Abstract: The IT and FT values for coal and coke samples can be accurately predicted by applying equations to determined ST and HT temperatures. For reducing atmospheres, the equations are IT=C1×ST?C2×HT+C3 and FT=C4×HT?C5×ST+C6. For oxidizing atmospheres, the equations are IT=C7×ST?C8×HT+C9 and FT=C10×HT?C11×ST+C12. IT is the initial deformation temperature. ST is the softening temperature. HT is the hemispherical temperature. FT is the fluid temperature. C1-C12 are constants determined by multi-linear regression coefficient analytical techniques on a collection of data.

Abstract: An analytical combustion furnace has an input port for receiving a holder for an analytical sample. A purge block is coupled to the input port of the combustion furnace and has an input end for receiving the holder and a gas inlet and a gas outlet. A door selectively closes the input end of the purge block, and a pressurized seal is coupled between the purge block and the door. A source of purging gas is coupled to the gas inlet of the purge block for pressurizing the seal. The gas outlet of the purge block communicates with the seal to allow purging gas to escape the area of the seal. In one embodiment, a pressurized seal surrounds a push rod, which seal is pressurized by a purging gas to continuously purge the entry of the push rod into the purge block, thereby eliminating atmospheric contamination.

Abstract: An automatic cleaning assembly for an analytical furnace is detachable from the filter chamber above the combustion tube. The cleaning assembly includes a rotating brush which is lowered through the filter chamber and into the combustion tube while a vacuum is drawn through the lower seal of the combustion tube. This results in a higher vacuum pressure differential and improved flow rate for removing dust from the filter of the furnace and the combustion tube.

Abstract: A data acquisition system and method are described that may be used with various spectrometers. The data acquisition system may include an ion detector, an initial processing module, and a spectra processing module. The initial processing module is provided for processing the ion detection signals and for supplying processed signals to the spectra processing module. The spectra processing module generates spectra from the processed signals and supplies the generated spectra to an external processor for post-processing. The spectra processing module may include one or more of: a cross-spectra filter for filtering data in each spectra as a function of data in at least one prior spectra; a shaping filter for removing skew and shoulders from the processed signals; a sharpening filter for sharpening the peaks of the processed signals to effectively deconvolve and separate overlapping peaks; an ion statistics filter; and a peak histogram filtering circuit.

Abstract: A data acquisition system and method are described that may be used with various spectrometers. The data acquisition system may include an ion detector and a processing circuit. The processing circuit may include an initial processing module and a spectra processing module. According to one embodiment, the spectra processing module generates stick spectra and supplies the stick spectra to an external processor. The stick spectra comprise a peak intensity, resolution, and a location in the spectra for each detected peak. The stick spectra may be generated in real time.

Abstract: Ion manipulation systems include ion repulsion by an RF field penetrating through a mesh. Another comprises trapping ions in a symmetric RF field around a mesh. The system uses macroscopic parts, or readily available fine meshes, or miniaturized devices made by MEMS, or flexible PCB methods. One application is ion transfer from gaseous ion sources with focusing at intermediate and elevated gas pressures. Another application is the formation of pulsed ion packets for TOF MS within trap array. Such trapping is preferably accompanied by pulsed switching of RF field and by gas pulses, preferably formed by pulsed vapor desorption. Ion guidance, ion flow manipulation, trapping, preparation of pulsed ion packets, confining ions during fragmentation or exposure to ion to particle reactions and for mass separation are disclosed. Ion chromatography employs an ion passage within a gas flow and through a set of multiple traps with a mass dependent well depth.

Abstract: A crucible handling shuttle includes a pair of opposed dual crucible-gripping arms mounted on a rotatable head. The shuttle is removably plugged into a sliding block of a carriage to move between a furnace and a crucible loading station. The carriage includes mechanical, electrical, and pneumatic plugs or sockets which couple to mating sockets or plugs of the shuttle. A linear actuator extends between the carriage and the furnace base to raise and lower the carriage and shuttle coupled thereto.

