Abstract: Galvanic metal-water cells and methods of manufacturing positive electrodes to be used in said galvanic metal-water cells. The galvanic metal-water cells in accordance with various embodiments include a cathode that includes a layer comprising nickel-molybdenum deposited thereon. The nickel-molybdenum coated cathodes exhibit favorable hydrogen evolution reaction overpotential compared with existing devices. In these galvanic metal-water cells, the metal is oxidized and water is reduced.

Abstract: An electrochemical cell and a method of operating the same. In accordance with various embodiments, the cell includes an anode, one or more cathodes opposite the anode defining a pathway there between. Chemical reactions allow the electrolyte to flow through the defined pathway without requiring a pumping device.

Abstract: Systems, methods, and apparatus configured for the mitigation of hydrogen accumulation within electrochemical systems are generally described. The systems, methods, and apparatus described herein can be, according to certain embodiments, configured to be part of an electrochemical system in which hydrogen is generated (e.g., as a reaction byproduct).

Abstract: A method of generating an electrical current and a multi-cell electrochemical device. The method includes extracting oxygen from an aqueous ambient environment surrounding an electrochemical system; transporting the extracted oxygen through a selectively oxygen-permeable membrane to an enclosed electrolyte configured to surround an anode and a cathode in the electrochemical system, wherein the electrolyte is separated from the aqueous ambient environment; transporting the oxygenated electrolyte to the cathode; reducing the oxygen at the cathode; and oxidizing a metal at the anode. The device includes a metal anode; a cathode; an enclosed electrolyte configured to surround the cathode and the anode, wherein the electrolyte is separated from an aqueous ambient environment surrounding the electrochemical device; and a selectively oxygen-permeable membrane configured to extract oxygen from the aqueous ambient environment.

Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.

Abstract: A method for collecting aluminate waste. The method includes transporting a super-saturated aqueous aluminate stream through a non-electrode open cell foam such that aluminum hydroxide that is the product of an electricity-generating electrochemical reaction between aluminum and water is precipitated on the non-electrode open cell foam, wherein at least 50% wt of the precipitation occurs within the non-electrode open cell foam instead of on an electrode.

Abstract: Waste management in electrochemical systems, such as electrochemical systems in which an electrochemically active material comprising aluminum is employed, is generally described.