Abstract: The formation of hydrocarbon hydrates can be inhibited or mitigated by contacting a a mixture comprising water and hydrate-forming guest molecules under gas hydrate forming conditions with a quaternary ammonium hydroxide QOH or a quaternary ammonium compound QA, in which A is not a halogen atom. The QOH or QA may be prepared reacting a quaternary ammonium halide QX with a metal hydroxide M(OH)x, or with a metal salt MA, in an alcohol solvent to form a quaternary ammonium hydroxide QOH, or a quaternary ammonium compound of formula QA, and metal halide MX. Optionally, the quaternary ammonium hydroxide QOH may be reacted with an organic or inorganic acid AH which is different from a hydrogen halide to form the quaternary ammonium compound QA. The metal halide MX may be removed by phase separation after addition of water or of a water/solvent mixture, or by filtration.
Type:
Application
Filed:
April 27, 2015
Publication date:
October 29, 2015
Applicant:
LAMBERTI SpA
Inventors:
Andrea BALESTRINI, Lorenzo GIARDINI, Mauro PARINI, Giuseppe LI BASSI, Giovanni FLORIDI
Abstract: Ethoxylated phospholipid-enriched soybean oil as an effective adjuvant in herbicidal compositions and method for killing or controlling the growth of weeds which comprises applying on the fields a herbicidal composition containing glyphosate and the ethoxylated phospholipid-enriched soybean oil.
Type:
Grant
Filed:
February 13, 2014
Date of Patent:
September 15, 2015
Assignee:
LAMBERTI SPA
Inventors:
Rocco Di Modugno, Dario Fornara, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Ethoxylated phospholipid-enriched soybean oil as an effective adjuvant in herbicidal compositions and method for killing or controlling the growth of weeds which comprises applying on the fields a herbicidal composition containing glyphosate and the ethoxylated phospholipid-enriched soybean oil.
Type:
Application
Filed:
February 13, 2014
Publication date:
August 13, 2015
Applicant:
LAMBERTI SPA
Inventors:
Rocco DI MODUGNO, Dario FORNARA, Giovanni FLORIDI, Giuseppe LI BASSI
Abstract: The present invention concerns aqueous polymer compositions comprising a water soluble hydrophilic polymer with poly(ethylene oxide) content higher than 50% by weight and a polyacrylic thickener containing sulfonic groups. The aqueous polymer compositions of the invention are useful as deflocculants, rheology modifiers and water retention agents for paper coating compositions.
Type:
Grant
Filed:
November 7, 2012
Date of Patent:
June 9, 2015
Assignee:
LAMBERTI SPA
Inventors:
Franco Federici, Vittorio Betti, Thierry Bossi, Christian Parisi, Riccardo Vago, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Ceramic inkjet inks comprising ceramic inorganic pigments having average particle size between 0.1 and 0.8 ?m, an organic medium and a dispersant, the dispersant being the reaction product of a polyethyleneimine with a homo- or co-polyester based on lactic acid, and method for decorating green or fired ceramic bodies by the use of the above ceramic inkjet inks.
Type:
Grant
Filed:
February 9, 2012
Date of Patent:
May 26, 2015
Assignee:
LAMBERTI SPA
Inventors:
Dario Fornara, Alan Nappa, Tamara Verzotti, Paolo Prampolini, Stefano Crespi, Giovanni Floridi, Giuseppe Li Bassi
Abstract: The hydration of clays in drilling operations can be inhibited by employing an aqueous based drilling fluid containing from about 0.2 to about 5 wt % of a hydration inhibitor that comprises bis-hexamethylene-triamine, bis-hexamethylene-triamine salts, or mixtures thereof.
Type:
Grant
Filed:
June 18, 2013
Date of Patent:
May 19, 2015
Assignee:
LAMBERTI SPA
Inventors:
Luigi Merli, Franscesca Giani, Pierangelo Pirovano, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Method for decorating green or fired ceramic bodies by inkjet printing comprising the use of a ceramic inkjet ink which is prepared by milling a ceramic inorganic pigment in an organic medium in the presence of a dispersant which is the reaction product of a polyethyleneimine and a ricinoleic acid polyester, until the average particle size of the pigment is between 0.1 and 0.8 ?m.
