Patents Assigned to L'Exploitation Des
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Patent number: 7241389Abstract: Methods for oxidizing a liquid with an oxidization gas in a closed volume reactor. A feed liquid which contains compounds to be oxidized is fed into the closed volume reactor, and a feed gas containing oxygen is fed into the reactor so as to form a gas overhead above the feed liquid. The overhead is later purged at a specific rate so as to ensure a predetermined oxygen partial pressure is maintained in the gas overhead. The value of this partial pressure corresponds to a predetermined, desired rate of oxidation of the compounds contained in the feed liquid.Type: GrantFiled: December 18, 2001Date of Patent: July 10, 2007Assignee: L'Air Liquide, Société Anonyme A Directoire et Conseil de Surveillance pour l'Etude Et l'Exploitation des Procedes Georges ClaudeInventors: Philippe Campo, Michel Muguet, Nadège Berthier
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Patent number: 7241970Abstract: A method of brazing galvanized metal parts such as those used for motor vehicle elements or container components. The parts are joined together to create a brazed joint by using at least one electric arc, a metal filler wire, and a gas shield. The gas shield contains hydrogen, carbon dioxide, and argon.Type: GrantFiled: January 17, 2003Date of Patent: July 10, 2007Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Marie Fortain, Jean-Yves Mouton, Thomas Opderbecke
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Patent number: 7241971Abstract: A method and an apparatus for a hybrid laser beam and electric arc welding process. A laser beam, an electric arc, a shielding gas and a consumable welding wire are used to create a weld on a steel work piece by melting the welding wire. The weld contains 30 to 1000 ppm titanium by weight, at least 0.7% manganese by weight, 50 to 1000 ppm oxygen by weight, and less than 10% nickel. The welding wire is either solid welding wire or cored welding wire, and may contain, in varying percentages: titanium, manganese, iron, nickel, boron, molybdenum, carbon or chromium.Type: GrantFiled: January 20, 2005Date of Patent: July 10, 2007Assignees: L'Air Liquide, Société Anonyme À Directoire et Conseil de Surveillance pour L'Étude et L'Exploitation des Procedes Georges Claude, La Soudure Autogène FrancaiseInventor: Christian Bonnet
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Patent number: 7238215Abstract: In an integrated process for the production of synthesis gas, a partial oxidation unit and a steam methane reformer are used to convert natural gas or another fuel to first and second mixtures of at least carbon monoxide and hydrogen, only the first process consuming oxygen. Carbon dioxide derived from the second mixture is sent to the inlet of the first process to reduce the oxygen consumption. The first and optionally second mixtures may be used as synthesis gas for a process such as a Fischer Tropsch process.Type: GrantFiled: December 21, 2001Date of Patent: July 3, 2007Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Pierre-Robert Gauthier, Christian Lacoste
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Patent number: 7228715Abstract: A low temperature air separation process and apparatus for producing pressurized gaseous product in an air separation unit using a system of distillation columns which include cooling a compressed air stream in a heat exchange line to form a compressed cooled air stream, sending at least part of the compressed, cooled air stream to a column of the system, liquefying a process stream to form a first liquid product, storing at least part of the first liquid product in a storage tank, sending at least part of the above first liquid product from the storage tank to the air separation unit as one of the feeds, extracting at least one second liquid product stream from a column of the column system and pressurizing the at least one second liquid product stream, vaporizing the above pressurized second liquid product stream to form pressurized gaseous product in the heat exchange line and extracting a cold gas without warming it completely in the heat exchange line.Type: GrantFiled: July 27, 2004Date of Patent: June 12, 2007Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventors: Jean-Renaud Brugerolle, Bao Ha
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Patent number: 7227099Abstract: Methods of controlling an arc welding shop. In the shop, several welding torches are used and each torch is supplied with consumable wire. The wire moves at a wire speed and is subjected to an electrical current. For each torch, either an average wire speed or an average electrical current, as measured over a fixed time period, is determined by a sensor. These values then allow productivity parameters to be selected for the torches. Productivity parameters include the duty factor, the deposition rate, the average duty factor, and the average deposition rate.Type: GrantFiled: July 30, 2003Date of Patent: June 5, 2007Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et, l'Exploitation des Procedes Georges, ClaudeInventors: Roger Blot, Serban Cantacuzene, Eric Cazottes, Stephane Cosson, Jean-François Lecouffe, Viwek Vaidya