Abstract: A combustion tube mounting system releasably mounts a combustion tube to an aperture in the floor of a furnace housing. The combustion tube has a base assembly with a cam and can be manually or automatically unlocked by cam pins in the floor for selectively engaging the cam for lowering the combustion tube from the floor of the furnace. When a new combustion tube is placed on the lower seal assembly and raised, it automatically aligns and engages the upper furnace seal and engages cams on the floor of the furnace housing which lock the combustion tube in place as it is introduced into the furnace.

Abstract: The IT and FT values for coal and coke samples can be accurately predicted by applying equations to determined ST and HT temperatures. For reducing atmospheres, the equations are IT=C1×ST?C2×HT+C3 and FT=C4×HT?C5×ST+C6. For oxidizing atmospheres, the equations are IT=C7×ST?C8×HT+C9 and FT=C10×HT?C11×ST+C12. IT is the initial deformation temperature. ST is the softening temperature. HT is the hemispherical temperature. FT is the fluid temperature. C1-C12 are constants determined by multi-linear regression coefficient analytical techniques on a collection of data.

Abstract: Circuits for correcting base line shift of the detector coupling circuit of a TOFMS provide gain and impedance characteristics that compensate for the AC coupling effect of the detector. In one circuit, base line correction is achieved by injecting a current equal to that which flows due to the buildup charge in the detectors AC coupling network. In another circuit, the current source drives an integrator which is coupled to the signal path to reduce the detector AC coupling effects. In another circuit, a low noise amplifier utilizes a feedback network that reduces the detector AC coupling effects. In yet another circuit, an operational amplifier is employed to reduce the detector AC coupling effects.

Abstract: The IT and FT values for coal and coke samples can be accurately predicted by applying equations to determine ST and HT temperatures. For reducing atmospheres, the equations are IT=C1×ST?C2×HT+C3 and FT=C4×HT?C5×ST+C6. For oxidizing atmospheres, the equations are IT=C7×ST?C8×HT+C9 and FT=C10×HT?C11×ST+C12. IT is the initial deformation temperature. ST is the softening temperature. HT is the hemispherical temperature. FT is the fluid temperature. C1-C12 are constants determined by multi-linear regression coefficient analytical techniques on a collection of data.

Abstract: A data acquisition system and method are described that may be used with various spectrometers. The data acquisition system may include an ion detector, an initial/transient processing module, and a spectra processing module. The initial/transient processing module is provided for processing the ion detection signals and for supplying processed signals to the spectra processing module. The transient processing module may contiguously sample the ion detection signals at a rate of at least 1.5 GHz. The spectra processing module may generate spectra from the transients at a rate of at least 50 spectra per second. The initial processing module may be configured to have a sensitivity that is sufficient to detect a single ion received within one of over at least 100 transients and to detect and quantify a number of ions simultaneously striking said ion detector up to at least 10 simultaneously striking ions.

Abstract: A circuit synchronizes the actuation of multi-dimensional separating valves with a system clock also coupled to a data acquisition circuit such that signals from a detector are synchronized and no signal information is lost. The system comprises an acquisition clock coupled to a data acquisition logic system and to a modulator valve control. The modulator valve control is, in turn, coupled to a multi-dimensional separation technique valve unit for controlling the valves for introduction of the eluant from a first separation column to a second, faster column in synchronism with acquisition of data by a detector.

Abstract: A data acquisition system and method are described that may be used with various spectrometers. The data acquisition system may include an ion detector, an initial processing module, and a spectra processing module. The initial processing module is provided for receiving, sampling, and processing ion detection signals received from the ion detector, and for supplying processed signals to the spectra processing module. The initial processing module includes a horizontal accumulation circuit that combines a fractional number of adjacent samples of the ion detection signals into bins. The number of adjacent samples to combine into bins may vary as a function of: (1) the time of arrival at the ion detector corresponding to that sample; (2) the mass corresponding to that sample; (3) the resolution corresponding to that sample; and/or (4) an operational mode of the spectrometer. The spectra processing module receives the processed signals and generates spectra.

