Patents Assigned to Linde GMBH
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Patent number: 12728382Abstract: A process for removal of unwanted components from a feed gas mixture, wherein a temperature swing adsorption unit comprising at least two adsorption vessels is used, the method comprising cyclically operating the temperature swing adsorption unit in successive operation modes in each of which a different one of the at least two adsorption vessels is operated in an adsorption mode while a further one of the at least two adsorption vessels previously operated in the adsorption mode is operated in a regeneration mode, the adsorption mode comprising forming an adsorption gas stream using a part of the feed gas mixture and passing the adsorption gas stream through the adsorption vessel operated in the adsorption mode, and the regeneration mode comprising passing a regeneration gas stream through the adsorption vessel operated in the regeneration mode, thereby forming the purified gas mixture.Type: GrantFiled: April 8, 2021Date of Patent: September 8, 2026Assignee: Linde GmbHInventors: Matthias Grahl, Christan Horn, Gabriel Salazar Duarte, Verena Kramer
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Patent number: 12716549Abstract: A method for conveying a cryogen from a storage vessel to a load, comprising the following steps: a) introducing the cryogen from the storage vessel into a conditioning tank, the cryogen flowing from the storage vessel into the conditioning tank only because of the hydrostatic pressure of the cryogen, b) bringing the cryogen accommodated in the conditioning tank into its supercritical state, and c) discharging the cryogen from the conditioning tank to the load, wherein the cryogen accommodated in the conditioning tank is kept in the supercritical state during step c).Type: GrantFiled: November 11, 2021Date of Patent: August 25, 2026Assignee: LINDE GMBHInventors: Heinz Posselt, Anton Wellenhofer, Eva Müller, Stefan Felbinger, Christian Zach, Harald Zenz, Kathrin Wellenhofer, Hakemi Nabeel, Julia Kleiner, Petya Toneva, Kay Dost
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Patent number: 12714965Abstract: Separating a starting gas mixture using pressure swing adsorption. In this, at least part of a low-pressure extraction flow from the pressure swing adsorption is subjected to a thermal separation, wherein a return fraction is formed in the thermal separation which is returned to the pressure swing adsorption separation. In the thermal separation, counterflow cooling takes place to obtain a two-phase mixture, wherein at least part of the two-phase mixture is subjected to phase separation to obtain a gas phase and a condensate. At least a part of the gas phase is used to form the return fraction, and counterflow cooling is carried out using at least a part of the gas phase and at least a part of one or more fluid flows which are formed by expansion of at least a part of the liquid phase.Type: GrantFiled: September 5, 2022Date of Patent: August 25, 2026Assignee: Linde GmbHInventors: Helmut Fritz, Werner Leitmayr, Martin Lang
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Patent number: 12710173Abstract: A method for heating a furnace is provided in which in the furnace has at least one heating zone which is heated by combusting a fuel with an oxidant. The furnace further has a dark zone, downstream of the heated zone, to which) no fuel is supplied directly. The fuel and oxidant are supplied to the heating zone is substoichiometric manner, in that between 10% and 40% of the total oxidant for achieving stoichiometric or near stoichiometric combustion is supplied directly to the dark zone. The flue gas temperature is measured in and/or downstream of the dark zone, and the share of the total oxidant supplied to the dark zone is controlled so as not to exceed a predetermined maximum measured temperature. A method for retrofitting an existing furnace is also provided.Type: GrantFiled: December 17, 2020Date of Patent: August 18, 2026Assignee: LINDE GMBHInventors: Tomas Ekman, Ola Ritzén, David Muren
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Patent number: 12710225Abstract: A method for producing liquefied natural gas (LNG), wherein a feed natural gas (NG) containing methane and higher hydrocarbons, including benzene, is cooled to a first temperature level in a first cooling step using a first mixed refrigerant (WMR) and is subsequently subjected to counter-current absorption using an absorption liquid, wherein a gas fraction depleted in the higher hydrocarbons is formed, at least a portion of the gas fraction is cooled to a second temperature level in a second cooling step using a second mixed refrigerant (CMR) and is liquefied to form the liquefied natural gas (LNG), characterized in that the absorption liquid is formed from another portion of the gas fraction, which portion preferably condenses above the counter-current absorption and is returned to the counter-current absorption, in particular without a pump.Type: GrantFiled: June 23, 2021Date of Patent: August 18, 2026Assignee: Linde GmbHInventors: Heinz Bauer, Andreas Kossmann, Rebecca Henkelmann