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Patent number: 7225637Abstract: Process and apparatus for optimization of integrated air separation systems. In an integrated process for the compression, cooling, and purification of air, an adiabatic compressor compresses an air stream to produce a compressed air stream. The compressed air stream is used to warm a first pressurized stream at a first pressure and a second pressurized stream at a second pressure. The produced streams include a first warmed pressurized stream, a second warmed pressurized stream, and a cooled compressed air stream. The first warmed pressurized stream is gaseous and is expanded in a turbine. At least part of the work produced by the turbine is used to power the adiabatic compressor. The cooled compressed air stream is further cooled by a cooling unit by heat exchange with water, and then purified in a purifying unit using a TSA process.Type: GrantFiled: December 27, 2004Date of Patent: June 5, 2007Assignee: L'Air Liquide Société Anonyme á´ Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventor: Patrick Le Bot
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Patent number: 7223978Abstract: The invention relates to a method for measuring the quantity of chemical species contained in a high-temperature gas, and especially the quantity of CO and/or CO2 contained in a gas emitted from a metal treating furnace, especially a light-arc furnace (EAF) or a converter (BOF). According to the invention, part of the gas to be analysed is extracted, the temperature of said gas is reduced to at least 300° C., preferably to a temperature that is lower than or equal to 200° C., in such a way as to obtain a at a temperature between 300° C., preferably 200° C., and the ambient temperature, and at least the quantity of CO and/or CO2 said gas is then measured by means of the coherent light signal which is emitted by a laser diode through the gas and is retrieved on emergence from the gas.Type: GrantFiled: August 31, 2004Date of Patent: May 29, 2007Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procédés Georges ClaudeInventors: Jean-Claude Vuillermoz, Jacky Laurent, Savine Bockel-Macal, Fabien Januard, Bruno Allemand
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Patent number: 7223356Abstract: The invention concerns a method for preparing a thin ceramic material with controlled surface porosity gradient, including (A) infiltrating a porous pore-forming substrate of controlled thickness, with a ceramic material suspension; (B) evaporating the solvent; (C) a step which includes eliminating the pore-forming agents and the various organic additives, and (D) a sintering step. The invention also concerns the use of the ceramic material in the method for preparing a solid electrolyte and a mixed ionic-electronic conductor, in methods for preparing ultra-pure oxygen, for eliminating oxygen from a gaseous atmosphere, for producing heat energy, for preparing gas or liquid filtering membranes, for ceramic/metal joints, for biomaterials and sensors.Type: GrantFiled: November 26, 2001Date of Patent: May 29, 2007Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil deSurveillance pour l'Étude et l'Exploitation des Procédés Georges ClaudeInventors: Thierry Chartier, François Guillotin
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Patent number: 7223607Abstract: The invention relates to a process for the detection of hydrocarbons other than methane in a gas predominantly or essentially comprising oxygen, as well as methane and the said hydrocarbons other than methane, the said process comprising: a stage of detection of the combined hydrocarbons in the said gas, providing a first value for the combined hydrocarbons, a stage of combustion of the hydrocarbons other than methane, a stage of detection of methane in the said gas, providing a second value, a stage of calculation of the amount of hydrocarbons other than methane by the difference between the first value and the second value. The invention also relates to a device for implementing this process.Type: GrantFiled: February 5, 2002Date of Patent: May 29, 2007Assignee: L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Francis Bryselbout
