Abstract: An article, process, and method for surface plasmon resonance plates are described. A substrate is covered with a thin metal film onto which a second thin metal film is deposited. The surface of the second thin metal film is converted to the metal oxide which is used to covalently bond organosilanes to the surface. Reactive organosilanes containing terminal bonding groups are arranged in a plurality of spots that are surrounded by inert organosilanes. Biomolecule attachment to the binding group is detected or measured from surface plasmon signals from the first thin metal film.

Abstract: In one aspect, a process comprises: a) fabricating polymer layers embedding an electro-optic polymer waveguide; b) fabricating a high speed electrode and a ground electrode, wherein the high speed electrode and ground electrode are positioned to control the electro-optic polymer waveguide; and c) fabricating a resistor at a predetermined location along the high speed electrode.

Abstract: In one aspect, an electro-optic device comprises: a) a high speed electrode; b) a ground electrode; c) polymer layers embedding an electro-optic polymer waveguide; and d) at least one integrated resistor in electrical contact with the high speed electrode and the ground electrode, wherein the high speed electrode and the ground electrode are positioned to control light in the electro-optic polymer waveguide.

Abstract: Crosslinked polymer blends comprising a poly(arylene ether) and a nonlinear optical chromophore. Also featured are electro-optic devices incorporating these blends.

Abstract: A polymer that includes a constitutional unit contributed by (a) a first monomer comprising a halocatechol diacrylate, a halocatechol diacrylate, a haloresorcinol diacrylate, or a halohydroquinone diacrylate, and (b) a second monomer comprising a charge transporting moiety.

Abstract: Methods for wireless communication may include selection of a photonic signal to generate a carrier frequency for wireless communication. In an illustrative example, the selected photonic signal may have sidebands with a frequency difference corresponding to a carrier frequency within one of multiple predetermined carrier frequency bands. In some implementations, each of the predetermined carrier frequency bands may contain a local minimum signal attenuation characteristic over a signal path of the wireless communication. For example, the selection of the photonic signal may be based on predetermined selection criteria such as error information, and/or signal path conditions (e.g., atmospheric humidity level, noise, signal strength). Apparatus for performing such methods may include a wireless communication system with a transmitter and/or receiver.

Abstract: A method including poling an optical waveguide device including an optical waveguide core, an electrode, and an organically modified sol-gel layer.

Abstract: A process that includes (a) providing a mixture including i) a halocatechol diacrylate, a haloresorcinol diacrylate, or a halohydroquinone diacrylate component, ii) a charge transporting component having a radical polymerizable group, and iii) a radical initiator and b) initiating a radical polymerization.

Abstract: In one aspect, a microelectrode comprising an upper surface, two walls, and a polymer core is described, wherein each of the two walls forms an angle with a lower surface, and the upper surface and each of the two walls comprises a metal thin film in contact with the polymer core. The lower surface, however, lacks a continuous metal thin film. In another aspect, a microelectrode comprising a metal thin film is described in which the metal thin film has a thickness and a plane bisects the thickness. The plane forms an angle with a lower surface that lacks a contiuous metal thin film. The metal thin film is in contact with a supporting polymer having an upper surface that also lacks a continuous metal thin film.

Abstract: Apparatus and associated systems, methods and computer program products relate to an electro-optic device that includes a drive electrode that is substantially resonant with millimeter wave and/or terahertz wave radiation. In various embodiments, the drive electrode may comprise at least one structure with an absorption resonance at the frequency of interest (e.g., 94 gigahertz, 120 gigahertz, 1 terahertz). In some embodiments, such periodic structures may be terminated with a characteristic impedance that substantially enhances the absorption resonance.

Abstract: A process for fabricating a microelectrode is described that includes: a) providing a substrate comprising at least one polymer micro-ridge, where the polymer micro-ridge comprises an upper surface and two walls, and the two walls form an angle with a lower surface; b) depositing a metal thin film on the upper surface, the two walls, and the lower surface; and c) etching a predetermined amount of the deposited metal thin film on the lower surface to form the microelectrode.

Abstract: A method including poling an optical waveguide device including an optical waveguide core, an electrode, and an organically modified sol-gel layer.

Abstract: Optical waveguide devices that include a polymer clad and a polymer core where the clad includes constitutional units contributed by (a) a monomer selected from the group consisting of a halocatechol diacrylate, a haloresorcinol diacrylate, and a haldhydroquinone diacrylate, and/or (b) a charge transport moiety.