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Patent number: 12710228Abstract: A SPECTRA process for low-temperature fractionation of air is proposed, in which bottoms liquid from an additional second rectification column used to obtain oxygen is evaporated in a second condenser evaporator arrangement. In this second condenser evaporator arrangement, gas that has been evaporated beforehand in a first condenser evaporator arrangement, which is used for condensation of tops gas from a first rectification column, is partially condensed after recompression. The invention also relates to a corresponding plant.Type: GrantFiled: March 10, 2022Date of Patent: August 18, 2026Assignee: Linde GmbHInventors: Dimitri Golubev, Xiaohua Fan
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Patent number: 12702964Abstract: A reactor for carrying out a chemical reaction includes a reactor wall and at least one group of M reaction tubes, each of which has an electrically heatable heating section that extends between a first and a second removal region. Each heating section has a respective feed region in a region which extends over 20% to 80% of a heating length of the heating section and electrically conductive feed elements. Each group M is paired with the feed elements connected to the feed regions of the group, and different phases of the alternating current can be fed to different feed elements paired with a group. Each group is paired with M first and M second removal elements connected to the first or second removal regions of the group, respectively. Each group is paired with a first and a second star bridge.Type: GrantFiled: September 9, 2021Date of Patent: August 11, 2026Assignees: Linde GmbH, BASF SEInventors: Martin Hofstatter, Clara Delhomme-Neudecker, Heinz Posselt, Mathieu Zellhuber
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Patent number: 12697584Abstract: A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. The separate layers of hopcalite catalyst preferably have different volumes and/or different average particle sizes of the hopcalite materials.Type: GrantFiled: May 22, 2023Date of Patent: August 4, 2026Assignees: Praxair Technology, Inc., Linde GmbHInventors: Ralph J. Mancini, Cem E. Celik, Arthur C. Selover, Sesha Hari Vemuri, Thomas A. McNamara, Matthias Grahl, Helko Schneider
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Patent number: 12696370Abstract: A consumables holder assembly for a plasma arc torch having a torch head, the consumables holder assembly comprising a main body, a shielding cup which engages to the main body, a connection means which engages the main body to the torch head, wherein the consumable components including an electrode, a nozzle, a plasma gas distributor, a shielding gas distributor which are all positioned inside the shielding cup, wherein the consumable holder assembly can be detached from the torch head together with the consumable components and the shielding cup as one unit, wherein the nozzle comprises two focus gas passageways which lead a focus gas out of the nozzle through at least two focus holes, wherein external visual features are provided on both connection means and the torch head which are aligned to each other showing the location of the focus holes.Type: GrantFiled: November 5, 2020Date of Patent: July 28, 2026Assignee: Linde GmbHInventors: Erwan Siewert, Nakhleh A. Hussary, Richard Andreas Wagner
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Patent number: 12685986Abstract: A reactor for carrying out a chemical reaction, which has a reactor vessel and one or more reaction tubes, wherein power input elements for electrical heating of the reaction tube(s) are guided into the reactor vessel. It is provided that the power input elements each have a rod-shaped section that, in each case, runs at a wall passage through a wall of the reactor vessel in such a way that a connection chamber into which the rod-shaped sections project is arranged outside the reactor vessel and adjacently to the wall of the reactor vessel through which the rod-shaped sections run at their wall passages, and that cooling panels through which a cooling fluid can flow are provided in the connection chamber and are arranged between at least two or between at least two groups of the rod-shaped sections that project into the connection chamber.Type: GrantFiled: March 11, 2021Date of Patent: July 21, 2026Assignees: Linde GmbH, BASF SEInventors: Heinz Posselt, Mathieu Zellhuber, Martin Hofstätter, Clara Delhomme-Neudecker, Andrey Shustov, Eric Jenne, Kiara Aenne Kochendörfer, Heinrich Laib, Reiner Jacob, Heinz-Jürgen Kühn