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Patent number: 7219514Abstract: A method and apparatus for separating air by cryogenic distillation. The energy of an air separation installation is increased by reducing the size of the exchangers, and therefore increasing the head losses and the temperature differences in the exchange line, and increasing the temperature difference at the main vaporizer. The size of the distillation column is reduced by minimizing the number of theoretical trays and the number of sections of packing or trays. The size of the refrigerating turbine is also reduced by increasing its intake temperature in order to reduce the output.Type: GrantFiled: October 8, 2002Date of Patent: May 22, 2007Assignee: L'Air Liquide, Société Anonyme á Directoire et Conseil de Surveillance our l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Emmanuel Garnier, Frédéric Judas, Frédéric Staine
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Patent number: 7197894Abstract: An integrated process and air separation process including the steps of: Work expanding at least one first pressurized gas 39 derived from a first process at a first site 1, using work generated by the expansion of the at least one pressurized gas to drive a first air compressor 5 at the first site and removing compressed air from the first air compressor, sending at least part of the compressed air 19 from the first air compressor to an air separation unit 21, located at a second site 2 remote by at least 1 km from the first site, separating at least part of the compressed air sent from the first site to the second site in the air separation unit and removing at least one fluid 37 enriched in a component of air from the air separation unit and sending at least part of the fluid enriched in a component of air to the first site.Type: GrantFiled: February 13, 2004Date of Patent: April 3, 2007Assignee: L'Air Liquide, Societe Anonyme A' Directorie et Conseil De Survelliance Pour L'Etude Et, L'Exploltation Des Procedes Georges, ClaudeInventors: Alain Guillard, Patrick Le Bot, Bernard Saulnier
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Patent number: 7195028Abstract: A self-contained oxygen generator containing a PSA unit and a flowmeter in the outlet line. The flowmeter provides a signal which represents the flow rate of the oxygen in the outlet line. A leakage circuit with a calibrated orifice and a solenoid valve are also located on the outlet line. In response to a signal from the flowmeter, the solenoid can be actuated so as to provide a calibrated leakage at the outlet of the PSA. This calibrated leakage is useful when overall oxygen usage is too low.Type: GrantFiled: August 2, 2004Date of Patent: March 27, 2007Assignee: L'Air Liquide, Société Anonyme Á Directoire et Conseil de Surveillance pour l'Étude Et l'Exploitation des Procedes Georges ClaudeInventors: Chrystelle Basset, Philippe Jean, Nicolas Schmutz
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Patent number: 7192626Abstract: Silicon nitride film is formed on substrate by feeding trisilylamine and ammonia into a CVD reaction chamber that contains a substrate. The ammonia gas/trisilylamine gas flow rate ratio is set to a value of at least about 10 and/or the thermal CVD reaction is run at a temperature no greater than about 600° C. Silicon oxynitride is obtained by introducing an oxygen source gas into the CVD reaction chamber. This method avoids the production of ammonium chloride and/or the incorporation of carbonaceous contaminants which are detrimental to the quality of the deposited film.Type: GrantFiled: September 24, 2003Date of Patent: March 20, 2007Assignee: L'Air Liquide, Société Anonyme á Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Christian Dussarrat, Jean-Marc Girard, Takako Kimura, Naoki Tamaoki, Yuusuke Sato
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Patent number: 7176410Abstract: An electric-arc welding process for assembling parts that are components of a motor vehicle, in which a consumable wire is used that is subjected to a cyclic mechanical movement. The wire is moved closer to and then further away from the parts to be welded so as to create a short arc between the end of the consumable wire and at least one of the parts to be joined. In this way, molten metal is deposited in order to progressively produce a welded joint between the parts.Type: GrantFiled: January 17, 2003Date of Patent: February 13, 2007Assignees: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Claude, La Soudure Autogene FrancaiseInventors: Jean-Marie Fortain, Gérard Plottier