Abstract: The disclosed apparatus includes a multi-reflecting time-of-flight mass spectrometer (MR-TOF MS) and an orthogonal accelerator. To improve the duty cycle of the ion injection at a low repetition rate dictated by a long flight in the MR-TOF MS, multiple measures may be taken. The incoming ion beam and the accelerator may be oriented substantially transverse to the ion path in the MR-TOF, while the initial velocity of the ion beam is compensated by tilting the accelerator and steering the beam for the same angle. To further improve the duty cycle of any multi-reflecting or multi-turn mass spectrometer, the beam may be time-compressed by modulating the axial ion velocity with an ion guide. The residence time of the ions in the accelerator may be improved by trapping the beam within an electrostatic trap. Apparatuses with a prolonged residence time in the accelerator provide improvements in both sensitivity and resolution.

Abstract: An imbalanced radio frequency (RF) field creates a retarding barrier near the exit aperture of a multipole ion guide, in combination with the extracting DC field such that the barrier provides an m/z dependent cut of ion sampling. Contrary to the prior art, the mass dependent sampling provides a well-conditioned ion beam suitable for other mass spectrometric devices. The mass selective sampling is suggested for improving duty cycle of o-TOF MS, for injecting ions into a multi-reflecting TOF MS in a zoom mode, for parallel MS-MS analysis in a trap-TOF MS, as well as for moderate mass filtering in fragmentation cells and ion reactors. With the aid of resonant excitation, the mass selective ion sampling is suggested for mass analysis.

Abstract: A data acquisition system and method are described that may be used with various spectrometers. The data acquisition system may include an ion detector, an initial/transient processing module, and a spectra processing module. The initial/transient processing module is provided for processing the ion detection signals and for supplying processed signals to the spectra processing module. The transient processing module may contiguously sample the ion detection signals at a rate of at least 1.5 GHz. The spectra processing module may generate spectra from the transients at a rate of at least 50 spectra per second. The initial processing module may be configured to have a sensitivity that is sufficient to detect a single ion received within one of over at least 100 transients and to detect and quantify a number of ions simultaneously striking said ion detector up to at least 10 simultaneously striking ions.

Abstract: A data acquisition system and method are described that may be used with various spectrometers. The data acquisition system may include an ion detector and a processing circuit. The processing circuit may include an initial processing module and a spectra processing module. According to one embodiment, the spectra processing module generates stick spectra and supplies the stick spectra to an external processor. The stick spectra comprise a peak intensity, resolution, and a location in the spectra for each detected peak. The initial processing module may contiguously sample the ion detection signals at a rate matched to the capabilities of the ion detector (up to at least 1.5 GHz) over a full spectral range. The spectra processing module may receive the processed signals and generate spectra from the processed signals at a rate matched to the time response of the separation techniques (up to 200 spectra/second).

Abstract: A reagent assembly for a combustion tube includes a reagent tube which is sealably and removably coupled to the open end of the combustion tube such that, when the reagent in the reagent tube is depleted, it can be easily removed without disassembly of the furnace or changing the combustion tube. The reagent tube includes a twist-lock cap to facilitate removal of the reagent tube.

Abstract: An automated apparatus for determining the calorific value of combustible substances employs an integrated, isothermal water reservoir to reduce the complexity of the apparatus and facilitates automation of the calorimeter by providing a convenient source of isothermal water. A moving divider is used to reconfigure the isothermal water reservoir to either provide for temperature equilibration prior to sample analysis or define a fixed volume of water during analysis in which high precision temperature measurements can be recorded. The apparatus includes mechanisms for controlling the moving divider, a sample holding combustion vessel, and loading, cleaning, and unloading the combustion vessel. This eliminates key analysis steps that had previously required manual intervention by an operator.