Patents Assigned to Marko Materials, Inc.
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Patent number: 4430115Abstract: Alloys having composition similar to commercial precipitation-hardenable stainless steels, but modified by the addition of 1.4 to 2.4 wt % boron, are disclosed. The alloys are subjected to a rapid solidification processing (RSP) technique which produces cooling rates between .about.10.sup.5 -10.sup.7 .degree.C./sec. The as-quenched RSP ribbon or powder, etc., consists primarily of a metastable crystalline solid solution phase. The metastable crystalline phases are subjected to suitable heat treatments so as to produce a transformation to a stable multiphase microstructure, which includes borides; this heat treated alloy exhibits superior mechanical properties and thermal stability in conjunction with good corrosion and oxidation resistance.Type: GrantFiled: May 27, 1980Date of Patent: February 7, 1984Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Donald E. Polk, Bill C. Giessen
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Patent number: 4410490Abstract: New nickel and cobalt base alloys containing tungsten and carbon are disclosed. The alloys are subjected to rapid solidification processing (RSP) technique which produces cooling rates between 10.sup.5 .degree. to 10.sup.7 .degree. C./sec. The as-quenched ribbon, powder, etc. consists predominantly of amorphous phase. The amorphous phase is subjected to suitable heat treatments so as to produce a transformation to a microcrystalline alloy which includes carbides; this heat treated alloy exhibits high hardness combined with toughness for many applications wherein superhard materials are required.Type: GrantFiled: July 12, 1982Date of Patent: October 18, 1983Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Viswanathan Panchanathan
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Patent number: 4405368Abstract: New iron base alloys containing aluminum and boron are disclosed. The alloys are subjected to a rapid solidification processing (RSP) technique which produces cooling rates between .about.10.sup.5 to 10.sup.7 .degree. C./sec. The as-quenched ribbon or powder, etc consists primarily of a metastable crystalline solid solution phase. The metastable crystalline phases are subjected to suitable heat treatments so as to produce a transformation to a stable multiphase microstructure which includes borides. The heat treated alloy exhibits superior mechanical properties with good corrosion and oxidation resistance.Type: GrantFiled: May 7, 1981Date of Patent: September 20, 1983Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Viswanathan Panchanathan, Bill C. Giessen
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Patent number: 4404028Abstract: New nickel rich metal alloys containing copper along with specific amounts of boron are disclosed. The alloys are subjected to rapid solidification processing (RSP) techniques which produce cooling rates between .about.10.sup.5 .degree. to 10.sup.7 .degree. C./sec. The as-quenched ribbon, powder, etc. consists primarily of a metastable crystalline solid solution phase. The metastable crystalline phases are subjected to suitable heat treatments so as to produce a transformation to a stable multiphase microstructure which includes borides. This heat treated alloy exhibits superior mechanical properties with good corrosion and/or oxidation resistance for numerous engineering applications.Type: GrantFiled: April 27, 1981Date of Patent: September 13, 1983Assignee: Marko Materials, Inc.Inventors: Viswanathan Panchanathan, Ranjan Ray, Bill C. Giessen
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Patent number: 4402745Abstract: New iron rich metal alloys containing aluminum and copper along with specific amounts of boron are disclosed. The alloys are subjected to rapid solidification processing (RSP) technique which produces cooling rates between .about.10.sup.5 to 10.sup.7 .degree.C./sec. The as-quenched ribbon, powder etc. consists primarily of a metastable crystalline solid solution phase. The metastable crystalline phases are subjected to suitable heat treatments so as to produce a transformation to a stable multiphase microstructure which includes borides; this heat treated alloy exhibits superior mechanical properties with good corrosion and/or oxidation resistance for numerous engineering applications.Type: GrantFiled: April 27, 1981Date of Patent: September 6, 1983Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Viswanathan Panchanathan, Bill C. Giessen
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Patent number: 4400212Abstract: New cobalt base alloys containing chromium and carbon are disclosed. The alloys are subjected to rapid solidification processing (RSP) technique which produces cooling rates between 10.sup.5 to 10.sup.7 oC/sec. The as-quenched ribbon, powder etc. consists predominantly of amorphous phase. The amorphous phase is subjected to suitable heat treatments so as to produce a transformation to a microcrystalline alloy which includes carbides; this heat treated alloy exhibits superior mechanical properties for numerous industrial applications.Type: GrantFiled: January 18, 1982Date of Patent: August 23, 1983Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Viswanathan Panchanathan
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Patent number: 4395464Abstract: New copper-rich metal alloys containing nickel along with certain specific amounts of boron are disclosed. The alloys are subjected to a rapid solidification processing (RSP) technique which produces cooling rates between .about.10.sup.5.degree. to 10.sup.7 .degree. C./sec. The asquenched ribbon, powder, etc. consists primarily of a metastable crystalline solid solution phase. The metastable crystalline phases are subjected to suitable heat treatments so as to produce a transformation to a stable multiphase microstructure, which includes borides. This heat treated alloy exhibits superior mechanical properties with good corrosion and/or oxidation resistance for numerous engineering applications.Type: GrantFiled: April 1, 1981Date of Patent: July 26, 1983Assignee: Marko Materials, Inc.Inventors: Viswanathan Panchanathan, Ranjan Ray, Bill C. Giessen
