Patents Assigned to Lion Copolymer Holdings, LLC
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Patent number: 11879072Abstract: Disclosed herein are styrene butadiene rubber latex compositions with high solids content and methods for making and using these compositions. The method for making the styrene butadiene rubber latex compositions can include mixing a seed, a styrene, an initiator, a base, a surfactant, and a solvent; adding a first portion of 1,3-butadiene to make a first reaction mixture; heating the first reaction mixture for a first reaction time to make a first styrene butadiene rubber latex; mixing the first styrene butadiene rubber latex, a styrene, a base, an initiator, a surfactant, and a solvent; adding a second portion of 1,3-butadiene to make a second reaction mixture; and heating the second reaction mixture for a second reaction time to make a second styrene butadiene rubber latex, where the second styrene butadiene rubber latex has a solids content higher than that of the first styrene butadiene rubber latex.Type: GrantFiled: May 1, 2023Date of Patent: January 23, 2024Assignee: Lion Copolymers Holdings, LLCInventors: Lawrence Douglas Harris, Willie C. Burton
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Publication number: 20230348762Abstract: Disclosed herein are styrene butadiene rubber latex compositions with high solids content and methods for making and using these compositions. The method for making the styrene butadiene rubber latex compositions can include mixing a seed, a styrene, an initiator, a base, a surfactant, and a solvent; adding a first portion of 1,3-butadiene to make a first reaction mixture; heating the first reaction mixture for a first reaction time to make a first styrene butadiene rubber latex; mixing the first styrene butadiene rubber latex, a styrene, a base, an initiator, a surfactant, and a solvent; adding a second portion of 1,3-butadiene to make a second reaction mixture; and heating the second reaction mixture for a second reaction time to make a second styrene butadiene rubber latex, where the second styrene butadiene rubber latex has a solids content higher than that of the first styrene butadiene rubber latex.Type: ApplicationFiled: May 1, 2023Publication date: November 2, 2023Applicant: LION COPOLYMER HOLDINGS, LLCInventors: Lawrence Douglas HARRIS, Willie C. Burton
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Patent number: 11674059Abstract: Disclosed herein are styrene butadiene rubber latex compositions with high solids content and methods for making and using these compositions. The method for making the styrene butadiene rubber latex compositions can include mixing a seed, a styrene, an initiator, a base, a surfactant, and a solvent; adding a first portion of 1,3-butadiene to make a first reaction mixture; heating the first reaction mixture for a first reaction time to make a first styrene butadiene rubber latex; mixing the first styrene butadiene rubber latex, a styrene, a base, an initiator, a surfactant, and a solvent; adding a second portion of 1,3-butadiene to make a second reaction mixture; and heating the second reaction mixture for a second reaction time to make a second styrene butadiene rubber latex, where the second styrene butadiene rubber latex has a solids content higher than that of the first styrene butadiene rubber latex.Type: GrantFiled: June 6, 2022Date of Patent: June 13, 2023Assignee: Lion Copolymers Holdings, LLCInventors: Lawrence Douglas Harris, Willie C. Burton
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Publication number: 20220389287Abstract: Disclosed herein are styrene butadiene rubber latex compositions with high solids content and methods for making and using these compositions. The method for making the styrene butadiene rubber latex compositions can include mixing a seed, a styrene, an initiator, a base, a surfactant, and a solvent; adding a first portion of 1,3-butadiene to make a first reaction mixture; heating the first reaction mixture for a first reaction time to make a first styrene butadiene rubber latex; mixing the first styrene butadiene rubber latex, a styrene, a base, an initiator, a surfactant, and a solvent; adding a second portion of 1,3-butadiene to make a second reaction mixture; and heating the second reaction mixture for a second reaction time to make a second styrene butadiene rubber latex, where the second styrene butadiene rubber latex has a solids content higher than that of the first styrene butadiene rubber latex.Type: ApplicationFiled: June 6, 2022Publication date: December 8, 2022Applicant: LION COPOLYMER HOLDINGS, LLCInventors: Lawrence Douglas HARRIS, Willie C. BURTON
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Patent number: 9574055Abstract: A compatibilized silica for incorporation into natural and synthetic polymers in latex form using precipitated or fumed silica with at least two organosilicon coupling compounds in an aqueous suspension. Polymer-silica reinforced masterbatches are prepared by addition of the compatibilized silica slurry using the formed compatibilized silica.Type: GrantFiled: August 24, 2012Date of Patent: February 21, 2017Assignee: LION COPOLYMER HOLDINGS, LLCInventors: Mark Arigo, Subir Debnath
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Patent number: 9267019Abstract: A rubber composition and a tire using the rubber composition utilizing a functionalized silica dry precipitated silica with a specific surface area in the range of 100 to 300 m2/gm treated with a plurality of silanes coupling agents to form a wet polymer silica masterbatch, then blending the masterbatch with a latex rubber component that includes a styrene-butadiene copolymer rubber or a blend of the styrene-butadiene copolymer rubber and another conjugated diene base rubber using a plurality of coupling agents simultaneously.Type: GrantFiled: July 27, 2012Date of Patent: February 23, 2016Assignee: LION COPOLYMER HOLDINGS, LLCInventors: Mark Arigo, Subir Debnath, Jorge Soto
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Patent number: 8835536Abstract: A highly loaded silica wet masterbatch utilizing a functionalized silica dry precipitated silica with a specific surface area in the range of 100 to 300 m2/gm treated with a plurality of silanes coupling agents to form a wet polymer silica masterbatch, then blending the masterbatch with a latex rubber component that includes a styrene-butadiene copolymer rubber or a blend of the styrene-butadiene copolymer rubber and another conjugated diene base rubber using a plurality of coupling agents simultaneously.Type: GrantFiled: July 27, 2012Date of Patent: September 16, 2014Assignee: Lion Copolymer Holdings, LLCInventors: Subir Debnath, Mark Arigo
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Patent number: 8741987Abstract: A polymer masterbatch in latex form having nanomaterials and a compatibilized silica for incorporation into natural and synthetic polymers in latex form using precipitated or fumed silica with at least two organosilicon coupling compounds attached to the silica in an aqueous suspension.Type: GrantFiled: August 24, 2012Date of Patent: June 3, 2014Assignee: Lion Copolymer Holdings, LLCInventors: Lawrence Douglas Harris, Mark Arigo, Subir Debnath, Jorge Soto