Patents Assigned to L'Air Liquide Societe Anonyme
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Patent number: 12181217Abstract: An apparatus for separation of air by cryogenic distillation comprising: a system of columns; a first turbine; a warm compressor coupled to the first turbine; a second turbine; a cold compressor coupled to the second turbine; a heat exchanger; means for sending air cooled in the heat exchanger at an intermediate temperature of the heat exchanger to the cold compressor; means for sending expanded air from the second turbine to the system of columns; means for sending air compressed in the cold compressor to an intermediate point of the heat exchanger and then at least in part to the system of columns via a first valve; means for sending air compressed in the cold compressor to the inlet of the first turbine via a second valve without passing through the heat exchanger, wherein the means for sending air compressed in the cold compressor to the inlet of the first turbine via the second valve without passing through the heat exchanger is also connected to the inlet of the first turbine; means for sending a fractiType: GrantFiled: August 3, 2018Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Cavagne Patrice, Benedicte Dos Santos, Yann-Pierrick Lemaire
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Patent number: 12181107Abstract: The present invention relates to a method for improving stability of a hydrogen gaseous dispensing system. An example of such system is hydrogen powered vehicle fuel filling station. Vehicle is filled by multiple high pressure gaseous hydrogen tubes, usually one tube at a time. For safety and reliability reasons a control requirement for such system is to be able to deliver the hydrogen at constant rate to the fuel tank so that its rate of pressure increase stays constant during entire filling process. A dual pressure regulator arrangement is proposed to better maintain flow continuity and/or pressure during tube switching.Type: GrantFiled: November 16, 2021Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Pierre-Philippe Guerif, Paul Kong, Wendy May Yee Yip, Aaron Harris, Jorge Lopez
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Patent number: 12181110Abstract: A method for delivering a liquid cryogen from a liquid cryogen source to a storage tank can include the steps of: providing a bayonet system having an in-line pump disposed therein, the bayonet system having an upstream end and a downstream end; attaching the bayonet system to an upstream conduit, wherein the upstream conduit is in fluid communication with a liquid cryogen source, attaching the bayonet system to a downstream conduit, wherein the downstream conduit is in fluid communication with the storage tank; purging and cooling the upstream conduit and the downstream conduit; and flowing the liquid cryogen from the liquid cryogen source to the storage tank.Type: GrantFiled: May 11, 2023Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes
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Patent number: 12178214Abstract: A method for stunning animals and a respective stunning system is disclosed. Animals are lowered in a cradle into a pit filled with anoxic stunning gas. The cradle is provided with a heat sink, preferably comprising solid carbon dioxide, for cooling the stunning gas in the pit resulting in a density increase of the stunning gas in the pit. This reduces demixing of the stunning gas and rising of components such as nitrogen (N2) usually having a lower density than the air surrounding the stunning system.Type: GrantFiled: May 24, 2023Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Nadia Mayoufi Ouerghemmi, Ansgar Rinklake, Marcel Brouns
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Patent number: 12180947Abstract: The invention relates to a fluid-compression device including a compression chamber comprising a movable piston, the device comprising a first end housing a first end of the compression chamber, the device comprising a second end housing a second end of the compression chamber, the piston being translatable between the first and second ends of the compression chamber, the device comprising a regeneration pipe connecting the first and second ends of the compression chamber and including a regenerator, the device comprising a supply pipe comprising an upstream end intended to be connected to a source of fluid to be compressed and a downstream end opening into the first end of the compression chamber, the supply pipe comprising a valve assembly, the device comprising a pipe for discharging the compressed fluid comprising an upstream end connected to the compression chamber and a downstream end intended to be connected to a receiver of the compressed fluid, the discharge pipe comprising a valve assembly, characteType: GrantFiled: December 17, 2020Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des ProcedesInventors: Yan Pennec, Rasmey Try
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Patent number: 12180073Abstract: The invention relates to a process and a plant for producing hydrogen by steam reforming and high-temperature electrolysis. Steam reforming produces a synthesis gas from a carbon-containing starting material and steam. Process heat generated in the context of the steam reforming is utilized for producing steam from water. Thus-produced steam is utilized as reactant for producing an electrolysis product in a high-temperature electrolysis step, wherein the electrolysis product includes at least hydrogen and oxygen. Hydrogen is separated from the synthesis gas produced by steam reforming and from the electrolysis product produced by high-temperature electrolysis.Type: GrantFiled: September 10, 2021Date of Patent: December 31, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Swatantra Kumar Shrivastava
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Publication number: 20240424463Abstract: What is proposed is a reactor for performing exothermic equilibrium reactions, in particular for performing methanol synthesis and/or ammonia synthesis, by heterogeneously catalysed reaction of the corresponding reactant gases which makes it possible to overcome the establishment of the reaction equilibrium in the reactor. To this end, according to the invention, the coolant temperature is influenced and thus optimized along the longitudinal coordinate of the reactor through subcooling of the coolant.Type: ApplicationFiled: June 21, 2024Publication date: December 26, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Frank CASTILLO-WELTER, Nga Thi Quynh DO, Stephane HAAG