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Patent number: 12685990Abstract: An apparatus for carrying out a chemical reaction in a process fluid includes a reactor comprising one or more reaction tubes which have a number of electrically heatable tube segments which are connected to one another by an electrically conductive star bridge, and at least one power source configured to provide a multiphase alternating current with N phases to N phase lines at a predetermined voltage. N is an integer greater than or equal to 2. For each of the at least one power source, a number of power connections is provided, each of which is connected to at least one of the tube segments and to one of the phase lines of the power source. In the at least one power source, a star point is formed at which the phase lines of the power source are connected, wherein the star point is not connected to a ground connection.Type: GrantFiled: September 10, 2021Date of Patent: July 21, 2026Assignees: Linde GmbH, BASF SEInventors: Martin Hofstatter, Clara Delhomme-Neudecker, Heinz Posselt, Niklas Fleischmann, Kiara Aenne Kochendorfer, Eric Jenne, Andrey Shustov, Werner Josef Still, Torsten Stark
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Patent number: 12678746Abstract: An apparatus for dissolving gas into a liquid is provided having a housing with an inlet opening for the liquid and an outlet opening for the liquid, and a blade unit arranged inside the housing in a small cross section area between the inlet opening and the outlet opening. A flow cross section for the liquid at the small cross section area is smaller than at the inlet opening. The apparatus further includes a gas inlet provided at an outside of the housing and at least one gas outlet provided in the housing on a surface of the blade unit. The at least one gas outlet is connected to the gas inlet by a channel. Methods for producing and using such an apparatus are also provided.Type: GrantFiled: July 14, 2020Date of Patent: July 14, 2026Assignee: Linde GmbHInventor: Kenneth Glomset
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Patent number: 12674102Abstract: A method of steam cracking using a steam cracking arrangement including an electric cracking furnace without a convection zone and a quench cooling train is proposed, wherein a process gas stream is passed through the cracking furnace and the cooling train. The cooling train is operated to comprise at least two distinct cooling steps arranged in either order, wherein in a first cooling step at least a part of the process gas stream withdrawn from the electric cracking furnace is cooled against vaporizing boiler feed water at an absolute pressure level between 30 and 175 bar and wherein in a second cooling step at least a part of the process gas stream withdrawn from the electric cracking furnace is cooled against a superheated mixture of feed hydrocarbons and process steam used in forming the process gas stream which is thereby heated to a temperature level between 350 and 750° C.Type: GrantFiled: March 8, 2022Date of Patent: July 7, 2026Assignee: LINDE GMBHInventors: Mathieu Zellhuber, Michael Horenz, David Bruder, Martin Hofstatter
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Patent number: 12655815Abstract: A method of operating an internal combustion engine specified to be run with a fuel gas mixture comprising at least one hydrocarbon and hydrogen in a maximum specified hydrogen content using a pipeline gas withdrawn from a pipeline and comprising the at least one hydrocarbon and a hydrogen content exceeding the maximum specified hydrogen content is provided. The pipeline gas is at least in part subjected to a hydrogen depletion to yield a hydrogen depleted gas mixture not exceeding the maximum specified hydrogen content. Said hydrogen depleted gas mixture is at least in part used as the fuel gas and said hydrogen depletion includes a membrane separation. A corresponding arrangement is also part of the present invention.Type: GrantFiled: May 31, 2023Date of Patent: June 16, 2026Assignee: Linde GmbHInventors: Tobias Keller, Christian Voss, Martin Bauer, Patrick Schiffmann, Alexander Siemens, Oliver Purrucker
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Patent number: 12631399Abstract: A wound heat exchanger, comprising a shell, a bundle of tubes arranged inside the shell and through which a medium can flow, a first annular channel arranged inside the shell and runs around it for separating a liquid phase of a refrigerant from a gaseous phase of the refrigerant, a second annular channel arranged inside the shell and runs around it and is intended for evenly distributing the liquid phase over the bundle of tubes in order to exchange the heat between the refrigerant and the medium, and a connecting channel which establishes a fluid connection between the first annular channel and the second annular channel in order to conduct the liquid phase out of the first annular channel into the second annular channel, wherein the first annular channel and the second annular channel are spaced apart.Type: GrantFiled: May 2, 2022Date of Patent: May 19, 2026Assignee: Linde GmbHInventors: Jürgen Spreemann, Hubert Lachenwitzer, Luis Matamoros, Florian Deichsel
