Abstract: Lubricating compositions comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The lubricating composition also comprises an antiwear agent. Methods of lubricating an internal combustion engine comprise contacting the internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. Methods of reducing lubricant oxidation and/or corrosion in an internal combustion engine with a lubricating composition comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative. The use of a comprising a thiol-carboxylic adduct that is the reaction product of a thiol and carboxylic acid and/or a carboxylic acid derivative to reduce lubricant oxidation and/or corrosion in an internal combustion engine.
Abstract: The disclosed technology provides a method of lubricating a compression-ignition internal combustion engine with a maximum laden mass over 2,700 kg comprising supplying to the engine a lubricating composition comprising: an oil of lubricating viscosity, a 300 TBN or higher alkaline earth metal sulfonate detergent having a metal ratio of 10 to 40, an alkaline earth metal sulfonate detergent having a metal ratio of 3 to 9, and a TBN of 81 to 180 mg KOH/g, wherein the sulfonate detergents provide a total amount of sulfonate substrate of 1 wt % to 3 wt % of the lubricating composition, 0.1 to 1.2 wt % of antioxidant, wherein at least 20 wt % of the antioxidant is a phenolic antioxidant, a borated compound present in an amount to deliver 25 ppm to 300 ppm of boron, the lubricating composition has a sulfated ash content of 0.5 wt % to not more than 1.5 wt %, and the lubricating composition has a TBN of 6.5 to 15 mg KOH/g.
Abstract: The present invention relates to a lubricating composition containing: an oil of lubricating viscosity, a non-borated dispersant, a detergent, and an antiwear package comprising (a) a derivative of a hydroxycarboxylic acid, (b) an amine salt of a phosphoric acid ester, and (c) a phosphite having at least one hydrocarbyl group with 4 or more carbon atoms. The invention further provides for a method of lubricating a driveline device application by employing a lubricating composition containing the antiwear package.
Abstract: A composition obtained by reacting an O,O?-dialkyldithiophosphoric acid with a hydroxyalkyl acrylate or a hydroxyalkyl methacrylate, and reacting the product thereof with a dialkylphosphite provides good antiwear protection.
Type:
Application
Filed:
October 22, 2020
Publication date:
February 11, 2021
Applicant:
The Lubrizol Corporation
Inventors:
William D. Abraham, Mahmud M. Hussain, Kurt F. Wollenberg
Abstract: The present invention relates to a lubricating composition containing (a) an oil of lubricating viscosity; and (b) a compound selected from the group consisting of: (i) an ester-containing heterocycle; (ii) an amide-containing heterocycle; and (iii) a pyrimidine, wherein the ester-containing heterocycle and the amide-containing heterocycle have a hydrocarbyl group containing 6 to 40 carbon atoms. The invention further provides for a method of supplying an internal combustion engine with the lubricating composition.
Type:
Grant
Filed:
December 20, 2019
Date of Patent:
February 9, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Patrick E. Mosier, Jason R. Brown, Matthew D. Gieselman, Calvin W. Schroeck, Seth L. Crawley, William R. S. Barton, William C. Ward, Jr.
Abstract: The invention relates to quaternary ammonium amide and/or ester salts and their use as additives, including their use in fuels, such as diesel fuel. The invention particularly relates to the use of quaternary ammonium amide and/or ester salts as detergents in diesel fuels.
Type:
Grant
Filed:
October 14, 2019
Date of Patent:
February 9, 2021
Assignee:
The Lubrizol Corporation
Inventors:
Paul R. Stevenson, James C. Ray, David J. Moreton, James H. Bush
Abstract: The present invention relates to industrial gear lubricating compositions that include a specific class of substituted triazoles, where the substituted triazole includes at least one hydrocarbyl group linked to one of the nitrogen atoms in the triazole ring. Such compositions provide surprisingly good seal compatibility compared to compositions with other triazoles and/or alternative additives.
Abstract: The instant disclosure is directed to a method of lubricating a sump-lubricated, high efficiency, gasoline-fueled internal combustion engine. Said method involves supplying to the engine a lubricating composition comprising an oil of lubricating viscosity, an anti-wear agent, an ashless antioxidant, a metal-containing detergent, an ashless polyolefin dispersant, and (f) a polymeric viscosity modifier. The disclosure further provides a method of operating a high efficiency sump-lubricated gasoline-fueled internal combustion engine while maintaining or improving at least one of durability, deposit control, oxidation control, fuel economy, and resistance to knock and stochastic pre-ignition.
Type:
Application
Filed:
November 28, 2018
Publication date:
January 7, 2021
Applicant:
The Lubrizol Corporation
Inventors:
Patrick E. Mosier, Matthew D. Gieselman, George S. Szappanos, Alexander Sammut, Ewan E. Delbridge, Oliver Smith
Abstract: The disclosed technology relates to an automotive gear oil, which may be used, for example, in heavy duty manual transmissions and axles, and includes an oil of lubricating viscosity, 1 wt % or less of a dispersant, and at least one boron containing compound.
Abstract: The disclosed technology relates to a dispersant composition comprising the reaction product of a polyolefin acylating agent and a polyamine having a sterically hindered head group. In addition, the technology relates to lubricating compositions containing the dispersant composition and an oil of lubricating viscosity, as well as methods of employing the lubricating composition in an engine and engine oils. Lubricating oils containing the dispersants of the disclosed technology simultaneously achieves seal compatibility, wear, deposit, varnish and corrosion control while also maintaining fuel economy performance over a broad temperature range.