Type:
Grant
Filed:
December 5, 2011
Date of Patent:
May 19, 2015
Assignee:
LAMBERTI SPA
Inventors:
Dario Fornara, Alan Nappa, Tamara Verzotti, Paolo Prampolini, Stefano Crespi, Giovanni Floridi, Giuseppe Li Bassi
Abstract: A method for reducing filtrate loss of oil based drilling fluids comprising the following steps: a) preparing by emulsion polymerization an aqueous dispersion containing: i) from 20% to 60% by weight of a copolymer comprising from 60% to 90% by weight of styrene and/or vinyltoluene monomers, from 7 to 40% by weight of 2-ethylhexyl acrylate monomers and from 0.01 to 3% of polyfunctional unsaturated monomers; ii) from 40 to 80% by weight of water; iii) from 0.1% to 5% by weight of at least one surfactant; b) providing an oil based drilling fluid containing the aqueous dispersion obtained from step a), or its copolymer in powder form; c) injecting and circulating the drilling fluid in the borehole.
Type:
Grant
Filed:
January 20, 2010
Date of Patent:
February 24, 2015
Assignee:
Lamberti SpA
Inventors:
Franco Federici, Thierry Bossi, Christian Parisi, Luigi Merli, Daniele Moro, Pierangelo Pirovano, Giuseppe Li Bassi
Abstract: Esters of alkanolamines with unsaturated, polyunsaturated or saturated C8-C36 monocarboxylic acids are additives for reducing accretion on drilling equipment (anti-accretion agents) to be used in drilling muds during drilling and completion of oil and gas wells.
Type:
Grant
Filed:
May 18, 2009
Date of Patent:
January 13, 2015
Assignee:
Lamberti SpA
Inventors:
Luigi Merli, Jacopo Franchini, Pierangelo Pirovano, Mattia Ossola, Franco Federici, Dario Fornara, Giuseppe Li Bassi
Abstract: 3-Esters and 3-amides of thioxanthone bearing alkyl chains of appropriate length and can be used as photoinitiators or sensitizers in photopolymerizable systems, in particular for the preparation of coatings compatible with the food use.
Type:
Grant
Filed:
November 7, 2011
Date of Patent:
January 13, 2015
Assignee:
Lamberti Spa
Inventors:
Angelo Casiraghi, Enzo Meneguzzo, Gabriele Norcini, Elena Bellotti, Giovanni Floridi, Giuseppe Li Bassi
Abstract: The disclosure relates to printing mediums, useful for ceramic sinterable materials, that are in powder form and are based on glycols, urea and an inorganic absorbent, to ceramic inks compositions comprising the printing mediums and to methods for decorating green or fired ceramic bodies by the use of said printing mediums and compositions.
Type:
Grant
Filed:
February 22, 2011
Date of Patent:
December 9, 2014
Assignee:
Lamberti SpA
Inventors:
Paolo Prampolini, Alan Nappa, Giuseppe Li Bassi, Giovanni Floridi
Abstract: Paper coating compositions contain specific polyethers which are obtained by reacting a diglycidyl ether with a water soluble polyol containing at least one polyoxyethylene chain acting as deflocculants, water retention agents and gloss enhancers.
Type:
Grant
Filed:
August 30, 2011
Date of Patent:
November 4, 2014
Assignee:
Lamberti SpA
Inventors:
Franco Federici, Thierry Bossi, Stefano Fumagalli, Riccardo Vago, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Compositions comprising a hydraulic binder such as cement or gypsum and a hydroxypropyl guar derivative that comprises unsubstituted linear or branched C6-C8 alkyl chains possess excellent water retention characteristics.
Type:
Grant
Filed:
December 15, 2011
Date of Patent:
July 1, 2014
Assignee:
Lamberti SpA
Inventors:
Barbara Biasotti, Max Giudici, Ugo Pfeiffer, Valentina Langella, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Personal care compositions comprising, as thickeners and suspending agents, crosslinked alkali swellable polyacrylates containing one or more acetoacetyl or cyanoacetyl groups.