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Publication number: 20240426429Abstract: The invention relates to a facility for supplying liquefied hydrogen, comprising: a liquefier configured to deliver liquefied hydrogen; a first liquefied hydrogen tank configured to receive liquefied hydrogen coming from the liquefier; a transfer line configured to allow liquefied hydrogen to be transferred from the first tank to a tank to be filled; a second liquefied hydrogen tank configured to receive liquefied hydrogen coming from the first tank; a pressurization system configured to allow the second tank to be pressurized; a vaporization pipe connecting the second tank and/or the pressurization system to the transfer line.Type: ApplicationFiled: June 20, 2024Publication date: December 26, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Matthieu MULLER, Jean-Marc PEYRON, Matilde AIRES, Emeline VANDROUX, Bhadri PRASAD
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Patent number: 12173854Abstract: A cryogen storage vessel at an installation is filled with liquid cryogen from a liquid cryogen storage tank that has a pressure lower than that of the vessel. After headspaces of the vessel and tank are placed in fluid communication with another via a gas transfer vessel and are pressure-balanced, a pump in a liquid transfer line connected between the tank and the vessel is operated to transfer amounts of liquid cryogen from the tank to the vessel via the liquid transfer line and pump as amounts of gaseous cryogen are transferred, through displacement by the pumped cryogenic liquid, from the vessel to the tank.Type: GrantFiled: November 22, 2022Date of Patent: December 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
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Patent number: 12173403Abstract: Disclosed are Group 6 transition metal-containing thin film forming precursors to deposit Group 6 transition metal-containing films on one or more substrates via vapor deposition processes.Type: GrantFiled: April 30, 2021Date of Patent: December 24, 2024Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Rocio Alejandra Arteaga Muller, Raphael Rochat, Antonio Sanchez, Jean-Marc Girard, Nicolas Blasco, Santiago Marques-Gonzalez, Clément Lansalot-Matras, Jooho Lee, Zhiwen Wan
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Patent number: 12173409Abstract: A process for the deposition of a coating on at least a part of a metallic substrate, a) mixing a liquid and a powder having particles of a metallic material to be deposited and particles of a pickling agent, so as to prepare a suspension, b) application of the suspension prepared in step a) to at least a part of the surfaces of the metallic substrate, so as to obtain a substrate-suspension assembly, c) carrying out a heat treatment of the assembly which includes heating at a first temperature of at least 500° C. and heating at a second temperature greater than the first temperature, and d) recovery of a substrate coated, at least in part, with a coating, the pickling agent being a halogenated compound and the suspension having from 10% to 60% of the pickling agent, with respect to the total weight of the powder.Type: GrantFiled: October 16, 2020Date of Patent: December 24, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Sébastien Doublet, Nicolas Ramenatte, Stéphane Mathieu, Michel Vilasi, Léo Portebois
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Publication number: 20240417251Abstract: A method for producing ultra-low carbon hydrogen, including producing a flue gas stream, a raw syngas stream, and a high-pressure steam stream in a syngas generator, introducing the flue gas stream into a point-source carbon capture unit, thereby producing a clean flue gas stream and a first carbon dioxide stream, introducing an ambient air stream into a direct air carbon capture unit, thereby producing a clean air stream and a second carbon dioxide stream, and combining the first carbon dioxide stream and the second carbon dioxide stream and storing the combined carbon dioxide stream. The method may also include introducing the high-pressure steam stream into a steam turbine generator, thereby producing electrical power. The method may also include utilizing at least a portion of the electrical power in the direct air carbon capture unit.Type: ApplicationFiled: June 13, 2024Publication date: December 19, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Regis REAU, Robert GAGLIANO, Pavol PRANDA, Claire BAROU, Andres RAYA-IMBERNON
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Publication number: 20240417250Abstract: A reactor for producing synthesis gas by partial oxidation of a carbon-containing fuel, having a reaction space and a cooling space, wherein a cooled gas guide tube connects the reaction space and the cooling space to one another. The gas guide tube has a gas inlet region, which adjoins the reaction space, and a gas outlet region, which adjoins the cooling space. The gas guide tube has an inner tube and an outer tube, as a result of which an annular gap is formed, wherein the annular gap is connected fluidically to a coolant feed, and the inner tube has an opening to the annular gap in the gas inlet region of the gas guide tube, and a baffle is arranged in the region of this opening, and an orifice is arranged in the gas outlet region of the gas guide tube.Type: ApplicationFiled: June 13, 2024Publication date: December 19, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Peter WEIGAND, Matthias MULLER-HAGEDORN, Stefan WALTER, Michael KRESS
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Publication number: 20240410649Abstract: The invention relates to an installation for producing liquefied gas comprising a circuit for supplying feed gas, a set of heat exchangers, a refrigerator for cooling some or all of the set of heat exchangers, the supply circuit comprising, between the set of heat exchangers and the downstream end thereof, a final expansion turbine for expanding the feed gas in liquid state, the supply circuit comprising a bypass line of the final expansion turbine fitted with a first expansion valve, a second expansion valve disposed in series upstream or downstream of the first expansion valve and of the final expansion turbine, an additional heat exchange line designed to exchange heat with a heat exchanger of the set of heat exchangers when the feed gas is expanded by the first expansion valve via the bypass line, the additional heat exchange line carrying out this heat exchange with said heat exchanger between the expansion carried out by the first expansion valve and the expansion carried out by the second expansion valType: ApplicationFiled: June 12, 2024Publication date: December 12, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Marine ANDRICH, Ludovic GRANADOS, Baptiste PAGES, Emeline VANDROUX, Pierre BARJHOUX, Bhadri PRASAD
