Abstract: The present invention provides for a permeable reactive barrier and an effective method of removing contaminants from water using adsorbent powders, such as zero valent iron particles, adhered throughout a reticulated foam structure. This structure provides improved mass transfer, higher reaction rates and reduced residence times. The barrier includes a reticulated foam substrate with high permeability, an adherent coating and a reactive adsorbent arranged in a reticulated foam structure. The substrate can be selected from various materials including polyurethane and polyester. The adherent may be selected from a wide range of materials including polyurethanes, acrylics, silicones, siliconized acrylics, latex emulsions, and other inherently tacky materials that cure to a water resistant coating. The reactive adsorbent can be selected from various adsorbents including a powdered zero-valent iron (ZVI).

Abstract: A process for a purification of water with multiple contaminants including dissolved solids. The process may involve one or more steps of separating oil and water, metals precipitation, dissolved air flotation (DAF), filtration, forward or reverse osmosis and crystallization. An improved DAF unit is described which increases air dissolution to oxidize impurities and improve flotation. Various embodiments of staged osmotic membrane systems are provided to generate an essentially pure water stream and a highly concentrated solute stream. In some embodiments, reverse osmosis and nanofiltration units are employed in a staged manner. In other embodiments, all stages are reverse osmosis units and the osmotic pressure of each stage is adjusted by the provision of a solution on the low pressure side of the reverse osmosis membrane using nanofiltration membranes. Various recycle options are employed to improve the efficiency of the systems.