Type:
Application
Filed:
March 16, 2012
Publication date:
January 16, 2014
Applicant:
Lamberti SPA
Inventors:
Chiara Fumagalli, Eva Baldaro, Giovanni Floridi, Giuseppe Li Bassi
Abstract: The present invention relates to a rheology modifier for ceramic glazes comprising a water-swellable granulated clay, a carboxymethyl cellulose and possibly another natural gum. In another aspect the invention relates to the ceramic glaze and the glaze slip obtained using the above rheology modifier, which can be used for glazing green or fired ceramic bodies such as artware, tableware, tile, heavy clays products and sanitaryware.
Type:
Grant
Filed:
March 3, 2011
Date of Patent:
January 14, 2014
Assignee:
Lamberti SpA
Inventors:
Stefano Crespi, Marco Antoniotti, Giuseppe Li Bassi, Giovanni Floridi
Abstract: Process for the preparation of the powdery crystalline mixtures of alpha-hydroxycarbonyl derivatives of alpha-methylstyrene dinners comprising the use of a solvent having polarity from 0 to 0.1.
Type:
Grant
Filed:
March 10, 2010
Date of Patent:
December 31, 2013
Assignee:
Lamberti SpA
Inventors:
Giuseppe Li Bassi, Gabriele Norcini, Leonardo Federici
Abstract: Ceramic inks comprising ceramic pigments dispersed in vehicles based on water and glycols and containing urea, and method for decorating green or fired ceramic bodies by the use of said inks.
Type:
Grant
Filed:
June 8, 2009
Date of Patent:
November 26, 2013
Assignee:
Lamberti SpA
Inventors:
Stefano Crespi, Alan Nappa, Paolo Prampolini, Giuseppe Li Bassi
Abstract: A glyoxal and boron free purified cationic polygalactomannan may be prepared by reacting a polygalactomannan flour, a nonionically derivatized polygalactomannan flour, or a mixture thereof, with a cationising reagent, adjusting the pH to be from about 4 to about 6; cross-linking the cationic with glyoxal, and filtering and water washing the cationic polygalactomannan to produce a glyoxalated purified cationic polygalactomannan containing not more than 70% by weight of water. In some cases it may be desirable to introduce a buffering agent to the glyoxalated purified cationic polygalactomannan to regulate the pH to from 8.0 to about 9.5, when measured at 1% (dry matter) in water. In other cases, it may be desirable to remove water to produce glyoxal free purified cationic polygalactomannan in powder form. Such compounds are particularly useful in personal care products.
Type:
Grant
Filed:
January 7, 2011
Date of Patent:
November 12, 2013
Assignee:
Lamberti SpA
Inventors:
Ugo Pfeiffer, Mauro Tenconi, Eva Baldaro, Valentina Langella, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Compositions comprising a hydraulic binder such as cement or gypsum and a hydroxypropyl guar derivative that comprises unsubstituted linear or branched C6-C8 alkyl chains possess excellent water retention characteristics.
Type:
Application
Filed:
December 15, 2011
Publication date:
October 31, 2013
Applicant:
Lamberti SpA
Inventors:
Barbara Biasotti, Max Giudici, Ugo Pfeiffer, Valentina Langella, Giovanni Floridi, Giuseppe Li Bassi
Abstract: Cationic hydrophobically modified galactomannan ethers having a cationic degree of substitution (DSC) from 0.01 to 0.5 and hydrophobic degree of substitution (DSH) below 0.001 are readily soluble in aqueous systems and useful to thicken, stabilize and condition cosmetics, detergent compositions and household cleaning products; they further improve the deposition of other ingredients on the treated surface (skin, hair or fabric).
Type:
Grant
Filed:
July 14, 2009
Date of Patent:
October 1, 2013
Assignee:
Lamberti SpA
Inventors:
Valentina Langella, Eva Baldaro, Giuseppe Li Bassi