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Patent number: 12611626Abstract: A process is proposed for separating carbon dioxide from a feed stream containing carbon dioxide, in which at least part of the feed stream is subjected to temperature swing adsorption to obtain a first and a second successive stream, wherein, in each case relative to the feed stream, the first subsequent stream is depleted in carbon dioxide and the second subsequent stream is enriched in carbon dioxide, and at least part of the second subsequent stream is subjected to membrane separation to obtain a third and a fourth subsequent stream, the third subsequent stream being depleted in carbon dioxide and the fourth subsequent stream being enriched in carbon dioxide, in each case relative to the second subsequent stream. A corresponding arrangement is also an object of the invention.Type: GrantFiled: November 23, 2022Date of Patent: April 28, 2026Assignee: LINDE GMBHInventors: Werner Leitmayr, Thomas Ried, Gabriel Salazar Duarte, Patrick Schiffmann
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Patent number: 12600912Abstract: A method of steam cracking using a steam cracking arrangement including an electric cracking furnace without a convection zone and a quench cooling train is proposed, wherein a process gas stream is passed through the cracking furnace and the cooling train. The cooling train is operated to comprise at least two distinct cooling steps arranged in either order, wherein in a first cooling step at least a part of the process gas stream withdrawn from the electric cracking furnace is cooled against vaporizing boiler feed water at an absolute pressure level between 30 and 175 bar and wherein in a second cooling step at least a part of the process gas stream withdrawn from the electric cracking furnace is cooled against a superheated mixture of feed hydrocarbons and process steam used in forming the process gas stream which is thereby heated to a temperature level between 350 and 750° C.Type: GrantFiled: March 8, 2022Date of Patent: April 14, 2026Assignee: LINDE GMBHInventors: Mathieu Zellhuber, Michael Horenz, David Bruder, Martin Hofstatter
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Patent number: 12583052Abstract: Provided is a method of connecting an austenitic steel pipe with a ferritic steel pipe. The method comprises providing the austenitic steel pipe and the ferritic steel pipe, such that an inner end section of the austenitic steel pipe has an outer diameter smaller than an inner diameter of an outer section of the ferritic steel pipe, inserting the inner end section into the outer end section, such that the inner and outer end sections overlap in a connection region, and welding the inner and outer end sections in the connection region by explosive welding or magnetic pulse welding. Further, a linear quench exchanger and a processing arrangement for processing a process fluid are provided.Type: GrantFiled: December 1, 2021Date of Patent: March 24, 2026Assignee: LINDE GMBHInventors: Reinhold Hölzl, Matthias Grundwürmer, Thomas Englert, Josef-Andreas Pöllmann
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Patent number: 12569799Abstract: The present invention proposes a gas treatment process in which a process arrangement comprising three process units is used, the gas treatment process comprising subsequently operating a different one of the three process units in a heating mode during a heating phase, the heating mode comprising heating a first gas stream to a first temperature level using a first heat exchanger, introducing the first gas stream at the first temperature level to the process unit which is operated in the heating mode, withdrawing a second gas stream from the process unit which is operated in the heating mode, and thereafter cooling the second gas stream to a second temperature level using a second heat exchanger.Type: GrantFiled: April 11, 2022Date of Patent: March 10, 2026Assignee: Linde GmbHInventors: Florian Deichsel, Thomas Ried, Gabriel Salazar Duarte, Martin Pottmann, Verena Kramer, Emilie Duval, Georg Förster
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Patent number: 12571586Abstract: A method for operating a process plant using a dynamic model of the process plant, the dynamic model being based on at least one of thermo fluidic correlations, thermo dynamic correlations, phenomenological correlations, and equations, and being based on geometry and/or topology of components of the process plant, the dynamic model receiving process parameters as input values, the dynamic model being adapted to represent a transition from one to another state of the process plant, wherein the dynamic model is used in an online mode, in which the dynamic model is used in parallel with the operation of the process plant, wherein signals from a control system of the process plant, the signals representing values of at least one first process parameter, are received and fed into the dynamic model.Type: GrantFiled: October 22, 2020Date of Patent: March 10, 2026Assignee: Linde GmbHInventors: Florian Schliebitz, Ingo Thomas, Bernd Wunderlich, Martin Pottmann, Anna Ecker