Patents Assigned to L'Air Liquide Societe Anonyme Pour l'Etude et l'Exploitations des Procedes Georges Claude
  • Patent number: 8766645
    Abstract: A method for tracking the deterioration of the insulators in a rotating machine, a method for preventive maintenance of these machines using this tracking and devices using the tracking method is presented.
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: July 1, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Gérard Friedrich, Marie Jaillet-Delclaud, Emilie Renouard-Mouren, David Laurent, Bernard Mineur, Emmanuel Odic
  • Patent number: 8765657
    Abstract: The invention relates to a microbicidal use solution which comprises a) one or more isothiazolin-3-ones and b) one or two organic amines selected from N-dodecylpropane-1,3-diamine and bis(aminopropyl)-dodecylamine and optionally c) one or more oxidizing agents. The use solution is preferably in the form of technical and domestic products.
    Type: Grant
    Filed: September 22, 2010
    Date of Patent: July 1, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Wolfgang Beilfuss, Ralf Gradtke, Ingo Krull, Jennifer Knopf
  • Patent number: 8762079
    Abstract: (EN) The invention relates to a method for estimating the characteristic parameters of a cryogenic tank (1), in particular geometric parameters, including: a step comprising the measurement of the pressure differential between the upper and lower parts of the tank prior to filling DPmes—before; a step comprising the measurement of the pressure differential between the upper and lower parts of the tank after filling DPmes—after; a step comprising the determination of the mass of liquid delivered (mdelivered) during filling; and a step comprising the calculation of a first geometric parameter (R) of the tank, namely the radius (R) which is calculated from equation (I), wherein g is the Earth's gravitational acceleration and MAVO is a density coefficient that is a function of the density of the liquid and the gas in the tank and optionally in the pressure measuring pipes (11) when the pressure differential is measured by at least one remote pressure sensor connected to the upper and lower parts of the tank via r
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: June 24, 2014
    Assignee: L'air Liquide, Societe Anonyme pour l'etude et l'exploitation des Procedes Georges Claude
    Inventors: Fouad Ammouri, Florence Boutemy, Jonathan Macron
  • Patent number: 8756953
    Abstract: The device according to the invention for the cooling of articles, comprising at least one channel which can be connected to a first coolant source such that a first stream of a first coolant can flow through the channel, the articles to be cooled being introducible into the stream, is distinguished in that at least one cross-sectional stabilizer for stabilizing the cross section of the at least one channel is formed. The device according to the invention advantageously allows the defined cooling of articles, in particular the freezing of drops of a liquid or pasty material, in particular of liquid or pasty foods. In particular, a deformation, such as warping, of the channels on account of pronounced temperature gradients and/or temperature transients is effectively reduced. Thus, even after cooling-down operations, uniform cooling conditions can be ensured.
    Type: Grant
    Filed: May 5, 2008
    Date of Patent: June 24, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Robert Taylor
  • Patent number: 8758867
    Abstract: Methods and compositions for depositing metal films are described herein. In general, the disclosed methods utilize precursor compounds comprising gold, silver or copper. More specifically, the disclosed precursor compounds utilize neutral ligands derived from ethylene or acetylene.
    Type: Grant
    Filed: September 17, 2008
    Date of Patent: June 24, 2014
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude
    Inventors: Benjamin J. Jurcik, Jr., Christian Dussarrat
  • Patent number: 8762291
    Abstract: Techniques are disclosed for increasing the robustness of optimization solutions for bulk gas distribution, relative to uncertain events such as unexpected plant outages. The techniques actively consider different assumptions regarding unexpected plant outages while searching for a solution (i.e., when generating a delivery schedule). A robust solution (delivery schedule) is one on which a plant outage only has a limited impact. A computer-implemented delivery scheduling application may identify a robust solution that performs well with respect to a range of uncertain future conditions (e.g., a variety of plant outages), at the lowest additional cost to the producer/distributor relative to other solutions.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: June 24, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude Et l'Exploitation des Procedes Georges Claude
    Inventors: Nicoleta Neagu, Hugues Dubedout
  • Publication number: 20140170517
    Abstract: A method for depolluting and regenerating a catalytic fuel-cell electrode, the reaction of the fuel of the cell and capture of at least one polluting species occurring on the catalytic electrode, comprises: a decrease, at a constant first reference current density, in fuel flow, relative to a nominal fuel flow, for a first length of time, leading to a value for the stoichiometric coefficient of fuel lower than 1, to increase oxidation potential on the catalytic electrode and reach oxidation potential of the polluting species, to eliminate it; a cut-off of current for a cut-off time; an increase in flow above nominal flow, leading to a value of stoichiometric coefficient higher than or equal to 1; and an increase in current density until a second current density chosen by operator and possibly identical to or different from the initial reference current density, is reached.