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Patent number: 7171815Abstract: The invention is a method for operating a cryogenic tunnel through which products to be chilled or deep-frozen pass. This tunnel is equipped with means for injecting a cryogenic fluid and means for extracting the cold gases in the tunnel. The method includes obtaining an entry or an exit gas temperature from a gas temperature probe outside the tunnel in proximity to the tunnel entrance or exit. The method also includes obtaining an ambient temperature from an ambient temperature probe located outside the tunnel. The method also includes determining a first delta which is the difference between the ambient temperature and the gas temperature. And the method includes controlling the extraction rate of the extraction means by feedback as a function of the the temperature difference between the first delta and a set point, in order to restore the value of the first delta to the setpoint value if necessary.Type: GrantFiled: March 12, 2003Date of Patent: February 6, 2007Assignee: L'Air Liquide, Societe Anonyme a Directoire Et Conseil de Surveillance pour l'Etude Et l'Exploitation des Procedes Georges ClaudeInventors: Didier Pathier, Alain Cloarec, Robert Taylor
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Patent number: 7168322Abstract: The invention concerns a method for non-destructive ultrasonic control, combining time-of-flight diffraction (TOFD) and inclined longitudinal wave techniques, of weld joints assembling two abutted parts. The method consists of using the time-of-flight diffraction technique, displacing in the longitudinal or circumferential direction, along the weld joint to be controlled, at least one pair consisting of a first transducer and of a second transducer, one transmitting and the other receiving ultrasonic waves, these transducers being laterally positioned on either side of the joint to be controlled, these transducers comprising piezoelectric ceramics or crystals. Furthermore, it consists of displacing along the welded joint to be controlled, using the inclined longitudinal wave technique, at least a third transducer, so as to detect any defect of the joint located at a thickness ranging between 0.5 mm and 15 mm.Type: GrantFiled: June 13, 2003Date of Patent: January 30, 2007Assignee: L'Air Liquide Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Olivier Bardoux, Mario Cence, Sophie Wastiaux
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Patent number: 7167700Abstract: An installation to provide data concerning an object. An electronic label, which includes data storage, is fixed on the object. The installation is capable of reading least part of the data stored by the label and is also capable of accessing a database which contains data concerning the object. The database is associated with an address in that database locating information is stored in the electronic label. The database is accessed on the basis of this locating data, which may be read by a reader. The installation may be used for marking and tracing gas packages.Type: GrantFiled: July 25, 2001Date of Patent: January 23, 2007Assignee: L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Jean-Renaud Brugerolle, Laurent Ferenczi
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Patent number: 7156283Abstract: A method for producing a soldered joint between the metal balls present in either a ball grid array or a chip-scale package, and the receiving pads for a circuit printed on a substrate or the receiving pads of an integrated circuit. Solder cream or an adhesive flux is deposited on the receiving pads, which then have metal balls are placed on them so as to form an assembly. The assembly is placed in an oven so as to heat the metal balls above their melting point. The balls are then cooled at a rate around 5° C./sec, so that the balls remain in their liquid state for a time period between 20 seconds to 65 seconds.Type: GrantFiled: December 10, 2001Date of Patent: January 2, 2007Assignee: L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Claude Bonet
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Patent number: 7152741Abstract: The use of ozone during certain stages of metal separation by flotation degrades certain collectors that are absorbed on the particle surface, as well as the collectors and frothers in the liquid slurry. As a result, the mineral particle has a fresh surface and new chemical reagent(s) can be added in the subsequent flotation step(s). Also since ozone oxidizes the iron sulfide particles faster than the other mineral particles, depending upon the duration of treatment, the ozone concentration, and the kg O3/ton consumed by the treated ore, the surface of the iron sulfide particles may be partially or even totally oxidized, thus allowing better separation. As a consequence, the iron content is decreased, and the grade of the mineral value such as zinc, copper, and nickel increases. Also, sulfide emissions during heat treatment or further processing of the minerals are decreased due to decrease iron sulfide content.Type: GrantFiled: February 12, 2003Date of Patent: December 26, 2006Assignees: Air Liquide Canada, L'Air Liquide. Sociètè Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procedes Georges ClaudeInventors: Javier Jara, Yawo Zuttah