Type:
Application
Filed:
November 29, 2018
Publication date:
November 26, 2020
Applicant:
The Lubrizol Corporation
Inventors:
Dixit Parmar, Joanne L. Jones, Daniel J. Saccomando, Nicolas Proust, Patrick E. Mosier
Abstract: The invention is directed to a method for reducing low speed pre-ignition events in a spark-ignited direct injection internal combustion engine by supplying to the sump a lubricant composition which contains an oil of lubricating viscosity and a boron-containing ashless dispersant. The ashless dispersant may be selected from succinimide compounds prepared from aliphatic or aromatic amines.
Type:
Grant
Filed:
March 22, 2016
Date of Patent:
October 13, 2020
Assignee:
The Lubrizol Corporation
Inventors:
Patrick E. Mosier, Jeffry G. Dietz, Alexander Sammut, Mary Galic Raguz, Matthew D. Gieselman
Abstract: A hydraulic fluid includes an oil of lubricating viscosity and at least 2 wt. % of an ester of a carboxy group-containing interpolymer comprising units derived from a vinyl aromatic monomer and units derived from a carboxylic acid monomer. The interpolymer also contains nitrogen functionality. The hydraulic fluid is at least substantially free of polyacrylates and polymethacrylates.
Type:
Application
Filed:
April 19, 2017
Publication date:
October 8, 2020
Applicant:
The Lubrizol Corporation
Inventors:
Daniel J. Knapton, David Cressey, Daniel C. Visger
Abstract: A lubricant composition of an oil of lubricating viscosity and a phosphite ester reaction product of a monomeric phosphorous acid or an ester thereof with a first alkylene diol having two hydroxy groups in a 1,4 or 1,5 or 1,6 relationship and a second, alkyl-substituted, diol being a substituted 1,3-propylene diol, exhibits good wear and frictional performance.
Type:
Grant
Filed:
November 11, 2015
Date of Patent:
October 6, 2020
Assignee:
The Lubrizol Corporation
Inventors:
William D. Abraham, Nga H. Nguyen, Paul E. Adams, Kurt F. Wollenberg
Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity, an ashless thiocarbamate compound having an optionally-substituted hydrocarbyl group on an S-atom and an optionally-substituted hydrocarbyl group on an N-atom, and a boron-containing compound. The invention further relates to a method of lubricating an internal combustion engine with the lubricating composition.
Type:
Grant
Filed:
December 17, 2014
Date of Patent:
September 29, 2020
Assignee:
The Lubrizol Corporation
Inventors:
Yanshi Zhang, Jody A. Kocsis, Mark J. McGuiness
Abstract: A cleaning composition, which is suitable for cleaning fuel delivery systems, air-intake systems, intake valves, and combustion chambers, includes at least 3 wt. % of a polyether component, at least 5 wt. % of a polar solvent, and at least 5 wt. % a non-polar solvent. The polyether component is selected from polyethers, polyetheramines, and mixtures thereof.
Type:
Grant
Filed:
January 15, 2016
Date of Patent:
September 22, 2020
Assignee:
The Lubrizol Corporation
Inventors:
Stuart L. Bartley, Thomas R. Weyenberg, Michael D. Nicholls, Garrett Parker
Abstract: A fully-formulating lubricating composition comprising an oil of lubricating viscosity; an ionic tetrahedral borate compound including a tetrahedral borate anion having a boron atom with two bidentate di-oxo ligands both being a linear C18-tartrimide; a first dispersant comprising a conventional ammonium substituted polyisobutenyl succinimide compound having a polyisobutenyl number average molecular weight of 750 to 2,500; a second dispersant comprising an ammonium substituted polyisobutenyl succinimde compound having an N:CO ratio of 1.8 and a polyisobutylenyl number average molecular weight of 750 to 2,500, wherein one or more of the first dispersant and the second dispersant are in cationic form. The fully formulated lubricating composition including one or more performance additives.
Type:
Grant
Filed:
July 21, 2017
Date of Patent:
September 15, 2020
Assignee:
The Lubrizol Corporation
Inventors:
James D. Burrington, Ewan E. Delbridge, Binbin Guo, Jason J. Hanthorn
Abstract: The disclosed technology relates to an additive composition and lubricating grease composition containing a synergistic combination of ingredients for inhibiting rust, particularly rust on mechanical devices subject to contact with salt water.
Abstract: A lubricating composition includes a sulfurized oxy-substituted aromatic polyol compound and an oil of lubricating viscosity. The sulfurized oxy-substituted aromatic polyol compound includes at least one of a sulfurized oxy-substituted aromatic polyol and a salt of a sulfurized oxy-substituted aromatic polyol. The compound is suitable as a replacement for detergents that contain Cn alkyl phenols derived from oligomers of propylene.
Type:
Application
Filed:
December 7, 2016
Publication date:
September 10, 2020
Applicant:
THE LUBRIZOL CORPORATION
Inventors:
Kamalakumari K. Salem, Gary M. Walker, Ewan E. Delbridge, David J. Moreton, Adam Cox, W. Preston Bames, James P. Roski, Mohamed G. Fahmy
Abstract: A lubricating composition includes an oil of lubricating viscosity and a compound comprising a protected mercaptophenol. The protected mercaptophenol includes a mercapto group in which the hydrogen is substituted with a substituent of at least 5 carbons. The substituent is selected from hydroxy-substituted hydrocarbyl groups, poly(ether) groups, hydrocarbyl groups, and mixtures and salts thereof.
Abstract: The invention provides a method of lubricating a 2-stroke marine diesel cylinder liner with a lubricating composition having a total base number of 10 to 25 mg KOH/g. The invention further provides a lubricating composition for lubricating the 2-stroke marine diesel cylinder liner.
Type:
Grant
Filed:
October 30, 2015
Date of Patent:
August 18, 2020
Assignee:
The Lubrizol Corporation
Inventors:
Stephen J. Cook, Natasha K. Horn, Shaun P. Carney, Mark C. Davies, David M. Hobson