which are parallel to the faces of the casing; and a set of volumes allowing the air stream to pass through the adsorbent mass horizontally, over the entire cross-section and throughout the entire thickness thereof.Type: GrantFiled: February 12, 2020Date of Patent: September 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Benoit Davidian
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Mono-substituted cyclopentadienes and metal cyclopentadienyl complexes and synthesis methods thereof
Patent number: 12091374Abstract: A metal cyclopentadienyl complex has the formula: wherein m?0; M is a Group I, II or III main group metal, alkali or transition metal; C5H4 represents a Cp ring where two hydrogens are substituted by M and R(F)m; R(F)m is connected to any one of the carbon atoms of the Cp and selected from a hydrocarbyl, fluorohydrocarbyl, silyl group [SiR?3], or amino group [—NR1R2]. The metal cyclopentadienyl complexes include Li(C5H4-2-C5H11) (CAS No: 2413046-23-6), K(C5H4-2-C5H11), Na(C5H4-2-C5H11), K(C5H4-1-F—C4H10), K(C5H4-1,1,1-3F—C4H6), Li(C5H4-2-C4H9), or In(C5H4-2-C5H11) (CAS No.: 2364634-67-1). A mono-substituted cyclopentadiene has the formula: wherein m?0; C5H5 represents the Cp ring where one hydrogen is substituted R(F)m; R(F)m is connected to any one of the carbon atoms of the Cp and selected from a hydrocarbyl, fluorohydrocarbyl, silyl group [SiR?3], or amino group [—NR1R2]. The mono-substituted cyclopentadienes include C5H5-1-F—C4H10, C5H5-2-C5H11, C5H5-2-C4H9, or C5H5-1,1,1-3F—C4H6.Type: GrantFiled: January 19, 2022Date of Patent: September 17, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Grigory Nikiforov