    Type: Application
    Filed: June 12, 2012
    Publication date: June 19, 2014
    Applicants: L'AIR LIQUIDE, Société Anonyme pour l'étude et l'exploitation des procédés Georges Claude, COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sylvain Passot, Christel Faure, Alejandro Franco, Olivier Lemaire
  • Patent number: 8753718
    Abstract: The invention concerns the use of the ruthenium-containing precursor having the formula (Rn-chd)Ru(CO)3, wherein: (Rn-chd) represents a cyclohexadiene (chd) ligand substituted with n substituents R, any R being in any position on the chd ligand; n is an integer comprised between 1 and 8 (1?n?8) and represents the number of substituents on the chd ligand; R is selected from the group consisting of C1-C4 linear or branched alkyls, alkylamides, alkoxides, alkylsilylamides, amidinates, carbonyl and/or fluoroalkyl for R being located in any of the eight available position on the chd ligand, while R can also be oxygen O for substitution on the C positions in the chd cycle which are not involved in a double bond for the deposition of a Ru containing film on a substrate.
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: June 17, 2014
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Christian Dussarrat, Julien Gatineau
  • Publication number: 20140157822
    Abstract: An improved refrigeration cycle is provided. The cycle provides for improved thermal performance by incorporating a refrigerant makeup tank that introduces liquid refrigerant with expanded refrigerant upstream of the heat exchanger, thereby providing a savings in either electricity costs or refrigerant.
    Type: Application
    Filed: December 6, 2012
    Publication date: June 12, 2014
    Applicant: L'air Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Michael A. TURNEY, Alain BRIGLIA
  • Patent number: 8747525
    Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic compound and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic compound. The fiber is made by extruding first and second suspensions of the first and second ceramic compounds in polymeric binders and solvent from a spinnerette and coagulating the nascent hollow fiber to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binder is burned off. Second, the sheath is densified and the second ceramic compound is sinter without fully sintering the first ceramic compound. The first ceramic compound has a melting point higher than that of the second ceramic compound.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: June 10, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Dean W. Kratzer, Tao Li, Madhava R. Kosuri
  • Patent number: 8749112
    Abstract: The motion of the magnetized movable masses of a bilinear electrodynamic motor comprising two movable masses moving in opposite senses parallel to the axis (x-x) of the motor is balanced. At least one first magnetic sensor and at least one second magnetic sensor are provided which are able to deliver respectively a first electrical signal (s1(t)) and a second electrical signal (s2(t)) respectively representative of the motion of a first and of a second movable mass. An error signal (?s(t)) equal to the difference between the said first (s1(t)) and second (s2(t)) electrical signals is recorded. A harmonic analysis of the error signal performed. A sinusoidal excitation signal (e1(t)) at a given frequency f0 is applied to the first movable mass.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: June 10, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Jonathan Buquet, Gérald Aigouy, Thierry Trollier
  • Patent number: 8747769
    Abstract: The invention relates to a catalytic reactor including: a reaction chamber; at least one catalytic structure made up of at least one catalytic cell-like architecture having outer dimensions at most 10% smaller than the inner dimensions of the reaction chamber; an annular space between the inner wall of the reaction chamber and the cell-like architectures; and at least one second structure positioned in the annular space, selected from among: a) a fibrous structure, or b) a structure including at least one metal collar clasping at least one portion of the cell-like architectures and supporting metal fins.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: June 10, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Pascal Del-Gallo, Daniel Gary, Aude Cuni, Mathieu Cornillac
  • Patent number: 8746009
    Abstract: Process for producing hydrogen from a gas mixture comprising hydrogen, CO2, CO, CH4 and water, employing a CO2 PSA unit, a cryogenic unit and an H2 PSA unit, in which process: a) said gas mixture is introduced into the CO2 PSA unit, producing a CO2-enriched fraction and CO2-depleted fraction; b) CO2-enriched fraction is introduced into the cryogenic unit, producing a CO2-enriched fraction and an H2-enriched fraction; c) the H2-enriched fraction is recycled upstream of the H2 PSA unit; and d) the CO2-depleted fraction coming from step b) is introduced into the H2 PSA unit, producing a hydrogen-enriched stream and a waste gas.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: June 10, 2014
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Christian Monereau, Céline Carriere
  • Patent number: 8741031
    Abstract: A composite hollow ceramic fiber includes a porous hollow core supporting a thin, dense sheath. The non-gas-tight core comprises a first ceramic material and an interconnecting network of pores. The gas-tight sheath comprises a second ceramic material. The fiber is made by extruding core and sheath suspensions from a spinnerette. The core suspension includes particles of the first ceramic material, a polymeric binder, a solvent, and a pore former material insoluble in the solvent. The sheath suspension includes particles of the second ceramic material, a polymeric binder and a solvent. The nascent hollow fiber is coagulated in a coagulant bath to effect phase inversion of the polymeric binders. The resultant green fiber is sintered in a two step process. First, the binders and pore former material are burned off. Second, the sheath is densified and the second ceramic material is sintered without fully sintering the core.