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Patent number: 4379720Abstract: Nickel-aluminum alloys containing boron in powder form are disclosed. These alloys are subjected to melt-spinning to form a brittle filament consisting in large measure of a metastable solid solution phase. This is then pulverized to powder configuration. Such powders exhibit excellent sprayability to form a dense, homogeneous, hard coating on a metallic substrate. The alloys, also exhibit excellent resistance to high temperature oxidation.Type: GrantFiled: March 15, 1982Date of Patent: April 12, 1983Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Viswanathan Panchanathan
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Patent number: 4362553Abstract: Iron base alloys containing chromium and refractory metals as well as 0.8 to 1.3 wt % boron are disclosed. The alloys are subjected to a rapid solidification processing (RSP) technique, producing cooling rates of about 10.sup.5 to 10.sup.7 .degree. C./sec. The as-quenched RSP ribbon, or powder, etc., consists primarily of a single phase with a body centered cubic structure. After appropriate heat treatments, the rapidly solidified alloys have a microstructure consisting of ultrafine hard particles of metallic carbides and borides and mixtures thereof dispersed in an iron-rich matrix. These alloys exhibit excellent corrosion resistance combined with high hardness, wear resistance and high temperature stability. These heat treated alloys have superior properties which make them suitable for many applications, where high strength and corrosion resistance are required, in particular at elevated temperature, e.g. high temperature bearings.Type: GrantFiled: June 22, 1981Date of Patent: December 7, 1982Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Donald E. Polk, Bill C. Giessen
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Patent number: 4359352Abstract: Nickel and iron-nickel base alloys are described together with a rapid solidification process used in the preparation thereof to provide materials useful in the fabrication of parts subject to high temperature operating conditions. The alloys include commercial nickel base superalloys to which a specified amount of boron is added.Type: GrantFiled: November 19, 1979Date of Patent: November 16, 1982Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Donald E. Polk, Bill C. Giessen
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Patent number: 4347076Abstract: A method of fabricating aluminum alloys containing finely dispersed aluminum-transition metal intermetallic phases is disclosed. The alloys are subjected to melt spinning to form a brittle filament consisting in large measure of a metastable face-centered cubic solid solution; this is then pulverized to a staple or powder configuration; the power or staple is consolidated using conventional techniques. Upon heat treatment, the solid solution decomposes into a structure consisting of an aluminum alloy matrix of conventional composition containing a fine uniform dispersion of the intermetallic phase, the heat-treated alloy being ductile. The heat-treated alloys possess high strength, especially at elevated temperatures. Preferred alloys are disclosed which contain 10 to 15 wt % Fe.Type: GrantFiled: October 3, 1980Date of Patent: August 31, 1982Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Donald E. Polk, Bill C. Giessen
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Patent number: 4318733Abstract: Alloys having compositions similar to commercial tool steels, but modified by the addition of 0.1 to 1.5 wt. % boron are disclosed. The alloys are subjected to a rapid solidification processing (RSP) technique, producing cooling rates between 10.sup.5 -10.sup.7 .degree.C./sec. The as-quenched RSP ribbon or powder, etc. consists essentially of a single phase with a body centered cubic structure. After selected heat treatments, the rapidly solidified alloys have a microstructure consisting of ultrafine metallic carbides and metallic borides dispersed in an iron rich matrix and thus have high hardness, wear resistance and high-temperature stability. These final structures have improved properties for applications, e.g., where standard high speed tool steels are now utilized.Type: GrantFiled: November 19, 1979Date of Patent: March 9, 1982Assignee: Marko Materials, Inc.Inventors: Ranjan Ray, Donald E. Polk, Bill C. Giessen
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Patent number: 4297135Abstract: Alloys, of iron, cobalt, nickel and chromium containing both metalloids and refractory metals are disclosed. The alloys are rapidly solidified at cooling rates of 10.sup.5 -10.sup.7 .degree. C./sec so as to produce an ultrafine grained metastable crystal structure having enhanced compositional homogeneity. The as-quenched metastable alloys are brittle, permitting pulverization, if desired. Heat treatment is used to convert the metastable brittle alloys into ductile alloys with primary grains of ultrafine grain size which contain an ultrafine dispersion of boride as well as carbide and/or silicide particles. The powders or ribbons can be consolidated into bulk parts. The heat treated alloys possess good mechanical properties, in particular high strength and hardness, as well as good corrosion resistance for selected compositions, making them suitable for many engineering applications.Type: GrantFiled: November 19, 1979Date of Patent: October 27, 1981Assignee: Marko Materials, Inc.Inventors: Bill C. Giessen, Donald E. Polk, Ranjan Ray