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Patent number: 12163741Abstract: A heat exchanger having multiple plates which are mutually parallel and parallel to a longitudinal direction, the exchanger having a length measured in the longitudinal direction, the plates being stacked with spacing so as to define a first series of passages for the flow, in a general flow direction parallel to the longitudinal direction, of at least a first refrigerant fluid and a second refrigerant fluid, at least one passage of the first series being defined between two adjacent plates.Type: GrantFiled: July 23, 2020Date of Patent: December 10, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Natacha Haik-Beraud, Sophie Lazzarini
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Patent number: 12163627Abstract: Method for delivering liquefied gas, especially hydrogen, by means of at least one mobile storage facility, especially a storage facility transported by lorry, comprising a step of filling the mobile storage facility with liquefied gas at a source plant, the mobile storage facility containing, after filling, liquefied gas and a fraction of the vaporized gas, the method comprising a movement of the mobile storage facility from the source plant to a receiving station and a transfer of liquefied gas from the mobile storage facility to the receiving station, characterized in that it comprises a step of interim cooling of the liquefied gas contained in the mobile storage facility between the source plant and the receiving station by means of a cooling device comprising a liquefied gas tank and a refrigerating element.Type: GrantFiled: February 5, 2021Date of Patent: December 10, 2024Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Laurent Allidieres, Thomas Fayer, Pierre Barjhoux
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Publication number: 20240401876Abstract: A hydrogen boil-off gas recovery method, comprises liquefying hydrogen by cooling a hydrogen feed stream in a first cryogenic cold box, further cooling the hydrogen in a second cryogenic cold box, liquefying the hydrogen in the second cryogenic cold box or downstream thereof, providing liquefied hydrogen a loading bay containing at least one hydrogen transport truck, sending boil-off gas from at least one hydrogen transport truck in the loading bay to which liquefied hydrogen has been provided to an indirect heat exchanger outside the first and second cryogenic cold boxes in order to warm the boil-off gas and mixing at least part of the warmed boil-off gas with the hydrogen feed stream upstream of the first cryogenic cold box or with hydrogen in a hydrogen refrigeration cycle used to provide refrigeration for the second cryogenic cold box as a function of the pressure of the boil-off gas.Type: ApplicationFiled: September 24, 2021Publication date: December 5, 2024Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l’Exploitation des Procedes Georges ClaudeInventors: Florence DIAS, Oriane FARGES, Ludovic GRANADOS, Baptiste PAGES
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Patent number: 12158245Abstract: A cryogen storage vessel at an installation is filled with liquid cryogen from a liquid cryogen storage tank that has a pressure lower than that of the vessel. After headspaces of the vessel and tank are placed in fluid communication with another via a gas transfer vessel and are pressure-balanced, a pump in a liquid transfer line connected between the tank and the vessel is operated to transfer amounts of liquid cryogen from the tank to the vessel via the liquid transfer line and pump as amounts of gaseous cryogen are transferred, through displacement by the pumped cryogenic liquid, from the vessel to the tank. Following filling, the tank is disconnected and then driven to another location to repeat the filling process with a second vessel that is at a different location.Type: GrantFiled: November 22, 2022Date of Patent: December 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Joshua Light, Jerry Hayes, Laurent Allidieres, Thomas Fayer, Cyril Benistand-Hector
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Patent number: 12158244Abstract: A device for filling pressurized gas tanks, including a fluid transfer circuit having an upstream end connected to a plurality of sources of pressurized fluid and a downstream end having at least one dispenser intended to be connected to a tank to be filled, the sources being connected in parallel, each source has a fluid outlet connected to a respective outlet valve, the transfer lines being connected in parallel to the at least one dispenser and each having a respective transfer valve, the transfer lines and the transfer valves being dimensioned so as to transfer a maximum transfer gas flow which is smaller than the maximum filling gas flow, the sum of a plurality of maximum transfer gas flows provided by a plurality of outlet valves and a plurality of transfer lines being greater than or equal to the maximum filling gas flow.Type: GrantFiled: March 23, 2021Date of Patent: December 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Benjamin Fischer, Herve Paoli
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Patent number: 12158242Abstract: A tank for storing liquefied gas, having a shell delimiting a storage volume extending in a main direction which is horizontal in the use configuration of the tank, the tank comprising multiple deflecting walls in the storage volume which extend in an offset manner in the main direction configured to force the fluid to perform at least one back-and-forth movement in the main direction as the fluid passes between the lower end and the upper end of the storage volume, wherein a plurality of these deflecting walls are located in the lower half of the storage volume.Type: GrantFiled: May 3, 2021Date of Patent: December 3, 2024Assignee: L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Jean-Marc Bernhardt