    Type: Grant
    Filed: July 31, 2011
    Date of Patent: June 3, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Madhava R. Kosuri, Dean W. Kratzer
  • Patent number: 8734569
    Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.
    Type: Grant
    Filed: July 1, 2010
    Date of Patent: May 27, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: David J. Hasse, Sudhir S. Kulkarni, Edgar S. Sanders, Jr., Jean-Pierre Tranier, Paul Terrien
  • Publication number: 20140138361
    Abstract: The invention relates to a plasma generating device that comprises at least one very high frequency source (>100 MHz) connected via an impedance adaptation device to an elongated conductor attached on a dielectric substrate, at least one means for cooling said conductor, and at least one gas supply in the vicinity of the dielectric substrate on a side opposite to that bearing the conductor. The invention also relates to plasma torches using said device.
    Type: Application
    Filed: November 22, 2013
    Publication date: May 22, 2014
    Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Zenon ZAKRZEWSKI, Michel MOISAN, Daniel GUERIN, Jean-Christophe ROSTAING
  • Publication number: 20140130482
    Abstract: Device for the purification of exhaust gases from a thermal combustion engine comprising: one or several ceramic catalyst carriers comprising an arrangement of crystallites of the same size, same isodiametric morphology and same chemical composition, or approximately the same size, same isodiametric morphology and same chemical composition in which each crystallite is in point or quasi-point contact with the surrounding crystallites, and one or several active phases for chemical destruction of impurities in the exhaust gas comprising metallic particles mechanically anchored in said catalyst carrier such that coalescence and mobility of each particle are limited to a maximum volume corresponding to the volume of a crystallite of said ceramic catalyst carrier.
    Type: Application
    Filed: June 8, 2012
    Publication date: May 15, 2014
    Applicants: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Centre National De La Recherche Scientifique, Universite De Limoges
    Inventors: Pascal Del-Gallo, Fabrice Rossignol, Thierry Chartier, Raphael Faure, Sebastien Goudalle, Claire Bonhomme
  • Publication number: 20140131484
    Abstract: The invention relates to a device for spraying particles of dry ice, notably for the purpose of cleaning surfaces, comprising a spray nozzle (4), allowing the passage of a working fluid carrying said particles, said nozzle (4) having an outlet orifice (5) and comprising a throat (6) and a divergent part (7) said divergent part (7) extending between the throat (6) and the outlet orifice (5) of the nozzle. According to the invention, said divergent part (7) has at least one first stage extending between the throat (6) and an outlet orifice of said first stage (5, 12) and the ratio between the area of the throat (6) and the area of said outlet orifice (5, 12) of the first stage of the divergent part is greater than 0.2.
    Type: Application
    Filed: June 19, 2012
    Publication date: May 15, 2014
    Applicant: L'Air Liquide Societe Anonyme pour L'Etude et L'Exploitation des Procedes Georges Claude
    Inventors: Philippe Gomez, Marc Leturmy, Benoit Loiselet
  • Patent number: 8722010
    Abstract: A method for the coproduction of oxygen, hydrogen and nitrogen using an ion transport membrane is provided. This method includes separating a compressed, hot air stream in an ion transport membrane, thereby producing a product oxygen stream and a hot nitrogen rich stream; utilizing at least a portion of the hot nitrogen rich stream as a heat source for reforming a hydrocarbons stream, thereby producing a syngas stream and a warm product nitrogen stream; and separating the syngas stream into a product hydrogen stream and a carbon dioxide rich stream.
    Type: Grant
    Filed: December 13, 2012
    Date of Patent: May 13, 2014
    Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Bhadra S. Grover
  • Patent number: 8721764
    Abstract: The invention relates to a method for operating a furnace, wherein a starting material comprising at least one metal element is molten, wherein the starting material is heated by at least one burner that is operated with a fuel volume flow of a fuel and an oxidant volume flow of an oxidant. An exhaust gas temperature of the furnace is monitored in an exhaust gas line at least at one measuring point downstream of a post combustion zone, wherein in a standard operational state a target fuel volume stream and a target oxidant volume stream is fed to the burner, wherein a change of the exhaust gas temperature is recorded at predetermined time frequencies and is compared to a predetermined threshold value.
    Type: Grant
    Filed: August 28, 2009
    Date of Patent: May 13, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Frank Rheker