Abstract: In various embodiments, chromophores are described that include novel electron acceptors, novel electron donors, and/or novel conjugated bridges that are useful in nonlinear optical applications. In some embodiments, the present invention provides chromophore architectures wherein a chromophore contains more than one electron acceptor in electronic communication with a single electron donor, and/or more than one electron donor in electronic communication with a single electron acceptor. Also described is processes for providing materials comprising the novel chromophores and polymer matrices containing the novel chromophores. Electro-optic devices described herein contain one or more of the described electron acceptors, electron donors, conjugated bridges, or chromophores.

Abstract: Electro-optic waveguide devices that comprise an electro-optic polymer core and a polymer buffer clad. The polymer buffer clad comprises an organically modified sol-gel and has a refractive index lower than the refractive index of the core.

Abstract: A process comprising: a) reacting a diphenol monomer A with a monomer B having two locations for reaction with A to form arylene ether monomer C and b) reacting arylene ether monomer C with a diphenol monomer D to form a polymer, where monomer A is HX1-Q1-X1H;??(II) monomer B is arylene ether monomer C is and monomer D is wherein: Q1 comprises at least one aryl or heteroaryl group; Q2 comprises at least one aryl or heteroaryl group; X1 is O bonded directly to an aryl carbon of Q1; X2 is O bonded directly to an aryl carbon of Q2; Z is a linker comprising at least one —(C(R2)2)— group; Y is a single bond or linker group (e.g., comprising up to about 50 carbons); R1 is independently at each occurrence H, a halogen, an alkyl group, a heteroalkyl group, an aryl group, or a heteroaryl group; R2 is independently at each occurrence H, an alkyl group, or a heteroalkyl group; and R3 is H or a crosslinkable group.

Abstract: Apparatus and associated systems for transmission of signals within a wide bandwidth (e.g., from DC to 40 GHz and above) include a conduction path and ground structures in an arrangement to provide a smooth transition between propagation in a coplanar waveguide mode and propagation in a microstrip waveguide mode. Some embodiments may be provided without vias, for example, by providing low impedance connections between ground structures on different layers, where the connections are made external to a medium between the layers. Some embodiments may feature a monotonically decreasing gap between a signal conduction path and a coplanar ground structure. Such embodiments may be used, for example, to provide a low loss, wide bandwidth interface between a coaxial transmission line and a microstrip transmission line. As another example, one or more such structures may be used in an electro-optic modulator to control an optical signal.

Abstract: A device that comprises: a) a first optical waveguide; b) a second optical waveguide; c) an optical coupling region including the first and second optical waveguides, the optical coupling region characterized as having at least one coupling length and comprising a first bias section, a modulation section, and a second bias section arranged such that light propagates serially through the first bias section, the modulation section, and the second bias section; d) a first bias electrode for biasing the first bias section; e) a modulating electrode for applying a modulating voltage to the modulation section, the modulating electrode being positioned to control the refractive index of the first optical waveguide; and f) a second bias electrode for biasing the second bias section.

Abstract: A process, comprising: a) reacting a an alkoxysilane, an (epoxy)alkoxysilane, and a fluorinated alkoxysilane to form a fluorinated sol-gel polymer; and b) reacting a nonlinear optical chromophore comprising a donor, a ?-bridge, an acceptor, and at least one alkoxysilyl group with the fluorinated sol-gel polymer to form a nonlinear optical fluorinated sol-gel polymer.

Abstract: A nonlinear optical chromophore having the formula D-?-A, wherein ? is a ? bridge including a thiophene ring having oxygen atoms bonded directly to the 3 and 4 positions of the thiophene ring, D is a donor, A is an acceptor, and the oxygen atoms are further substituted with a fluorinated group comprising at least three fluorines is described. Some examples of fluorinated groups comprising at least three fluorine atoms are 2,2,2-trifluoroethyl; 2,2,3,3,3-pentafluoropropyl; 2,2,3,3,4,4,4-heptafluorobutyl; 2,2,3,3,4,4,5,5,5-octafluoropentyl; 3,3,4,4,-5,5,6,6,7,7,8,8,8-tridecafluoro-1-octyl; 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8 -pentadecafluorooctyl; 1-trifluoromethyl-2,2,2-trifluoroethyl; 1-trifluoromethyl-2,2,3,3,3 -pentafluoropropyl; 2,3,4,5,6-pentafluorobenzyl; and (2,3,4,5,6-pentafluorophenyl)ethyl.