Abstract: Xenon based biosensors have the potential to detect and localize biomarkers associated with a wide variety of diseases. The development and nuclear magnetic resonance (NMR) characterization of cage molecules which encapsulate hyperpolarized xenon is imperative for the development of these xenon biosensors. We acquired 129Xe NMR spectra, and magnetic resonance images and a HyperCEST saturation map of cucurbituril (CB6) in whole bovine blood. We observed a mean HyperCEST depletion of 84% (n=5) at a concentration of 5 mM and 74% at 2.5 mM. Additionally, we collected these data using a pulsed HyperCEST saturation pre-pulse train with a SAR of 0.025 W/kg which will minimize any potential RF heating in animal or human tissue.

Abstract: A water-based process was developed for the synthesis of aminated lignin copolymers with high MW, thermal stability and solubility in water over a wide range of p H values. The cationic lignin copolymer described herein comprises: a grafting ratio of (weight of cationic amine compound)/(weight of lignin) of 70 to 200% and a charge density of +1.4-3.0 meq/g. This cationic lignin copolymer can be used as a flocculant in numerous wastewater streams including municipal and industrial systems and sludge dewatering in the pulp & paper, mining and oil industries.

Abstract: A one-pot approach for the scalable production of novel interconnected reduced graphene oxide (IC-RGO) is demonstrated). The method consists of two steps: oxidation of graphite into graphene oxide (GO); and concomitant reduction and interconnection of GO. IC-RGO is formed without additional chemical and reduction agents. Instead, interconnection of graphene oxide is enabled thorough inherently presenting oxygen functional groups produced during the first step of synthesis.

Abstract: The spent liquor (SL) of a thermomechanical pulping (TMP) process introduces a high load to the wastewater system of this process. To reduce this load, fly ash from a biomass boiler is used and the application of fly ash improves the performance of biological process. Three different alternatives are introduced to apply fly ash to treat spent liquor.

Abstract: Doping and functionalization could significantly assist in the improvement of the electrochemical properties of graphene derivatives. Herein, we report a one-pot synthesis of fluorinated graphene oxide (FGO) from graphite. The surface morphology, functionalities and composition of the resulting FGO have been studied using various surface characterization techniques, revealing that layer-structured nanosheets with ˜1.0 at. % F were formed. The carbon bound F exhibited semi-ionic bonding characteristic and significantly increased the capacitance of FGO compared to graphene oxide (GO). Further, the FGO has been employed for the simultaneous detection of heavy metal ions Cd2+, Pb2+, Cu2+ and Hg2+ using square wave anodic stripping voltammetry; and a substantial improvement in the electrochemical sensing performance is achieved in comparison with GO.

Abstract: An acidic water-based process was developed for the synthesis of anionic lignin copolymers with adjustable MW, thermal stability and solubility in water. The anionic lignin copolymer described herein comprises: a molecular weight of 5,000 to 7.4×105 g/mol; and a charge density of ?1 to ?7.2 meq/g. The anionic lignin copolymers described herein which have a molecular weight range of 000-50,000 g/mol can be used as dispersants of negatively charged molecules or particles in numerous process or wastewater streams (e.g. concrete admixtures, gypsum slurries, textile dye) while such copolymers in a molecular weight range of 90,000-740,000 g/mole can be used as flocculants of positively charged molecules or particles in numerous process and wastewater streams including industrial and municipal systems and sludge dewatering in the textile dye, pulp & paper, mining and oil industries.

Abstract: We have developed an environmentally-friendly new process for producing textile yarns. The process involves chemical modification of cellulose with subsequent dissolution of the chemically modified cellulose with chitosan or other amine group-containing compounds which yields a highly viscous gel. The chemical modification of cellulose employs a known process of periodate oxidation which we have modified to obtain fibers with a low degree of aldehyde groups (˜2 mmol/g cellulose) that still remain insoluble in water. After washing, the chemically modified fibers can be cross-linked with chitosan or other amine group-containing compounds to produce the viscous gel. The viscous gel can then be extruded through a syringe nozzle in the form of textile yarns.

Abstract: Unique gas cell constructions based on a hollow-core photonic crystal fiber are used, for example, inside a fiber ring laser cavity as an intracavity gas cell. In one embodiment, two simple terminal blocks are coupled to opposite ends of the hollow-core photonic crystal fiber. Each block features a main through-bore with an optical window at one end and an optical fiber chuck fitted at the other end, while a transverse bore intersects the main bore and features a gas fitting for connection to a gas source or vacuum pump. In another embodiment, the hollow-core photonic crystal fiber is contained within an enclosure whose exterior walls are fitted with optical windows and gas ports. Inside the enclosure, fiber clamps supports the ends of the hollow-core photonic crystal fiber at positions adjacent to an in alignment with the optical windows.

Abstract: The main objective of the invention was to develop a new flotation collector that could eliminate or reduce the amount of copper sulfate used in the flotation of sphalerite. Different series of collectors such as cupferrons, arylhydroxamic acids and amino mercaptans or amino thiols were synthesized and tested. Amino mercaptans/aminothiols were found to be very effective in floating sphalerite from a lead-zinc ore using only 10-15% of copper sulfate used with conventional xanthate collector. The present invention does not require any alteration in the current mill practices. This warrants only changing the flotation collector in zinc flotation stage from, for example, potassium amyl xanthate (PAX) to the new collector.

Abstract: A gas detection system uses intracavity fiber laser absorption spectroscopy. The fiber laser is stabilized by a saturable absorber, and the sensitivity is enhanced by multiple circulations of amplified spontaneous emission light under threshold conditions, and multi-longitudinal mode oscillation of the laser.

Abstract: The spent liquor (SL) of a thermomechanical pulping (TMP) process introduces a high load to the wastewater system of this process. To reduce this load, fly ash from a biomass boiler is used for removing lignin from the SL, and also for decreasing the chemical oxidation demand (COD) and turbidity of the SL.

Abstract: The present invention utilizes the marriage of photocatalytic degradation and electrochemical oxidation to provide wastewater remediation and water purification based on the use of bifunctional electrodes. The bifunctional electrode provides for combined photocatalytic and electrochemical wastewater remediation for removing any one or combination of organic chemical pollutants, inorganic chemical pollutants and microorganisms. The electrode includes an electronically conducting substrate having a photocatalyst applied to a portion of the surface, the photocatalyst having a bandgap energy (Eg), and an electrocatalyst applied to another portion of the surface. Under illumination the photocatalyst produces electron-hole pairs which are separated by an anodic bias potential applied across the photocatalyst. The same bias is applied across the electrocatalyst.

Abstract: A scooter has a platform on which a rider can stand, a front wheel attached to a steering system including an upstanding handle bar and rear wheel which is driven. The scooter can be folded at a hinge line across the platform so to allow it to collapse. A case for the scooter includes a front part and a rear part covering the front and rear wheels with the parts brought together by the collapsing of the platform. This folding action also uses a pivot link to move the front and rear wheels pivoted within the respective case parts to a folded position. The steering includes a headstock with the steering bar connected to the front fork by a drive coupling which converts the rotation of the steering bar about the generally vertical axis to the rotation of the fork about an inclined axis.